专利号:US-4107089-A 优先权日:1977-03-14 标 题 :Catalyst for the synthesis of methanol and method for preparing same 发明人:BONDAR PETR GRIGORIEVICH; GOROSHKO OLEG NIKOLAEVICH; SUSCHAYA LARISA EMMANUILOVNA; LAVROVA VALENTINA VASILIEVNA; LELEKA VALENTINA EMMANUILOVNA; ILKO EDUARD GRIGORIEVICH 权利人:BONDAR PETR GRIGORIEVICH; GOROSHKO OLEG NIKOLAEVICH; SUSCHAYA LARISA EMMANUILOVNA; LAVROVA VALENTINA VASILIEVNA; LELEKA VALENTINA EMMANUILOVNA; ILKO EDUARD GRIGORIEVICH 摘要:A catalyst for the synthesis of methanol which contains an oxide of one or more metals of Group VI, chromium subgroup, of the periodic system, copper oxide, zinc oxide and an oxide of one or more hardly reducible metals of Group II-III of the periodic system.
专利号:US-4790963-A 优先权日:1984-08-20 标 题:Process for synthesis of esters from gaseous reactants containing organic hydroxy compounds and mixtures of hydrogen and carbon monoxide 发明人:ATTIG THOMAS G; GRAHAM ANNE M; PESA FREDERICK A 权利人:STANDARD OIL CO OHIO 摘要:A process for producing an ester is disclosed comprising contacting a gaseous reactant containing at least one organic hydroxy compound and a mixture of carbon monoxide and hydrogen with an ester synthesis catalyst of the formula MaAbRuCucNzOx wherein M is selected from the group consisting of Ce, Cr, Fe, Mn and mixtures thereof, A is an alkali metal, alkaline earth metal or mixture thereof, a is from 0 to about 1, b is from 0.002 to about 10, c is from 0.2 to about 20, z is from 0 to about 196 by weight, x is the number of oxygens needed to fulfill the valence requirements of the other elements. The organic hydroxy compound can be provided separately or formed by contacting a mixture of carbon monoxide and hydrogen with an alcohol synthesis catalyst at an elevated temperature and pressure. The alcohol synthesis catalyst and ester synthesis catalyst can be in tandem or mixed.
专利号:US-4943551-A 优先权日:1985-11-08 标 题:Catalyst for synthesis of mixtures of methanol and higher alcohols 发明人:DOMBEK BERNARD D 权利人:UNION CARBIDE CHEM PLASTIC 摘要:Catalyst composition for the production of methanol and higher saturated aliphatic alcohols from synthesis gas. The catalysts consist essentially of: n (i) about 0.18 to about 0.81 mol fraction of copper; n (ii) about 0.045 to about 0.54 mol fraction of thorium; n (iii) up to about 0.54 mol fraction of zirconium; and n (iv) about 0.01 to about 0.2 mol fraction of an alkali metal.
专利号:US-3840478-A 优先权日:1970-12-31 标题:Catalyst of copper oxide-zinc-oxide-chromium oxide for methanol synthesis 发明人:UDA A; ASANO S 权利人:MITSUBISHI GAS CHEMICAL CO 摘要:1. A METHOD OF MANUFACTURING A COPPER OXIDE-ZINC OXIDE-CHROMIUM OXIDE CATALYST FOR USE IN THE SYNTHESIS OF METHANOL FROM HYDROGEN AND CARBON OXIDES WHICH COMPRISES MIXING, IN THE PRESENCE OF WATER, CHROMIUM TRIOXIDE WITH A COPPER-CHROMIUM PYROLYZED PRODUCT OBTAINED BY THE PYROLYSIS OF BASIC AMMONIUM COPPER CHROMATE AT 300* TO 400* C., IN AN AMOUNT SUCH THAT 1 TO 9 MOL OF CHROMIUM TRIOXIDE IS PRESENT FOR EVERY COPPER ATOM IN SAID PYROLYZED PRODUCT, ADDING TO THE ABOVE-OBTAINED MIXTURE BASE COPPER CARBONATE AND BASIC ZINC CARBONATE SO THAT THE ATOMIC RATIO CU:ZN:CR IS 10 TO 90:5 TO 70:2 TO 70, KNEADING THE MIXTURE FOLLOWED BY, DRYING, INITIAL CALCINING AT 200 TO 350* C. AND POST-CALCINING AT 250 TO 450* C.
专利号:US-12370534-B1 优先权日:2025-03-10 标 题:g-C3N4@CuO/MgAl2O4 nanocomposite synthesis for hydrogen generation 发明人:IBRAHIM MOHAMED NADY ABD EL-HAMEED; OMRAN MOHAMED KHAIRY; ABDULKHAIR BABIKER YAGOUB ELHADI 权利人:IMAM MOHAMMAD IBN SAUD ISLAMIC UNIV 摘要:A method for hydrogen (H2) generation includes reacting sodium borohydride (NaBH4) with water in the presence of a graphite-phase carbon nitride copper oxide and magnesium aluminum oxide (g-C3N4@CuO/MgAl2O4) nanocomposite to hydrolyze the sodium borohydride and generate hydrogen. The g-C3N4@CuO/MgAl2O4 nanocomposite comprises a graphite-phase carbon nitride (g-C3N4) in an amount of 5 to 15 percent by weight (wt. %), copper oxide in an amount of 3 to 7 wt. %, and magnesium aluminum oxide (MgAl2O4) in an amount of 80 to 90 wt. % based on a total weight of the g-C3N4@CuO/MgAl2O4 nanocomposite.
专利号:CA-2298099-C 优先权日:1989-12-19 标 题:Multistep synthesis of hexafluoropropylene
摘要:Merck Index - O'Neil MJ, Heckelman PE, Dobbelaar PH, Roman KJ (eds). The Merck Index, An Encyclopedia of Chemicals, Drugs, and Biologicals, 15th Ed. Cambridge, UK: The Royal Society of Chemistry, 2013. 摘要:Tominaga, Y., Science of Synthesis, (2004) 17, 1042.