CAS: 7376-90-1; (S)-2-Acetamido-3-Phenylpropanamide

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📜N-苄氧羰基-L-苯丙氨酰胺置于palladium On Activated Charcoal 氢气体系中,用 吡啶,N,N-二甲基甲酰胺 作为反应溶剂,化学反应生成 乙酰基苯甲酰胺
参考文献:含有氨基酸和肽的水溶液.第17部分.在25oc下,N-乙酰基-L-苯丙氨酸酰胺与某些n-乙酰基氨基酸酰胺相互作用的对焓系数
标题:含有氨基酸和肽的水溶液.第17部分.在25oc下,N-乙酰基-L-苯丙氨酸酰胺与某些n-乙酰基氨基酸酰胺相互作用的对焓系数
摘要:的稀释的焓ñ乙酰基大号-Phenylalaninamide并用此溶液equimolal ñ-Acetylglycinamide,ñ乙酰基大号丙氨酸酰胺,ñ乙酰基大号-Valinamide和ñ乙酰基大号-Leucinamide一直使用微量测定.获得的结果用于计算相似-类似(全同)和相似-不相似(异规)溶质相互作用的成对焓系数.然后将它们与组可加性方法一起使用,该方法对这些系统非常有效,以获取有关已定义的组之间的相互作用的信息.
DOI:10.1039/f19858102207

专利信息

专利号:US-5304631-A
优先权日:1990-01-16
标题:Synthetic helizyme enzymes
发明人：STEWART JOHN M; HAHN KARL W; KLIS WIESLAW A
权利人:UNIV COLORADO FOUNDATION
摘要:The design, and synthesis of peptide-based molecules termed helizymes which possess catalytic activity are described herein The catalytic molecules of the invention comprise a number of amphiphilic helical peptides, which interact via hydrophobic interactions and which are bonded at their carboxyl ends to a multifunctional base. Active site residues functional for catalysis are positioned within or at the N-termini of the helical peptides. The helizyme molecule adopts a conformation in aqueous medium such that a substrate binding pocket is formed and such that functional active site geometry results from the association of the helical peptides Specifically exemplified helizymes possess specificities and at least one catalytic activity of chymotrypsin, trypsin and acetylcholine esterase.