CAS: 161337-67-3; Hafnium Trifluoromethanesulfonate

该化合物是有机金属化合物,其特征是,存在一种过渡性金属,与三氟乙烷磺酸(又称三氟酸盐)离子体相协调.该化合物通常具有高度的热稳定性,在极地有机溶剂中可溶解,使其在各种化学应用中,包括催化解和材料科学中有用.三氟化硫集团以其极好的离子群能力而著称,这可以促进有机合成的反应.氢化合物本身以其高熔点和耐腐蚀性而著称,这种特性可以影响其化合物的行为.在再活性方面,三氟乙烷磺酸氢可参与协调化学,与其他离子形成复合体,并可能参与需要刘易剂的化学反应.

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    专利信息


    专利号:WO-2017030685-A1
    优先权日:2015-08-14
    标题 :One-pot synthesis of anhydropentitol mono- and diethers
    发明人:STENSRUD KENNETH
    权利人:ARCHER DANIELS MIDLAND CO
    摘要:A process for preparing anhydropentitol mono- and diethers from C 5 sugar alcohols is described. The process involves performing in a single reaction vessel consolidated reactions that a) cyclize dehydratively a linear C 5 sugar alcohol and b) etherify a resulting anhydropentitol. Each of the reactions is catalyzed by a very low amount of a water-tolerant Lewis acid catalyst relative to the starting sugar-alcohol. Depending on the reaction conditions, the synthesis method is efficient, selective and affords good yields of mono- and diethers. The anhydropentiol ethers can serve as renewable substitute precursors of petroleum incumbents for use in the making of surfactants and plasticizers.

    专利号:WO-2017100402-A1
    优先权日:2015-12-11
    标 题 :One-pot synthesis of anhydropentitol esters from pentitols, catalyzed by water-tolerant lewis acids
    发明人:STENSRUD KENNETH
    权利人:ARCHER DANIELS MIDLAND CO
    摘要:A procedure for preparing anhydropentitol mono, di, and tri esters is described. The process is performed in a single vessel and involves sequential dehydrative cyclization and carboxylic acid acylation steps. Each step is catalyzed by low loadings of a water-tolerant Lewis acid catalyst. The method of synthesis is efficacious and depending on the reaction condition, generates modest to high yields of the target mono-, di-, and triesters. The esters can be practical surrogates of incumbent petroleum materials of similar structure used for surfactants and plasticizers.

    专利号:WO-2023247609-A1
    优先权日:2022-06-22
    标题 :Process for the preparation of cyclohomogeranates
    发明人:SCHELWIES MATHIAS; BRUNNER BERNHARD; PELZER RALF; LIST BENJAMIN; TURBERG MATHIAS; MITSCHKE BENJAMIN; DAS SAYANTANI; DE CHANDRA KANTA
    权利人:BASF SE; STUDIENGESELLSCHAFT KOHLE GGMBH
    摘要:The present invention relates to a process for the preparation of cyclohomogeranates. The invention relates to the synthesis of cyclohomogeranates from well available esters of homogeranic acid in only one step. The cyclohomogeranates prepared according to the process of the present invention can be used in the fragrance industry as intermediates or the compounds can be used as such as aroma compound.

    专利号:US-6657068-B2
    优先权日:2002-03-22
    标题:Liquid phase oxidation of halogenated ortho-xylenes
    发明人:COLBORN ROBERT EDGAR; HALL DAVID BRUCE; KOCH PETER; OECKEL GERALD
    权利人:GEN ELECTRIC
    摘要:A method for the manufacture of halophthalic acid by liquid phase oxidation of halo-ortho-xylene is disclosed. The halophthalic acid may be dehydrated to form halophthalic anhydride which is useful in the synthesis of polyetherimide.

    专利号:US-6649773-B2
    优先权日:2002-03-22
    标题:Method for the manufacture of halophthalic acids and anhydrides
    发明人:COLBORN ROBERT EDGAR; HALL DAVID BRUCE; KOCH PETER; OECKEL GERALD
    权利人:GEN ELECTRIC
    摘要:A method for the manufacture of halophthalic acid by liquid phase oxidation of halo-ortho-xylene is disclosed. The halophthalic acid may be dehydrated to form halophthalic anhydride which is useful in the synthesis of polyetherimide.

    专利号:US-6657067-B2
    优先权日:2002-03-22
    标题 :Method for the manufacture of chlorophthalic anhydride
    发明人:COLBORN ROBERT EDGAR; HALL DAVID BRUCE; KOCH PETER; OECKEL GERALD
    权利人:GEN ELECTRIC
    摘要:A method for the manufacture of chlorophthalic acid by liquid phase oxidation of chloro-ortho-xylene is disclosed. The chlorophthalic acid may be dehydrated to form chlorophthalic anhydride which is useful in the synthesis of polyetherimide.

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    合成参考文献


    摘要:Mérour, J.-Y.; Joseph, B., Science of Synthesis Knowledge Updates, (2016) 3, 452.
    摘要:Spitzner, D., Science of Synthesis Knowledge Updates, (2016) 1, 50.
    摘要:Cheng, B.; Wang, T., Science of Synthesis Knowledge Updates, (2020) 3, 213.
    摘要:Mourad, A. K.; Czekelius, C., Science of Synthesis Knowledge Updates, (2011) 3, 81.
    摘要:Ulfkjær, A.; Pittelkow, M., Science of Synthesis Knowledge Updates, (2018) 1, 175.
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