甲基丙烯酸甲酯,二乙氨基乙醇置于sodium Ethanolate体系中,用47%的收率获得甲基丙烯酸二乙氨基乙酯 参考文献:Producing Unsaturated Esters By A Lanthanide Metal Alkoxide Catalyzed Transesterification Process 标题:Producing Unsaturated Esters By A Lanthanide Metal Alkoxide Catalyzed Transesterification Process 摘要:公开了一种生产式(3)的不饱和酯的方法:其中r1,R2和r3独立地代表氢,卤素,烷基,烯基等,R5代表烷基(可能被取代)等.该方法的特征在于,将式(1)的不饱和酯:其中r1,R2和r3的含义与前面定义的相同,R4代表烷基或苯基等,与式(2)的羟基化合物进行酯交换反应:R5Oh(2)其中r5的含义与前面定义的相同,在镧系金属烷氧化物的存在下进行.
专利信息
专利号:WO-2023102600-A1 优先权日:2021-12-06 标题:Synthesis of amphiphilic block copolymers and polymeric nanofibers produced therefrom 发明人:ZETTERLUND PER B; ISHIZUKA FUMI; KIM HYUN JIN; CHATANI SHUNSUKE; NIINO HIROSHI 权利人:NEWSOUTH INNOVATIONS PTY LTD 摘要:The present disclosure relates to the field of synthesis of block copolymers, and polymeric nanofibers having a core-shell morphology produced therefrom. The present disclosure relates to the field of synthesis of block copolymers where one block is more hydrophobic than the other block and is a different composition. The disclosure also relates to uses of these polymeric nanofibers in various applications, such as reinforcing a polymeric matrix and for coatings applications.
专利号:US-6512081-B1 优先权日:1997-07-21 标题:Synthesis of dithioester chain transfer agents and use of bis(thioacyl) disulfides or dithioesters as chain transfer agents 发明人:RIZZARDO ENZIO; THANG SAN HOA; MOAD GRAEME 权利人:E I DUPONT NEMOURS AND COMPANY; COMMW SCIENT IND RES ORG 摘要:This invention relates to the synthesis of dithiocarboxylic acid esters by reaction of bis(thioacyl) disulphides, thioacetals or vinylidane bis(thioether) with free-radicals (optionally in the presence of monomers). The invention also relates to processes for the synthesis of polymers utilising these dithioesters as polymerisation regulators (chain transfer agents) or to the use of bis(thioacyl) disulphides to generate dithioester chain transfer agents in situ.
专利号:US-11407993-B2 优先权日:2017-02-14 标 题 :Method for the synthesis of DNA conjugates by micellar catalysis 发明人:BHAT AVINASH SHASHIDHAR; KLIKA SKOPIC MATEJA; BRUNSCHWEIGER ANDREAS; WEBERSKIRCH RALF 权利人:UNIV DORTMUND TECH 摘要:A method for the synthesis of a chimeric conjugate molecule by micellar catalysis that may form part of DNA-encoded compound libraries. A DNA-coupled organic starter molecule may be reacted with another organic compound, using a catalyst located within a micelle, to form a conjugate of an organic candidate compound coupled to a DNA identifier tag.
专利号:EP-4428168-A1 优先权日:2023-03-08 标 题 :Polyurethane/oligomeric urethane synthesis method by radiation 发明人:AKBULUT HÜSEYIN; ÇEL KBA SENA; ENADA SEHER; U AKLI MÜGE; DEM RBAY DUYGU 权利人:CHT TURKEY KIMYA SANAYI VE TICARET A S 摘要:In particular, the invention relates to the synthesis of radiation-curable polyurethane/oligomeric urethane dispersions of anionic and cationic characters, containing neutralization techniques characterized by the selection of counter ions as monomers and/or agents which can be polymers acting as promoters under radiation, to a radiation polyurethane/oligomeric urethane synthesis method that enables the creation of radiation curable binder systems without using cosolvents, surfactants, emulsifiers, defoamers, stabilizers and additives, wherein all components of the radiation-curable binder systems can be polymerized.
专利号:US-10465033-B2 优先权日:2016-11-10 标题:One step synthesis of ultrahigh molecular weight block copolymers 发明人:URBAN MAREK W 权利人:UNIV CLEMSON; UNIV CLEMSON RES FOUNDATION 摘要:Single-step synthesis processes for production of ultrahigh molecular weight block copolymers are described. The ultrahigh molecular weight copolymers can have a molecular weight of about 10 6 or greater and can be formed within a few hours in a surfactant-free environment. The formation process is controlled by initiator-starvation conditions in a sequential polymerization of monomers exhibiting different solubility in the solvent.
专利号:US-6291620-B1 优先权日:1994-11-09 标 题:Polymer synthesis 发明人:MOAD GRAEME; MOAD CATHERINE LOUISE; KRSTINA JULIA; RIZZARDO EZIO; DARLING THOMAS ROBERT; BERGE CHARLES THOMAS 权利人:DU PONT; COMMW SCIENT IND RES ORG 摘要:Process for the synthesis of block polymers, homopolymers and copolymers of narrow polydispersity having formula (1) by contacting selected vinyl monomer(s), vinyl-terminated compound(s) and free radicals in which effective control of production of polymer is achieved by controlling the mole ratio of vinyl monomer(s), vinyl-terminated compound(s) and free radicals relative to one another; and polymers produced thereby
[参考文献]: Abed Abdel Qader, Et Al. Peptide Imprinted Receptors For The Determination Of The Small Cell Lung Cancer Associated Biomarker Progastrin Releasing Peptide. J Chromatogr A. 2014 Nov 28:1370:56-62. [参考文献]: Abhay Shankar Patra, Et Al. Selective Removal Of Toxic Anionic Dyes Using A Novel Nanocomposite Derived From Cationically Modified Guar Gum And Silica Nanoparticles. J Hazard Mater. 2016 Jan 15:301:127-36. [参考文献]: Adelene S M Wong, Et Al. Self-Assembling Dual Component Nanoparticles With Endosomal Escape Capability. Soft Matter. 2015 Apr 21;11(15):2993-3002. [参考文献]: Anchao Feng, Et Al. Co2-Breathing And Piercing Polymersomes As Tunable And Reversible Nanocarriers. Sci Rep. 2016 Mar 29:6:23624. [参考文献]: Diane C Forbes, Et Al. Polymeric Nanocarriers For Sirna Delivery To Murine Macrophages. Macromol Biosci. 2014 Aug;14(8):1096-105.
合成参考文献
摘要:Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure, Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982, -(51), 1982 摘要:USEPA/Pollution Prevention and Toxics; 2012 Chemical Data Reporting Database. 2-Propenoic acid, 2-methyl-, 2-(diethylamino)ethyl ester (105-16-8). Available from, as of August 31, 2015: 摘要:Kirk-Othmer Encyclopedia of Chemical Technology. 4th ed. Volumes 1: New York, NY. John Wiley and Sons, 1991-Present., p. V16 499 (1995) 摘要:Mill T; pp. 368 in Handbook of Property Estimation Methods for Chemicals. Boethling RS, Mackay D, eds. Boca Raton, FL: Lewis Publ (2000) 摘要:Franke C et al; Chemosphere 29: 1501-14 (1994)