CAS: 10203-28-8; 2-Dodecanol

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📜1-十二烯十二碳烯α-十二碳烯α-十二碳烯置于四氟硼酸-二乙醚络合物,C22H31Cl2Con2P体系中,用 四氢呋喃,二氯甲烷 用作溶剂,化学反应 44.17H,反应生成2-十二烷醇
参考文献:碱金属催化的区域发散性烯烃氢甲硅烷基化
标题:碱金属催化的区域发散性烯烃氢甲硅烷基化
摘要:已开发出一套互补的贱金属催化剂用于区域发散性的烯烃加氢甲硅烷基化:膦-亚氨基吡啶的铁配合物对反马氏化学氢化硅烷化具有选择性(线性/支链度最高> 99:1),而钴配合物则带有相同类型的配体提供前所未有的高水平的马尔可夫尼科夫选择性(分支/线性高达> 99:1).两种系统均显示出高效率和宽泛的官能团耐受性.
Doi:10.1002/anie.201601197

专利信息

专利号:US-6384228-B2
优先权日:1998-05-26
标题 :Method for synthesis of halopyridyl-azacyclopentane derivative and intermediate thereof
发明人：NODE MANABU; NAKAMURA DAISAKU; FUJIWARA TOSHIO; ICHIHASHI SHOGO
权利人:NIHON MEDIPHYSICS CO LTD
摘要:The present invention relates to a method for synthesis of an optically active halopyridyl-azacyclo-pentane derivative and the intermediate thereof which comprises preparing an optically active allene-1,3-dicarboxylic acid ester derivative from an optically active acetonedicarboxylic acid ester derivative and then proceeding through a 7-azabicyclo[2.2.1]heptane derivative to obtain the objective product.

专利号:WO-2017171674-A1
优先权日:2016-03-22
标题 :Synthesis of attractant of pistachio twig borer (kermania pistaciella)
发明人：ABDULKADIR SIRIT
权利人:ABDULKADIR SIRIT
摘要:The present invention relates to the stereoselective synthesis (2S,12Z)-2-acetoxy-12-heptadecene secreted by female pistachio twig borer and attract male individuals.

专利号:WO-2014108526-A1
优先权日:2013-01-11
标题 :Synthetic process for the manufacture of pipecolidepsin compounds
发明人：PELAY GIMENO MARTA; GARCÃ?A-RAMOS YESICA; TULLA PUCHE JUDIT; ALBERICIO PALOMERA FERNANDO; MARTÃ?N LÓPEZ M JES S
权利人:PHARMA MAR SA
摘要:(I) wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 , R 12 , n and Y are as described. The invention provides a process for the synthesis of complex pipecolidepsin and related compounds of formula (I), opening a new field of compounds with useful biological properties. The invention also provides intermediates, useful in the synthesis of compounds of formula (I).

专利号:US-2007082039-A1
优先权日:2004-10-18
标题 :Synthesis of fatty alcohol esters of alpha-hydroxy carboxylic acids, the use of the same as percutaneous permeation enhancers, and topical gels for the transdermal delivery of steroids
发明人：JONES GERALD S JR; ST LAURENT JOSEPH P; GOODRICH SCOTT A
权利人:JONES GERALD S JR; ST LAURENT JOSEPH P; GOODRICH SCOTT A
摘要:The present invention provides a novel approach for the preparation of fatty alcohol esters of α-hydroxy carboxylic acids. The present invention also provides a novel topical gel for the transdermal delivery of steroids using the fatty alcohol esters as permeation enhancers.

专利号:US-6011171-A
优先权日:1996-08-14
标 题 :Process for synthesis of tertiary carboxylic acids and the esters thereof
发明人：XU QIANG; SOUMA YOSHIE
权利人:JIRO HIRAISHI DIRECTOR GENERAL
摘要:The present invention provides a process for synthesizing tertiary carboxylic acids or the esters thereof having one or two more carbon atoms than the raw material has, comprising reacting in a strong acid (e.g., sulfuric acid, sulfuric acid-phosphoric acid, hydrogen fluoride, fluorosulfuric acid, boron trifluoride.water complex and trifluoromethanesulfonic acid) a raw material compound (i.e., olefin, alcohol, diene, diol or saturated hydrocarbon) with carbon monoxide in the presence of a specific metal carbonyl catalyst (i.e., platinum carbonyl catalyst, palladium carbonyl catalyst and gold dicarbonyl catalyst). The metal carbonyl catalyst is formed by reacting in a strong acid at least one specific metal compounds (e.g., platinum compound such as platinum (II, IV) oxide, platinum (II, IV) hydroxide, a platinum powder, etc.; palladium compound such as palladium (II, III, IV) oxide, palladium (II) hydroxide, palladium (II) sulfate, palladium (II) carboxylate, a palladium powder, etc.; and gold compound such as gold (I, III) oxide, gold (I, III) hydroxide, a gold powder, etc.) with carbon monoxide.

专利号:US-8936922-B2
优先权日:2004-10-18
标题 :Synthesis of fatty alcohol esters of alpha-hydroxy carboxylic acids and their use as percutaneous absorption enhancers
发明人：JONES JR GERALD S; GOODRICH SCOTT A; ST LAURENT JOSEPH P
权利人:JONES JR GERALD S; GOODRICH SCOTT A; ST LAURENT JOSEPH P; CHEMSMART LLC
摘要:The present invention provides a novel approach for the preparation of fatty alcohol esters of α-hydroxy carboxylic acids. In one form of the invention, the target fatty alcohol ester of α-hydroxy carboxylic acid is produced by converting a lower alkyl ester of α-hydroxy carboxylic acid into a fatty alcohol ester of α-hydroxy carboxylic acid via alcoholysis (i.e., transesterification). The transesterification process is an equilibrium reaction, catalyzed chemically (i.e., with acids or bases) or enzymatically, that is shifted in the desired direction to produce the desired product. One way of shifting the reaction in the direction of the desired product is by reducing the concentration of one of the products (e.g., distillation of a lower-boiling alcohol as it is formed). Another preferred way of shifting the reaction in the direction of the desired product is by increasing the concentration of one of the reactants.