CAS: 826-74-4; 1-Vinylnaphthalene

该化合物是一种高纯度单体,主要用于聚合反应和特殊化学合成.添加tet-Butylcatchol作为抑制剂,通过防止过早聚合,确保储存和处理过程中的稳定性.该化合物在生产先进的聚合物,树脂和功能性材料方面特别宝贵,因为它的活性乙烯组和丙烯脊椎有助于增强衍生产品的热性和机械性.规定的抑制剂浓度(4,000ppm)在储存寿命和再活性之间提供了最佳平衡,使之适合实验室和工业用途,要求对聚合动力学进行精确控制.

英文名称1-Vinylnaphthalene
中文名称1-乙烯萘酯
IUPAC名称1-vinylnaphthalene
其它别名1-萘乙烯; Naphthalene, 1-Ethenyl-
CAS编号826-74-4
MFCD编号:MFCD00075766
EINECS号:212-560-5
分子式:C12H10
分子量:154.21
产品CID: 1816898
产品分类有机原料→分子砌块→芳环类化合物→萘类化合物

相似结构搜索
InChIKey: IGGDKDTUCAWDAN-UHFFFAOYSA-N
InChI=1S/C12H10/c1-2-10-7-5-8-11-6-3-4-9-12(10)11/h2-9H,1H2…
计算化学: 氢键受体数0.0氢键供体数0.0可旋转键数1.0

相似化合物

827-54-3 2489-86-3 3710-23-4

物理性质

熔点322 °C
沸点135-138°C at 760 mmHg
闪点101°C
密度1.0±0.1 g/cm3
PSA:0.0
LogP:3.4828
折射率1.657
蒸汽压0.0±0.3 mmHg at 25°C
溶解性Soluble In Ethyl Acetate, Hexane And Methanol.
敏感性易受潮
外观形态无色至橙色油状物
储存条件-20°C
产品应用该化合物用于基质材料,生产以氮化为基础的产品.

MSDS等安全信息

GHS象形图
GHS符号GHS07 & GHS09;
注释: Exclamation mark & Environment
危险类别急性毒性类别4(经口)
特定目标器官毒性 - 单次接触类别3
皮肤腐蚀/刺激类别2
严重眼刺激类别2
水生慢性毒性类别2
致癌性类别2
皮肤致敏类别1
水生慢性毒性类别3
警示词Warning(警告)
危险描述H302 |吞咽有害.
H335 |可能引起呼吸道刺激.
H315 |造成皮肤刺激.
H319 |造成严重眼刺激.
H411 |对水生生物有毒并具有长期持续影响.
H351 |怀疑致癌.
H317 |可能引起皮肤过敏反应.
H412 |对水生生物有害并具有长期持续影响.
防范说明P261-P264-P270-P271-P272-P273-P280-P302+P352-P304+P340-P330-P362+P364-P391-P405-P501
危险等级9
UN编号3082.0
危险品标志Xi,N,Xn
包装等级Ⅲ
安全声明26-36-61
危险类别码36/37/38-51/53-22
WGK Germany2

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

tetrachloromethane N-Bromosuccinimide 1-ethylnapthelene 2-naphthaleneethanol r,3bξ,11ac)-3a,3b,11,11a-tetrahydro-phenanthro[1,2-c]furan-1,3-dione(+/-)-(3ar,3bξ,11ac)-3a,3b,11,11a-tetrahydro-phenanthro[1,2-c]furan-1,3-dione 5,6-Dioxo-5,6-dihydro-picen 2-(1-naphthyl)oxirane 1-ethylnapthelene

合成工艺路线路线简述

合成目标产物 1-Vinylnaphthalene 主要起始原料 1-Naphthaleneethanol
1779-49-3 + 66-77-3 = 826-74-4
反应条件:1.1 Reagents: Potassium Tert-Butoxide Solvents: Toluene; 30 Min,0 °C; 4 H,Rt1.2 Overnight,Rt
标题:Diselenide- And Disulfide-Mediated Synthesis Of Isocoumarins
作者:Shahzad,Sohail A.; Et Al
参考文献:European Journal Of Organic Chemistry 日期:2010 卷标:(18) 页码:3465-3472]

1779-49-3 + 66-77-3 = 826-74-4
反应条件:1.1 Reagents: Potassium Tert-Butoxide Solvents: Toluene; 30 Min,0 °C; 4 H,Rt; Rt -> 0 °C1.2 Overnight,Rt
标题:Selenium-Mediated Synthesis Of Biaryls Through Rearrangement
作者:Shahzad,Sohail A.; Et Al
参考文献:Organic Letters 日期:2010 卷标:12(6) 页码:1364-1367]

773-99-9 = 826-74-4 [标题:Reaction Conditions
标题:Reactions With Nitrosodisulfonate. Xx. Chrysene-3,6-Quinone And Dinaphthoanthraquinone
作者:Teuber,Hans Joachim; Et Al
参考文献:Chemische Berichte 日期:1959 卷标:92 页码:921-6]

773-99-9 = 826-74-4
反应条件:1.1 Reagents: Thionyl Chloride2.1 Catalysts: Potassium Tert-Butoxide
标题:A Practical Large-Scale Synthesis Of (1-Naphthyl)Acetylene
作者:Hanekamp,Jaap C.; Et Al
参考文献:Synthetic Communications 日期:1989 卷标:19(15) 页码:2677-82]

83813-73-4 + 13922-41-3 = 826-74-4
反应条件:1.1 Reagents: Potassium Carbonate Catalysts: Disodium Tetrachloropalladate,9H-Fluorene-2-Sulfonic Acid,9-(Dicyclohexylphosphino)-9-[3-(4-Sulfophenyl)Propy... Solvents: Water; 3 H,45 °C1.2 Reagents: Potassium Carbonate Solvents: Water; 16 H,95 °C
标题:Retracted Article: Cross Coupling In Water: Suzuki-Miyaura Vinylation And Difluorovinylation Of Arylboronic Acids
作者:Pschierer,Jan; Et Al
参考文献:Green Chemistry 日期:2010 卷标:12(4) 页码:636-642]

2768-02-7 = 826-74-4
反应条件:1.1 Reagents: Tetrabutylammonium Bromide Catalysts: Di-μ-Chlorobis[5-Hydroxy-2-[1-(Hydroxyimino-Kn)Ethyl]Phenyl-Kc]Dipalladium Solvents: Water; 5 Min,Rt1.2 Reagents: Sodium Hydroxide Solvents: Water; Rt; Rt -> 120 °C; 24 H,120 °C; 120 °C -> Rt
标题:The First Fluoride-Free Hiyama Reaction Of Vinylsiloxanes Promoted By Sodium Hydroxide In Water
作者:Alacid,Emilio; Et Al
参考文献:Advanced Synthesis & Catalysis 日期:2006 卷标:348(15) 页码:2085-2091]

2768-02-7 = 826-74-4
反应条件:1.1 Reagents: Sodium Hydroxide,Tetrabutylammonium Bromide Catalysts: Di-μ-Chlorobis[5-Hydroxy-2-[1-(Hydroxyimino-Kn)Ethyl]Phenyl-Kc]Dipalladium Solvents: Water; 20 Min,120 °C
标题:Aqueous Sodium Hydroxide Promoted Cross-Coupling Reactions Of Alkenyltrialkoxysilanes Under Ligand-Free Conditions
作者:Alacid,Emilio; Et Al
参考文献:Journal Of Organic Chemistry 日期:2008 卷标:73(6) 页码:2315-2322]

= 826-74-4
反应条件:1.1 Catalysts: Dichlorobis(Triphenylphosphine)Palladium Solvents: Tetrahydrofuran; 12 H,60 °C
标题:Pd-Catalyzed Cross-Coupling Of Haloarenes And Chloroarene-Cr(Co)3 Complexes With Stabilized Vinyl- And Allylaluminium Reagents
作者:Schumann,Herbert; Et Al
参考文献:Synlett 日期:2003 卷标:(12) 页码:1783-1788]

754-05-2 + 90-14-2 = 826-74-4
反应条件:1.1 Reagents: Triethyl Phosphite,Sulfiliminium,S,S-Bis(Diethylamino)-N,N-Diethyl-,Difluorotrimethylsilicate(1-)... Catalysts: Di-μ-Chlorobis(η3-2-Propenyl)Dipalladium Solvents: Hexamethylphosphoramide
标题:Cross-Coupling Of Organosilanes With Organic Halides Mediated By A Palladium Catalyst And Tris(Diethylamino)Sulfonium Difluorotrimethylsilicate
作者:Hatanaka,Yasuo; Et Al
参考文献:Journal Of Organic Chemistry 日期:1988 卷标:53(4) 页码:918-20]

90-14-2 = 826-74-4
反应条件:1.1 Reagents: Silver Oxide (Ag2O) Catalysts: Tetrakis(Triphenylphosphine)Palladium Solvents: Tetrahydrofuran; 24 H,67 °C
标题:4,4,6-Trimethyl-2-Vinyl-1,3,2-Dioxaborinane: An Efficient And Selective 2-Carbon Building Block For Vinylboronate Suzuki-Miyaura Coupling Reactions
作者:Lightfoot,Andrew P.; Et Al
参考文献:Synlett 日期:2005 卷标:(3) 页码:529-531]

2768-02-7 + 90-14-2 = 826-74-4
反应条件:1.1 Reagents: Sodium Hydroxide,Tetrabutylammonium Bromide Catalysts: Di-μ-Chlorobis[5-Hydroxy-2-[1-(Hydroxyimino-Kn)Ethyl]Phenyl-Kc]Dipalladium Solvents: Water; 10 Min,120 °C
标题:Aqueous Sodium Hydroxide Promoted Cross-Coupling Reactions Of Alkenyltrialkoxysilanes Under Ligand-Free Conditions
作者:Alacid,Emilio; Et Al
参考文献:Journal Of Organic Chemistry 日期:2008 卷标:73(6) 页码:2315-2322]

67-71-0 + 4780-79-4 = 826-74-4
反应条件:1.1 Reagents: Potassium Tert-Butoxide Catalysts: 1,10-Phenanthroline,Ferrous Chloride Solvents: Toluene; 8 H,120 °C
标题:Iron-Catalyzed Direct Julia-Type Olefination Of Alcohols
作者:Landge,Vinod G.; Et Al
参考文献:Journal Of Organic Chemistry 日期:2020 卷标:85(15) 页码:9876-9886]

7486-35-3 = 826-74-4
反应条件:1.1 Catalysts: Tri-Tert-Butylphosphine,Tris(Dibenzylideneacetone)Dipalladium Solvents: Toluene
标题:Pd/p(T-Bu)3: A Mild And General Catalyst For Stille Reactions Of Aryl Chlorides And Aryl Bromides
作者:Littke,Adam F.; Et Al
参考文献:Journal Of The American Chemical Society 日期:2002 卷标:124(22) 页码:6343-6348]

13682-77-4 = 826-74-4
反应条件:1.1 Reagents: Cesium Carbonate Catalysts: (-)-Binap,Di-μ-Chlorobis[5-Hydroxy-2-[1-(Hydroxyimino-Kn)Ethyl]Phenyl-Kc]Dipalladium Solvents: Dimethylformamide; 20 H,120 °C; 120 °C -> Rt
标题:General Reaction Conditions For The Palladium-Catalyzed Vinylation Of Aryl Chlorides With Potassium Alkenyltrifluoroborates
作者:Alacid,Emilio; Et Al
参考文献:Journal Of Organic Chemistry 日期:2009 卷标:74(21) 页码:8191-8195]

106-93-4 + 13922-41-3 = 826-74-4
反应条件:1.1 Reagents: Potassium Hydroxide Solvents: Tetrahydrofuran; 1 H,100 °C; 100 °C -> Rt1.2 Catalysts: Triphenylphosphine,Palladium Diacetate Solvents: Methanol; 1 H,100 °C; 100 °C -> Rt
标题:Simple And Efficient Protocol For The Synthesis Of Functionalized Styrenes From 1,2-Dibromoethane And Arylboronic Acids
作者:Lando,Vanusa R.; Et Al
参考文献:Organic Letters 日期:2003 卷标:5(16) 页码:2891-2894]

15727-65-8 = 826-74-4
反应条件:1.1 Reagents: Hydrogen Catalysts: Iron Oxide (Inorganic Oxide Supported) Solvents: Mesitylene; 20 H,10 Bar,100 °C
标题:Synthesis Of Supported Planar Iron Oxide Nanoparticles And Their Chemo- And Stereoselectivity For Hydrogenation Of Alkynes
作者:Tejeda-Serrano,Maria; Et Al
参考文献:Acs Catalysis 日期:2017 卷标:7(5) 页码:3721-3729]

1779-49-3 + 66-77-3 = 826-74-4
反应条件:1.1 Reagents: Potassium Tert-Butoxide Solvents: Toluene; 30 Min,0 °C; 4 H,Rt; Rt -> 0 °C1.2 Overnight,Rt
标题:Novel Cyclization Cascades To Functionalized Indanes And Tetrahydronaphthalenes
作者:Khan,Zulfiqar A.; Et Al
参考文献:Tetrahedron 日期:2010 卷标:66(33) 页码:6639-6646]

121825-35-2 = 826-74-4
反应条件:1.1 Catalysts: 1637333-83-5 Solvents: Tetrahydrofuran; 5 H,50 °C
标题:Synthesis,Mechanism Of Formation,And Catalytic Activity Of Xantphos Nickel π-Complexes
作者:Staudaher,Nicholas D.; Et Al
参考文献:Chemical Communications (Cambridge 日期:2014 卷标:50(98) 页码:15577-15580]

13922-41-3 + 63918-53-6 = 826-74-4
反应条件:1.1 Reagents: Potassium Carbonate Catalysts: Disodium Tetrachloropalladate,9H-Fluorene-2-Sulfonic Acid,9-(Dicyclohexylphosphino)-9-[3-(4-Sulfophenyl)Propy... Solvents: Water; 3 H,45 °C1.2 Reagents: Potassium Carbonate Solvents: Water; 16 H,95 °C
标题:Retracted Article: Cross Coupling In Water: Suzuki-Miyaura Vinylation And Difluorovinylation Of Arylboronic Acids
作者:Pschierer,Jan; Et Al
参考文献:Green Chemistry 日期:2010 卷标:12(4) 页码:636-642]

1517-72-2 = 826-74-4
反应条件:1.1 Reagents: Oxalyl Chloride Solvents: Dimethylformamide; 0 °C; 52 H,95 °C
标题:"Conducted Tour" Migration Of Li+ During The Cis/trans Stereoinversion Of α-Arylvinyllithiums
作者:Knorr,Rudolf; Et Al
参考文献:Chemistry - A European Journal 日期:2017 卷标:23(52) 页码:12861-12869]

1517-72-2 = 826-74-4
反应条件:1.1 Reagents: Alumina
标题:The Kinetics Of Polymerization Of 1-Vinylnaphthalene
作者:Loshaek,S.; Et Al
参考文献:Journal Of Polymer Science 日期:1959 卷标:39 页码:223-39]

754-05-2 + 90-14-2 = 826-74-4
反应条件:1.1 Reagents: Tetrabutylammonium Chloride,Potassium Fluoride Catalysts: Bis(Dibenzylideneacetone)Palladium Solvents: Toluene
标题:Tetraalkylammonium Salt-Based Catalyst Systems For Directing The Arylation Of Vinyltrimethylsilane
作者:Jeffery,Tuyet
参考文献:Tetrahedron Letters 日期:1999 卷标:40(9) 页码:1673-1676]

754-05-2 + 90-14-2 = 826-74-4
反应条件:1.1 Catalysts: Di-μ-Chlorobis(η3-2-Propenyl)Dipalladium Solvents: Dimethylformamide
标题:The Electrophilic Substitution Of Allylsilanes And Vinylsilanes
作者:Fleming,Ian; Et Al
参考文献:Organic Reactions (Hoboken 日期:1989 卷标:37]

77295-63-7 = 826-74-4
反应条件:1.1 Reagents: Samarium Solvents: Methanol; 6 H,45 °C
标题:Unexpected Chemoselective Debromination And Reduction Of 1,1-Dibromo-1-Alkenes Mediated By Samarium Metal In Methanol
作者:Wang,Lei; Et Al
参考文献:Synlett 日期:2003 卷标:(8) 页码:1137-1140]

66-77-3 = 826-74-4
反应条件:1.1 Solvents: Tetrahydrofuran; 3 H,25 °C
标题:Isolation And Structural Characterization Of Geminal Di(Iodozincio)Methane Complexes Stabilized With Nitrogen Ligands
作者:Nishida,Yusuke; Et Al
参考文献:Journal Of The American Chemical Society 日期:2015 卷标:137(1) 页码:114-117]

43245-19-8 + 90-14-2 = 826-74-4
反应条件:1.1 Catalysts: Tetrakis(Triphenylphosphine)Palladium Solvents: Tetrahydrofuran; 60 °C1.2 Reagents: Sodium Bicarbonate Solvents: Water
标题:Tetraorganoindates As Nucleophilic Coupling Partners In Pd-Catalyzed Cross-Coupling Reactions
作者:Lee,Phil Ho; Et Al
参考文献:Organic Letters 日期:2003 卷标:5(26) 页码:4963-4966]

67-71-0 + 4780-79-4 = 826-74-4
反应条件:1.1 Reagents: Potassium Tert-Butoxide Catalysts: Platinum Solvents: Toluene; 15 H,Reflux
标题:Direct Olefination Of Alcohols With Sulfones By Using Heterogeneous Platinum Catalysts
作者:Siddiki,S. M. A. Hakim; Et Al
参考文献:Chemistry - A European Journal 日期:2016 卷标:22(17) 页码:6111-6119]

67-71-0 + 4780-79-4 = 826-74-4
反应条件:1.1 Reagents: Potassium Tert-Butoxide Catalysts: Ruthenium,Carbonylchloro[6-[(Diphenylphosphino-Kp)Methyl]-2,2′-Bipyridine-Kn1,K... Solvents: 1,4-Dioxane; 5 H,125 °C
标题:Direct Catalytic Olefination Of Alcohols With Sulfones
作者:Srimani,Dipankar; Et Al
参考文献:Angewandte Chemie 日期:2014 卷标:53(41) 页码:11092-11095]

7486-35-3 = 826-74-4 [标题:Reaction Conditions
标题:Product Class 3: Bromoarenes
作者:Stanforth,S. P.
参考文献:Science Of Synthesis 日期:2007 卷标:31 页码:121-160]

7486-35-3 = 826-74-4
反应条件:1.1 Reagents: Lithium Chloride Catalysts: Dichlorobis(Triphenylphosphine)Palladium Solvents: Dimethylformamide
标题:The Stille Reaction
作者:Farina,Vittorio; Et Al
参考文献:Organic Reactions (Hoboken 日期:1997 卷标:50]

7486-35-3 = 826-74-4
反应条件:1.1 Reagents: Lithium Chloride Catalysts: Dichlorobis(Triphenylphosphine)Palladium Solvents: Dimethylformamide
标题:Palladium Cross-Coupling Reactions Of Aryl Fluorosulfonates: An Alternative To Triflate Chemistry
作者:Roth,Gregory P.; Et Al
参考文献:Journal Of Organic Chemistry 日期:1991 卷标:56(11) 页码:3493-6

2-(1-Naphthyl)-Aziridin置于dinitrogen Tetraoxide,三乙胺体系中,用四氢呋喃作为反应溶剂,化学反应 0.17H,以82%的收率获得产物1-乙烯萘
参考文献:A Facile Deamination Of Aziridines Using N2O4Under Very Mild Conditions
标题:A Facile Deamination Of Aziridines Using N2O4Under Very Mild Conditions
摘要:Various Aziridines Reacted With N2O4 (2 Eq) In The Presence Of Et3N (1 Or 2 Eq) In Dry Thf To Give The Corresponding Ethylenes In Good To Excellent Yields At (-23 Degrees C Or-43 Degrees C) In 10 Min Under Ar.
DOI:10.1080/00397919908086096