CAS: 699-08-1; 1-Ethoxy-4-Iodobenzene

上下游产品

CAS号103-73-1 苯乙醚 | CAS号74-96-4 溴乙烷 | CAS号540-38-5 4-碘苯酚 | CAS号87261-58-3 1-((4-ethoxyphe... | CAS号64-17-5 乙醇 | CAS号589-87-7 对溴碘苯 | CAS号75-03-6 碘乙烷 | CAS号156-43-4 对氨基苯乙醚 | CAS号110-86-1 吡啶 | CAS号7553-56-2 碘 | CAS号79887-14-2 乙氧基苯乙炔 | CAS号23197-69-5 DIETHYL 4-ETHOX... | CAS号7168-54-9 4,4'-二乙氧基联苯 | CAS号613-40-1 1-ethoxy-4-phen... | CAS号16029-98-4 三甲基碘硅烷 | CAS号107-46-0 六甲基二硅氧烷 | CAS号5459-40-5 4-乙氧基苯乙烯 | CAS号106-99-0 丁二烯 | CAS号760150-51-4 4-(4-乙氧基苯基)哌啶盐酸盐 | CAS号65629-84-7 (4-ethoxyphenyl...

📜苯乙醚置于iron(Iii) Nitrate Nonahydrate,二氧化碳,碘,氧气体系中,用 乙二醇 作为反应溶剂,100.0 °C,1.2 Mpa 条件下,反应 10.0H,以85%的收率获得产物4-碘苯乙醚
参考文献:An In Situ Acidic Carbon Dioxide/glycol System For Aerobic Oxidative Iodination Of Electron-Rich Aromatics Catalyzed By Fe(No3)3.9H2O
标题:An In Situ Acidic Carbon Dioxide/glycol System For Aerobic Oxidative Iodination Of Electron-Rich Aromatics Catalyzed By Fe(No3)3.9H2O
摘要:开发了一种环境友好的 Co2/乙二醇可逆酸性系统,用于在富电子芳香化合物上进行铁(Iii)催化的空气氧化碘化反应,无需任何常规酸添加剂或有机溶剂.值得注意的是,当使用无水硝酸铁作为催化剂,分子碘在 1 Mpa 的 Co2 下进行反应时,获得了中等至高分离产率的碘代芳烃(高达 97%),并且具有相当的区域选择性.
DOI:10.1039/c4Cy00721B

专利信息

专利号:US-2006287529-A1
优先权日:2003-02-20
标 题:Solid phase synthesis of antitumoral compounds
发明人：ALVAREZ MERCEDES; ALBERICIO FERNANDO; CIRONI PABLO; CUE VAS CARMEN; FRANCESCH ANDREAS; MARFIL MARTA
权利人:ALVAREZ MERCEDES; ALBERICIO FERNANDO; CIRONI PABLO; CUE VAS CARMEN; FRANCESCH ANDREAS; MARFIL MARTA
摘要:Lamellarins are prepared using a solid phase synthesis. In a first aspect, the process includes a step as follows: Formula (I) where R 1 to R 15 are as defined, and X is halogen, provided that one of R 2 , R 3 or R 4 is immobilised to a resin. In a second aspect, the process includes a step as follows: Formula (II) where R 1 ′ to R 5 ′, R 11 ′ and R 13 ′ are as defined, X 1 and X 2 are halogen, M is a metal function and PG is an amino protecting group, provided that one of that R 2 ′, R 3 ′ or R 4 ′ is immobilised to a resin.

专利号:US-10865163-B2
优先权日:2017-12-20
标题:Carbon dioxide as a directing group for C—H functionalization reactions involving Lewis basic amines, alcohols, thiols, and phosphines for the synthesis of compounds
发明人：YOUNG MICHAEL C; KAPOOR MOHIT
权利人:UNIV TOLEDO
摘要:Methods of synthesizing compounds using CO 2 as a directing group for C—H functionalization, and compounds made thereby, are described.

专利号:US-7884125-B2
优先权日:2008-04-30
标 题:Straightforward entry to 7-azabicyclo[2.2.1]heptane-1-carbonitriles and subsequent synthesis of epibatidine analogues
发明人：STEVENS CHRISTIAN; HEUGEBAERT THOMAS
权利人:UNIV GENT
摘要:The present invention relates to a group of substituted-7-azabicyclo-[2.2.1]heptyl derivatives with biological activity. The present invention also relates to synthetic methods for producing said substituted-7-azabicyclo-[2.2.1]heptyl derivatives. The present invention also relates to certain intermediates for producing such substituted-7-azabicyclo-[2.2.1]heptyl derivatives, as well as a synthetic method for producing such intermediates. The present invention also relates to pharmaceutical compositions comprising such substituted-7-azabicyclo-[2.2.1]heptyl derivatives, as well as their use as medicaments for the treatment of diseases mediated by a Nicotinic Acetylcholine Receptor or a receptor being a member of the Neurotransmitter-gated Ion Channel Superfamily, such as pain, Alzheimer's disease, Parkinson's disease, schizophrenia, epilepsy and nicotine addiction.

专利号:US-2019185392-A1
优先权日:2017-12-20
标 题 :Carbon Dioxide as a Directing Group for C-H Functionalization Reactions Involving Lewis Basic Amines, Alcohols, Thiols, and Phosphines for the Synthesis of Compounds

专利号:US-2009275616-A1
优先权日:2008-04-30
标 题 :Straightforward entry to 7-azabicyclo[2.2.1]heptane-1-carbonitriles and subsequent synthesis of epibatidine analogues

专利号:CN-106588788-B
优先权日:2016-11-11
标 题 :The method of one pot of two-step method synthesis 1,2,3- triazole compound