CAS: 5112-23-2; 3-(2,4,6-Trichlorophenoxy)Propane-1,2-Diol

上下游产品

3-mon°Chloro-1,2-propanediol 2,4,6-Trichlorophenol 1-acetoxy-3-(2,4,6-trichlorophenoxy)propan-2-ol 1-acetoxy-3-(2,4,6-trichlorophenoxy)propan-2-one

📜3-氯-1,2-丙二醇,2,4,6-三氯苯酚置于sodium Hydroxide体系中,用 乙醇 作为反应溶剂,化学反应 2.0H,以99%的收率获得产物3-(2,4,6-三氯苯氧基)丙烷-1,2-二醇
参考文献:Baker'S Yeast Mediated Stereoselective Biotransformation Of 1-Acetoxy-3-Aryloxypropan-2-Ones
标题:Baker'S Yeast Mediated Stereoselective Biotransformation Of 1-Acetoxy-3-Aryloxypropan-2-Ones
摘要:A Series Of 1-Acetoxy-3-Aryloxypropan-2-Ones La-M Were Synthesized And Subjected To Biotransformation By Baker'S Yeast Yielding Optically Active Monoacetates 5 Or Ent-5 And/or Diols 4 Of Moderate To Excellent Enantiomeric Purity. The Dependence Of The Reduction/hydrolysis Ratio And Stereoselectivity On The Size And Substitution Pattern Of The Aromatic Moiety In The Substrate Is Also Discussed. (C) 1998 Elsevier Science Ltd. All Rights Reserved.
DOI:10.1016/s0957-4166(97)00626-5