1-己基-3-甲基溴化咪唑翁置于盐酸体系中,用 丙酮 用作溶剂,化学反应 10.0H,反应生成1-己基-3-甲基咪唑氯化物 参考文献:Various Metal Organic Frameworks Combined With Imidazolium,Quinolinum And Benzothiazolium Ionic Liquids For Removal Of Three Antibiotics From Water 标题:Various Metal Organic Frameworks Combined With Imidazolium,Quinolinum And Benzothiazolium Ionic Liquids For Removal Of Three Antibiotics From Water 摘要:In This Research,Imidazolium,Quinolinum And Benzothiazolium Based Ionic Liquids (Ils) Were Immobilized On A Metal Organic Framework (Mof) By Solvent Impregnation Or Capillary Action. The Synthesized Il@mof Composite Materials Were Characterized By Ftir,Xrd,Sem And Tga Methods And Then Applied In Removal Of Tetracyclines (Tcs) From Aqueous Samples. The Presence Of Ionic Liquids Significantly Improved The Adsorption Efficiency Of The Metal Organic Framework,With 82% Or Higher Removal Percentage Was Obtained For The Three Target Tcs While The Pristine Mob Adsorption Efficiency Was Below 50%. This Could Be Attributed To The Ability Of Ils To Make Complex Interaction With Target Drugs Via Multiple Intermolecular Forces. Experimental Results Revealed The Effects Of Three Significant Factors Including Ph,Temperature And Solid-Liquid Ratio,And Optimum Adsorption Efficiency Could Be Achieved At Ph 8 And 30 Degrees C When Solid-Liquid Ratio 1:2 Was Adopted. The Adsorption Kinetics Was Properly Fitted With Pseudo-Second Order Model And Redlich-Peterson Model Could Be Used To Describe The Adsorption Isotherm For Three Antibiotics; Moreover,The Adsorption Was An Endothermic And Spontaneous Process In Nature. Finally,The Adsorbed Tcs Could Be Desorbed Efficiently And The Performance Of The Il@mof Sorbent Was Further Verified By Actual Water Samples. (C) 2020 Published By Elsevier B.V. Doi:10.1016/j.Molliq.2020.114304
专利号:US-7927516-B2 优先权日:2004-09-20 标题 :Method for synthesis of colloidal nanoparticles 发明人:STROUSE GEOFFREY F; GERBEC JEFFREY A; MAGANA DONNY 权利人:UNIV CALIFORNIA 摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.
专利号:US-2010191010-A1 优先权日:2007-07-02 标题 :Process for the synthesis of carbamates using co2 发明人:BOSMAN JORIS KAREL PETER; CARR ROBERT HENRY 权利人:HUNTSMAN INT LLC 摘要:Process for the synthesis of non cyclic carbamate derivatives from amine compounds, alcohols and CO 2 in the presence of ionic liquids and optionally in the presence of a base.
专利号:US-2023106492-A1 优先权日:2020-02-28 标题:Synthesis of drag reducing latex product using cationic surfactants in emulsion polymerization 发明人:MALLAVAJULA RAJESH K 权利人:LIQUIDPOWER SPECIALTY PRODUCTS INC 摘要:A drag reducing composition, methods of forming a drag reducing composition, and methods of using a drag reducing composition to reduce the pressure drop of a liquid hydrocarbon through a conduit are provided. The drag reducing composition includes a latex polymer, a cationic surfactant, optionally a nonionic surfactant, and a continuous phase. The cationic surfactant is selected from quaternary ammonium-based cationic surfactants, imidazolium-based cationic surfactants, pyridinium-based cationic surfactants, or a combination thereof.
专利号:US-9126848-B2 优先权日:2009-12-29 标题:Synthesis of nanoparticles by means of ionic liquids 发明人:DE OLIVEIRA PETER WILLIAM; LIN HECHUN; VEITH MICHAEL 权利人:DE OLIVEIRA PETER WILLIAM; LIN HECHUN; VEITH MICHAEL; LEIBNIZ INSITUT FUER NEUE MATERIALIEN GEMEINNUETZIGE GMBH 摘要:A method for producing nanoscale particles by means of ionic liquids produces highly crystalline particles. The ionic liquids can be easily regenerated.
专利号:US-2007100184-A1 优先权日:2005-10-27 标题 :Alkylation of aromatic compounds 发明人:HARMER MARK A; JUNK CHRISTOPHER P; VICKERY JEMMA 权利人:HARMER MARK A; JUNK CHRISTOPHER P; VICKERY JEMMA 摘要:The present invention relates to the synthesis of alkylated aromatic compounds using ionic liquids as the solvent. Alkylated aromatic compounds are synthesized by reacting an aromatic compound with a monoolefin in the presence of an acid catalyst.
专利号:US-6939974-B2 优先权日:2000-04-07 标 题:Imidazole carbenes 发明人:EARLE JOHN MARTYN; SEDDON RICHARD KENNETH 权利人:UNIV BELFAST 摘要:The disclosure herein relates to imidazole carbenes and imidazole carbene salts. The disclosure also relates to the synthesis of imidazole carbenes and imidazole carbene salts. The imidazole carbenes disclosed include those synthesized by reacting an imidazole halide with a base under reduced pressure. The imidazole carbene salts disclosed include those synthesized by reaction of imidazole carbenes with an acid or alcohol suitable for creation of a salt. The disclosure also relates to the use of imidazole carbenes and imidazole carbene salts for the synthesis of organic liquids.
参考标题:The One-Pot Synthesis Of Butyl-1H-Indol-3-Alkylcarboxylic Acid Derivatives In Ionic Liquid As Potent Dual-Acting Agent For Management Of Bph 作者:Li-Yan Zeng,Fubiao Yang,Kaixuan Chen,Yunong Zeng,Zhenzhou Jiang,Shuwen Liu,Baomin Xi |发布日期:2020.11 摘要:H-Indol-3-Yl)Butanoic Acid 4Aaa Was Designed Against Bph And Synthesized By Two Steps Of N-Alkylation. One-Pot Protocol Towards 4Aaa Was Newly Developed. With Il [c6Min]Br As Solvent, The Yield Of 4Aaa Was Increased To 75.1 % From 16.0 % And The Reaction Time Was Shortened In 1.5 Hours From 48 Hours. 25 Derivatives Structurally Based On Arylpiperazine And Indolyl Butyric Acid With Alkyl Linker Were
合成参考文献
参考文献:10.1007/s00216-015-9098-z 摘要:Cacho JI, Campillo N, Viñas P, Hernández-Córdoba M. In situ ionic liquid dispersive liquid–liquid microextraction and direct microvial insert thermal desorption for gas chromatographic determination of bisphenol compounds. Analytical and Bioanalytical Chemistry. 2015 Oct 17;408(1):243–9. doi: 10.1007/s00216-015-9098-z.