CAS: 732276-63-0; 11-(Bromomethyl)Tricosane

2-癸基-1-十四醇置于四溴化碳,三苯基膦体系中,用 四氢呋喃 作为反应溶剂,化学反应 0.5H,反应生成 2-癸基-1-十四烷基溴
参考文献:带有小抗衡离子的萘功能化,光致发光室温离子液体
标题:带有小抗衡离子的萘功能化,光致发光室温离子液体
摘要:由于π部分之间相对强的π-π相互作用,因此很难获得π共轭的室温离子液体(rtil).通过使用大体积抗衡离子的现有策略极大地阻碍了进一步的性能优化,以及通过简单的离子交换这些引人入胜的功能性流体的潜在应用.在此,4萘官能化的,π共轭具有小的抗衡离子(br的rtil-)已被轻便以高收率合成.我们的策略是将支链烷基链连接到目标化合物的阳离子主链上(2 A-D),从而有效地调节分子间和分子内的相互作用.化合物2 A-D具有令人满意的热稳定性(最高300oc)和低熔点(<−19oc).流变学测量显示2 A-D的流体特性,其粘度随烷基链长度和温度的增加而降低.π共轭萘部分的存在在本体溶液中赋予2 A-D光致发光特性.此外,无溶剂状态的萘单元之间不存在强烈的π-π堆积,因此它们可以用作新一代的光致发光油墨.
DOI:10.1002/chem.201504764

专利信息

专利号:US-9136483-B1
优先权日:2014-04-17
标 题:Thiophene fused azacoronenes: regioselective synthesis, self organization, charge transport, and its incorporation in conjugated polymers
发明人：LIU YI; HE BO
权利人:LIU YI; HE BO; UNIV CALIFORNIA
摘要:A regioselective synthesis of an azacoronene fused with two peripheral thiophene groups has been realized through a concise synthetic route. The resulting thienoazacoronene (TAC) derivatives show high degree of self-organization in solution, in single crystals, in the bulk, and in spuncast thin films. Spuncast thin film field-effect transistors of the TACs exhibited mobilities up to 0.028 cm 2 V −1 S −1 , which is among the top field effect mobilities for solution processed discotic materials. Organic photovoltaic devices using TAC-containing conjugated polymers as the donor material exhibited a high open-circuit voltage of 0.89 V, which was ascribable to TAC's low-lying highest occupied molecular orbital energy level.