CAS: 597-64-8; Tetraethylstannane

该化合物是有机锡化合物,其特征是附于锡原子的四组乙基组,在室内温度下对黄色的青色液体无色,表现出一种独特的大蒜味.四乙基锡以其高度挥发性和低溶解性而闻名,使其在水中更易溶解,主要用作有机合成中的试剂和聚氯乙烯生产中的稳定剂.然而,它也因其毒性,特别是对水生生物的毒性而得到承认,并因其生物累积潜力而对环境造成危害.在处理四乙基锡时,安全防范是必要的,因为它可引起皮肤和眼刺激,而且与...

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CAS号74-96-4 溴乙烷 | CAS号7646-78-8 四氯化锡 | CAS号75-00-3 氯乙烷 | CAS号993-63-5 Hexaethyldistannane | CAS号994-32-1 triethyltin,hydrate | CAS号925-90-6 乙基溴化镁 | CAS号97-93-8 三乙基铝 | CAS号994-31-0 氯化三乙基锡 | CAS号7440-31-5 锡粉 | CAS号811-49-4 乙基锂 | CAS号1066-57-5 一乙基锡 | CAS号994-31-0 氯化三乙基锡 | CAS号866-55-7 二乙基二氯化锡 | CAS号107-26-6 ethylmercury bromide | CAS号109000-86-4 9-ethyl-10-meth... | CAS号109-62-6 ethylmercury acetate | CAS号1907-13-7 triethyl tin (1... | CAS号1012-56-2 triethyl(phenyl... | CAS号108354-35-4 dimethylethyltin | CAS号58589-88-1 bromo-diethyl-m...

合成工艺路线路线简述

    📜Stannane置于乙烯体系中,用34%的收率获得产物四乙基锡
    参考文献:Stannane
    标题:Stannane
    摘要:
    DOI:10.1021/ja01037A054

    海关参考信息

    专利信息


    专利号:US-2024383928-A1
    优先权日:2021-07-30
    标 题:Production of diorganotin dihalides
    发明人:VINCENT ROBERT; ZIMMERMANN JARROD C
    权利人:MERCK PATENT GMBH
    摘要:The disclosed and claimed subject matter relates to the safe and efficient synthesis of diorganotin dihalide compounds of the formula R2SnX2 that as-synthesized are free of tetraalkyltin (R4Sn), trialkyltin halide (R3SnX) and monoalkyltin trihalide (RSnX3) species and of methods for their synthesis and use.

    专利号:US-6624116-B1
    优先权日:1998-09-03
    标 题 :On-line synthesis and regeneration of a catalyst used in autothermal oxidation
    发明人:BHARADWAJ SAMEER S; MAJ JOSEPH J; SIDDALL JONATHAN H
    权利人:DOW GLOBAL TECHNOLOGIES INC
    摘要:An on-line method of synthesizing or regenerating catalysts for autothermal oxidation processes, specifically, the oxidation of paraffinic hydrocarbons, for example, ethane, propane, and naphtha, to olefins, for example, ethylene and propylene. The catalyst comprises a Group 8B metal, for example, a platinum group metal and, optionally, a promoter, such as tin, antimony, or copper, on a support, preferably a monolith support. On-line synthesis or regeneration involves co-feeding a volatile Group 8B metal compound and/or a volatile promoter compound with the paraffinic hydrocarbon and oxygen into the oxidation reactor under ignition or autothermal conditions.

    专利号:US-5693792-A
    优先权日:1992-02-18
    标 题 :β-lactam and cephem compounds and processes for their production
    发明人:TORII SHIGERU; TANAKA HIDEO; SASAOKA MITIO; SHIROI TAKASHI; KAMEYAMA YUTAKA
    权利人:OTSUKA KAGAKU KK
    摘要:The object of the invention is to provide a β-lactam compound and a 2-substituted methyl-3-cephem compound, both of which are of value as intermediates for the synthesis of cephem antibiotics. n The β-lactam compound of the invention may be represented by the general formula ##STR1## wherein R 1 represents a protected amino group, for instance; R 2 represents hydrogen, for instance; R 3 represents hydrogen or a carboxy-protecting group; R 4 represents an aryl group which may be substituted; R 5 represents an alkenyl group which may be substituted, for instance. The 2-substituted methyl-3-cephem compound of the invention may be represented by the general formula ##STR2## wherein R 1 , R 2 and R 3 are as defined above; R 6 represents an aryl group which may be substituted.

    专利号:US-5596115-A
    优先权日:1994-11-04
    标题:Compounds of rhenium and aluminium, preparation thereof and use thereof as catalysts
    发明人:COMMEREUC DOMINIQUE
    权利人:INST FRANCAIS DU PETROLE
    摘要:The present invention concerns new compounds of rhenium and aluminum corresponding to the general formula: O 3 Re--O--[Al(OR)(L) x --O] n --ReO 3 in which R is a hydrocarbyl residue, for example alkyl, cycloalkyl, alkenyl, aryl and aryl or cycloalkyl which are substituted, containing from 1 to 40 carbon atoms, which residue can be substituted by alkoxy groups or by halogens, L is the synthesis solvent, x is equal to 0 or 1 and n is an integer of from 1 to 10. The invention also concerns derived compounds of the formula O 3 Re(L')--O--[Al(OR)(L) x --O] n --ReO 3 (L') in which L' is a stabilising ligand. The invention also concerns the preparation of such compounds and the use thereof in the preparation of catalysts.

    专利号:US-8329923-B2
    优先权日:2010-06-17
    标 题:4, 4′ disubstituted 4H-cyclopentadithiophene and new methods for synthesizing the same
    发明人:VANDERZANDE DIRK; LUTSEN LAURENCE; VAN MIERLOO SARAH
    权利人:VANDERZANDE DIRK; LUTSEN LAURENCE; VAN MIERLOO SARAH; IMEC; UNIV HASSELT
    摘要:The present preferred embodiments relate to a method for the synthesis of a compound having the following general formula: n nthe method comprising the step of reacting, in presence of a diprotic acid having a negative pKa, a compound having the general formula:n n nwherein R 1 and R 2 are organic groups and wherein X and Y are independently selected from the group consisting of hydrogen, chloro, bromo, iodo, boronic acid, boronate esters, borane, pseudohalogen and organotin. It further relates to compounds so obtained and to compounds resulting from the ring closure of compound (II).

    专利号:US-5747409-A
    优先权日:1994-11-04
    标题 :Catalytic compositions based on compounds of rhenium and aluminium, preparation thereof and use thereof for the metathesis of olefins
    发明人:COMMEREUC DOMINIQUE
    权利人:INST FRANCAIS DU PETROLE
    摘要:The present invention concerns new catalytic compositions containing at least one compound of rhenium and aluminium corresponding to the general formula: O 3 Re--O-- Al(OR)(L) x --O! n --ReO 3 in which R is a hydrocarbyl residue, for example alkyl, cycloalkyl, alkenyl, aryl and aryl or cycloalkyl which are substituted, containing from 1 to 40 carbon atoms, which residue can be substituted by alkoxy groups or by halogens, L is the synthesis solvent, x is equal to 0 or 1 and n is an integer of from 1 to 10. The invention also concerns the preparation of such compositions and the use thereof for the metathesis of olefins in a homogeneous phase.

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    合成参考文献


    摘要:Mérour, J.-Y.; Joseph, B., Science of Synthesis Knowledge Updates, (2016) 3, 399.
    摘要:Liang, Y.; Wen, Z.; Cabrera, M.; Howlader, A. H.; Wnuk, S. F., Science of Synthesis Knowledge Updates, (2020) 1, 328.
    摘要:Yi, C. S., Science of Synthesis: Catalytic Transformations via CH Activation, (2015) 1, 242.
    摘要:Summary Tables of Biological Tests, National Research Council Chemical-Biological Coordination Center., 4(234), 1952
    摘要:National Technical Information Service., OTS0572001
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