专利号:US-2024383928-A1 优先权日:2021-07-30 标 题:Production of diorganotin dihalides 发明人:VINCENT ROBERT; ZIMMERMANN JARROD C 权利人:MERCK PATENT GMBH 摘要:The disclosed and claimed subject matter relates to the safe and efficient synthesis of diorganotin dihalide compounds of the formula R2SnX2 that as-synthesized are free of tetraalkyltin (R4Sn), trialkyltin halide (R3SnX) and monoalkyltin trihalide (RSnX3) species and of methods for their synthesis and use.
专利号:US-6624116-B1 优先权日:1998-09-03 标 题 :On-line synthesis and regeneration of a catalyst used in autothermal oxidation 发明人:BHARADWAJ SAMEER S; MAJ JOSEPH J; SIDDALL JONATHAN H 权利人:DOW GLOBAL TECHNOLOGIES INC 摘要:An on-line method of synthesizing or regenerating catalysts for autothermal oxidation processes, specifically, the oxidation of paraffinic hydrocarbons, for example, ethane, propane, and naphtha, to olefins, for example, ethylene and propylene. The catalyst comprises a Group 8B metal, for example, a platinum group metal and, optionally, a promoter, such as tin, antimony, or copper, on a support, preferably a monolith support. On-line synthesis or regeneration involves co-feeding a volatile Group 8B metal compound and/or a volatile promoter compound with the paraffinic hydrocarbon and oxygen into the oxidation reactor under ignition or autothermal conditions.
专利号:US-5693792-A 优先权日:1992-02-18 标 题 :β-lactam and cephem compounds and processes for their production 发明人:TORII SHIGERU; TANAKA HIDEO; SASAOKA MITIO; SHIROI TAKASHI; KAMEYAMA YUTAKA 权利人:OTSUKA KAGAKU KK 摘要:The object of the invention is to provide a β-lactam compound and a 2-substituted methyl-3-cephem compound, both of which are of value as intermediates for the synthesis of cephem antibiotics. n The β-lactam compound of the invention may be represented by the general formula ##STR1## wherein R 1 represents a protected amino group, for instance; R 2 represents hydrogen, for instance; R 3 represents hydrogen or a carboxy-protecting group; R 4 represents an aryl group which may be substituted; R 5 represents an alkenyl group which may be substituted, for instance. The 2-substituted methyl-3-cephem compound of the invention may be represented by the general formula ##STR2## wherein R 1 , R 2 and R 3 are as defined above; R 6 represents an aryl group which may be substituted.
专利号:US-5596115-A 优先权日:1994-11-04 标题:Compounds of rhenium and aluminium, preparation thereof and use thereof as catalysts 发明人:COMMEREUC DOMINIQUE 权利人:INST FRANCAIS DU PETROLE 摘要:The present invention concerns new compounds of rhenium and aluminum corresponding to the general formula: O 3 Re--O--[Al(OR)(L) x --O] n --ReO 3 in which R is a hydrocarbyl residue, for example alkyl, cycloalkyl, alkenyl, aryl and aryl or cycloalkyl which are substituted, containing from 1 to 40 carbon atoms, which residue can be substituted by alkoxy groups or by halogens, L is the synthesis solvent, x is equal to 0 or 1 and n is an integer of from 1 to 10. The invention also concerns derived compounds of the formula O 3 Re(L')--O--[Al(OR)(L) x --O] n --ReO 3 (L') in which L' is a stabilising ligand. The invention also concerns the preparation of such compounds and the use thereof in the preparation of catalysts.
专利号:US-8329923-B2 优先权日:2010-06-17 标 题:4, 4′ disubstituted 4H-cyclopentadithiophene and new methods for synthesizing the same 发明人:VANDERZANDE DIRK; LUTSEN LAURENCE; VAN MIERLOO SARAH 权利人:VANDERZANDE DIRK; LUTSEN LAURENCE; VAN MIERLOO SARAH; IMEC; UNIV HASSELT 摘要:The present preferred embodiments relate to a method for the synthesis of a compound having the following general formula: n nthe method comprising the step of reacting, in presence of a diprotic acid having a negative pKa, a compound having the general formula:n n nwherein R 1 and R 2 are organic groups and wherein X and Y are independently selected from the group consisting of hydrogen, chloro, bromo, iodo, boronic acid, boronate esters, borane, pseudohalogen and organotin. It further relates to compounds so obtained and to compounds resulting from the ring closure of compound (II).
专利号:US-5747409-A 优先权日:1994-11-04 标题 :Catalytic compositions based on compounds of rhenium and aluminium, preparation thereof and use thereof for the metathesis of olefins 发明人:COMMEREUC DOMINIQUE 权利人:INST FRANCAIS DU PETROLE 摘要:The present invention concerns new catalytic compositions containing at least one compound of rhenium and aluminium corresponding to the general formula: O 3 Re--O-- Al(OR)(L) x --O! n --ReO 3 in which R is a hydrocarbyl residue, for example alkyl, cycloalkyl, alkenyl, aryl and aryl or cycloalkyl which are substituted, containing from 1 to 40 carbon atoms, which residue can be substituted by alkoxy groups or by halogens, L is the synthesis solvent, x is equal to 0 or 1 and n is an integer of from 1 to 10. The invention also concerns the preparation of such compositions and the use thereof for the metathesis of olefins in a homogeneous phase.
摘要:Mérour, J.-Y.; Joseph, B., Science of Synthesis Knowledge Updates, (2016) 3, 399. 摘要:Liang, Y.; Wen, Z.; Cabrera, M.; Howlader, A. H.; Wnuk, S. F., Science of Synthesis Knowledge Updates, (2020) 1, 328. 摘要:Yi, C. S., Science of Synthesis: Catalytic Transformations via CH Activation, (2015) 1, 242. 摘要:Summary Tables of Biological Tests, National Research Council Chemical-Biological Coordination Center., 4(234), 1952 摘要:National Technical Information Service., OTS0572001