CAS: 2350-89-2; 4-Vinylbiphenyl

上下游产品

1-(4-phenyl-phenyl)-1-ethanol 2-phthalimido-1-biphenyl-4-yl-1-ethanone 4-(1-chloroethyl)-1,1′-biphenyl methyl magnesium iodide 4-Methoxy-4'-phenyl-stilben 4-Methoxy-3-nitro-4'-phenyl-stilben dithi°Cin6H,12H-Dibenzo1,5dithi°Cin 3,4-Dihydro-2-(4-biphenylyl)-2H-1-benzothiopyran

联苯单乙酮置于sodium Methylate体系中,用 甲醇,乙醇,环己烷 用作溶剂,化学反应 0.08H,反应生成4-乙烯基联苯
参考文献:对联苯基重氮乙烷的超快研究.重氮激发态和松弛卡宾的化学
标题:对联苯基重氮乙烷的超快研究.重氮激发态和松弛卡宾的化学
摘要:对联苯基重氮乙烷 (Bde) 的超快光解在乙腈,环己烷和甲醇中产生重氮化合物的激发态,λmax = 490 Nm,寿命小于 300 Fs.重氮激发态的衰减与 360 Nm 处单线态卡宾吸收的增长相关.对联苯基重氮甲烷 (Bdm) 和 Bde 光解产生的重氮激发态的光学产率相同;然而,在所有三种溶剂中,单线态对联苯基甲基卡宾 (1Bpcme) 的光学产率比对联苯基卡宾 (1Bpch) 的光学产率低 30-40%.通过在 Bde 的激发态 (Ries) 中重排形成对乙烯基联苯 (Vb) 并同时挤出氮气以降低产率形成 1Bpcme,可以解释该结果.这种解释与产品研究(环己烷中的乙醇-Od)一致,这表明 Vb 的收率约为 25%,这是通过绕过松弛单线态卡宾的机制形成的.1Bpcme 的衰减是双指数的,1Bpch 的衰减是单指数的.这归因于通过氢的 1,2 迁移形成 Vb(次要)或由甲基(主要)提供
Doi:10.1021/ja067213U

专利信息

专利号:US-7956011-B2
优先权日:2005-05-04
标题:Materials and methods for the photodirected synthesis of oligonucleotide arrays
发明人：SERAFINOWSKI PAWEL JERZY; GARLAND PETER BRYAN
权利人:CANCER RES INST ROYAL
摘要:Materials and methods for photodirected synthesis of oligonucleotide arrays on a solid substrate by photodirected synthesis are disclosed which employ a film formed from (i) a photoacid generator that on photolysis generates acid that is capable of directly removing the protecting group of the linker molecules or oligonucleotides and (ii) a polymer substantially lacking electronegative heteroatoms that are capable of hydrogen bonding with photogenerated acid. Methods of synthesizing an oligomer arrays are also described that use a film that restricts diffusion of reactants and products on the substrate during synthesis of the array and which includes a precursor of a deprotecting reagent. The method involves removing one or more of the non-required products of the deprotection reaction from the reactive array elements at which they are produced during the reaction, in order to displace the deprotection reaction towards completion.

专利号:WO-2022155981-A1
优先权日:2021-01-25
标题 :USE OF N-HETEROCYCLIC CARBENE-BASED COMPOUNDED NICKEL (II) COMPLEX IN SYNTHESIS OF α-BENZYL BENZOFURAN COMPOUND
发明人：SUN HONGMEI; SHUI YU; JIN WENHUI
权利人:UNIV SOOCHOW
摘要:Disclosed is the use of an N-heterocyclic carbene-based compounded nickel (II) complex in the synthesis of an α-benzyl benzofuran compound. In the present invention, an air-stable compounded nickel (II) complex Ni[P(OEt) 3 ]{[R`NC(CH 3 )C(CH 3 )NR`]C}Br 2 is used as a catalyst, wherein R` is 2,4,6-trimethylphenyl, and the α-benzyl benzofuran compound is synthesized by means of a hydrogen heteroarylation reaction of an aryl ethylene compound and a benzofuran compound in the presence of an organic base. The operability and substrate applicability of the catalyst are obviously better than those of the prior art, and meanwhile, the nickel catalyst has a higher practical application value due to the air stability and easiness of synthesis thereof.

专利号:US-6107408-A
优先权日:1998-02-26
标题 :Processes for improving linking efficiencies in the synthesis of star polymers
发明人：QUIRK RODERIC PAUL; LETCHFORD ROBERT JAMES; SCHWINDEMAN JAMES ANTHONY
权利人:FMC CORP
摘要:Processes for the synthesis of star or multi-branched polymers and the resultant polymers. One or more alkadiene monomers are polymerized in the presence of suitable organometallic initiators and subsequently coupled to form star polymers. Prior to coupling, one or more alkenylsubstituted aromatic hydrocarbons are incorporated at the living ends of the polydienyl anions to provide increased linking efficiencies.

专利号:WO-2017051326-A1
优先权日:2015-09-23
标 题 :New processes and intermediates useful in synthesis of nep inhibitors
发明人：MARTIN BENJAMIN; PENN GERHARD; SCHENKEL BERTHOLD; BOURNE SAMUEL; LAU SHING-HING; LEY Steven
权利人:NOVARTIS AG; MARTIN BENJAMIN; PENN GERHARD; SCHENKEL BERTHOLD; BOURNE SAMUEL; LAU SHING-HING; LEY Steven
摘要:The invention relates to a novel process, novel process steps and novel intermediates useful in the synthesis of pharmaceutically active compounds, in particular neutral endopeptidase (NEP) inhibitors such as sacubitril, and prodrugs thereof.

专利号:US-5420237-A
优先权日:1991-08-29
标 题:Enzymatic synthesis of polyaniline
发明人：ZEMEL HAYA; QUINN JOHN F
权利人:ALLIED SIGNAL INC
摘要:This invention relates to a process for the enzymatic synthesis of electrically conductive substituted and unsubstituted polyanilines. Aniline monomer(s), an oxidizing agent, which comprises an enzyme and an electron acceptor, and an acidifying agent are reacted together to form polyanilines.

专利号:US-9403854-B2
优先权日:2001-03-30
标 题 :Cross-metathesis reaction of functionalized and substituted olefins using group 8 transition metal carbene complexes as metathesis catalysts
发明人：GRUBBS ROBERT H; CHATTERJEE ARNAB K; CHOI TAE-LIM; GOLDBERG STEVEN D; LOVE JENNIFER A; MORGAN JOHN P; SANDERS DANIEL P; SCHOLL MATTHIAS; TOSTE F DEAN; TRNKA TINA M
权利人:CALIFORNIA INST OF TECHN
摘要:The invention pertains to the use of Group 8 transition metal carbene complexes as catalysts for olefin cross-metathesis reactions. In particular, ruthenium and osmium alkylidene complexes substituted with an N-heterocyclic carbene ligand are used to catalyze cross-metathesis reactions to provide a variety of substituted and functionalized olefins, including phosphonate-substituted olefins, directly halogenated olefins, 1,1,2-trisubstituted olefins, and quaternary allylic olefins. The invention further provides a method for creating functional diversity using the aforementioned complexes to catalyze cross-metathesis reactions of a first olefinic reactant, which may or may not be substituted with a functional group, with each of a plurality of different olefinic reactants, which may or may not be substituted with functional groups, to give a plurality of structurally distinct olefinic products. The methodology of the invention is also useful in facilitating the stereoselective synthesis of 1,2-disubstituted olefins in the cis configuration.