CAS: 83708-70-7; Dihydrosesamin

该化合物是一种来自自然来源的离子体化合物,以其潜在的生物活性及其在制药和营养研究中的应用而著称,与血清有结构关系,由于氢化而表现出更大的稳定性;二氢血清在临床前研究中表现出抗氧化剂,抗炎和潜在的...

英文名称Dihydrosesamin
中文名称(-)-二氢芝麻素
IUPAC名称((2R,3S,4S)-2-(benzo[d][1,3]dioxol-5-yl)-4-(benzo[d][1,3]dioxol-5-ylmethyl)tetrahydrofuran-3-yl)methanol
其它别名Dihydrosesamin; (2R,3S,4S)-2-(1,3-Benzodioxol-5-yl)-4-(1,3-Benzodioxol-5-Ylmethyl)Tetrahydro-3-Furanmethanol; 3-Furanmethanol, 2-(1,3-Benzodioxol-5-yl)-4-(1,3-Benzodioxol-5-Ylmethyl)Tetrahydro-, (2R,3S,4S)-; (-)-Dihydrosesamin/dihydrosesamin
CAS编号83708-70-7
MFCD编号:MFCD28009426
分子式:C20H20O6分子量:356.37
产品CID: 1825262
产品分类天然产物 → 木脂素

相似结构搜索
产品信息参考;;;;
InChIKey: JOCPSXXUQJXDBI-SXGZJXTBSA-N
InChI=1S/C20H20O6/c21-8-15-14(5-12-1-3-16-18(6-12)25-10-23-16)9-22-20(15)13-2-4-17-19(7-13)26-11-24-17/h1-4,6-7,14-15,20-21H,5,8-11H2/t14-,15-,20+/m1/s1
计算化学: 氢键受体数6.0氢键供体数1.0可旋转键数4.0

MSDS等安全信息

警示词Warning
危险描述H302-H315-H319-H335-
防范说明P261-P305+P351+P338-
安全声明H303+H313+H333

上下游产品

4β-tert-butyldimethylsilyloxymethyl-3β-(3,4-methylenedioxybenzyl)-5β-(3,4-methylenedioxyphenyl)dihydrofuran-2(3H)-one ethyl acetate 1-(3,4-methylenedioxyphenyl)-1-(3-(3,4-methylenedioxyphenyl)-2-propenyloxy)-2,3-epoxypropane (E)-5-(3-bromoprop-1-en-1-yl)benzo[d][1,3]dioxole

合成工艺路线路线简述

872728-42-2 = 83708-70-7
反应条件:1.1 Reagents: Titanocene Dichloride,Zinc Solvents: Tetrahydrofuran; 1 H,Rt1.2 Solvents: Tetrahydrofuran; 0.5 H,Rt; 1 H,Rt1.3 Reagents: Sulfuric Acid Solvents: Water
标题:Concise Enantioselective Synthesis Of Furan Lignans (-)-Dihydrosesamin And (-)-Acuminatin And Furofuran Lignans (-)-Sesamin And (-)-Methyl Piperitol By Radical Cyclization Of Epoxides
作者:Banerjee,Biplab; Et Al
参考文献:Synthesis 日期:2005 卷标:(17) 页码:2913-2919]

67911-75-5 = 83708-70-7
反应条件:1.1 Reagents: Sodium Hydride Solvents: Dimethyl Sulfoxide,Tetrahydrofuran; 15 Min,0 - 10 °C1.2 Solvents: Tetrahydrofuran; 25 Min,0 °C; 8 H,Rt1.3 Reagents: Water; 0 °C2.1 Reagents: Titanocene Dichloride,Zinc Solvents: Tetrahydrofuran; 1 H,Rt2.2 Solvents: Tetrahydrofuran; 0.5 H,Rt; 1 H,Rt2.3 Reagents: Sulfuric Acid Solvents: Water
标题:Concise Enantioselective Synthesis Of Furan Lignans (-)-Dihydrosesamin And (-)-Acuminatin And Furofuran Lignans (-)-Sesamin And (-)-Methyl Piperitol By Radical Cyclization Of Epoxides
作者:Banerjee,Biplab; Et Al
参考文献:Synthesis 日期:2005 卷标:(17) 页码:2913-2919]

5208-87-7 = 83708-70-7
反应条件:1.1 Reagents: Diethyl Tartrate,Titanium Isopropoxide Solvents: Dichloromethane; 20 Min,-20 °C1.2 Reagents: Tert-Butyl Hydroperoxide Solvents: Decane; 0.5 H,-20 °C1.3 Solvents: Dichloromethane; 4 H,-20 °C1.4 Reagents: Dl-Tartaric Acid Solvents: Water; 0.5 H,-20 °C -> 0 °C2.1 Reagents: Sodium Hydride Solvents: Dimethyl Sulfoxide,Tetrahydrofuran; 15 Min,0 - 10 °C2.2 Solvents: Tetrahydrofuran; 25 Min,0 °C; 8 H,Rt2.3 Reagents: Water; 0 °C3.1 Reagents: Titanocene Dichloride,Zinc Solvents: Tetrahydrofuran; 1 H,Rt3.2 Solvents: Tetrahydrofuran; 0.5 H,Rt; 1 H,Rt3.3 Reagents: Sulfuric Acid Solvents: Water
标题:Concise Enantioselective Synthesis Of Furan Lignans (-)-Dihydrosesamin And (-)-Acuminatin And Furofuran Lignans (-)-Sesamin And (-)-Methyl Piperitol By Radical Cyclization Of Epoxides
作者:Banerjee,Biplab; Et Al
参考文献:Synthesis 日期:2005 卷标:(17) 页码:2913-2919