CAS: 704-00-7; 1,1'-(1,2-Phenylene)Diethanone

该化合物是一种有机化合物,其芳香结构特征为:在1和2个位置的苯环上附着两个乙酰组,其分子式为C10H10O2,其分子量约为162.18克/摩尔,其分子量约为162.18克/摩尔.该化合物一般是一种无色的黄色液体,具有甜美味的香味.它溶于乙醇和乙醚等有机溶剂,但水溶性有限. 1,2-二乙基苯主要用于有机合成,并用作各种化学化合物生产的中间体.它显示出芳香化合物的典型特性,包括电荷替代反应的稳定性和再活性.此外,它可以发生氧化和减少反应,使其在合成化学中具有多种特性.在处理该化合物时,应当采取安全防范措施,因为如果吸入或浸泡,可能会对健康造成危害.

英文名称1,1'-(1,2-Phenylene)Diethanone
中文名称1,2-二乙酰苯
IUPAC名称1,1'-(1,2-phenylene)bis(ethan-1-one)
其它别名1-(2-Acetylphenyl)Ethanone; 1,2-Diacetylbenzene,; 1,2-Diacetylbenzene ; 2-Acetylacetophenone; 1,2-Diacetylbenzene; 1,1’-(1,2-Phenylene)Bis-Ethanon; 1,1’-(1,2-Phenylene)Bisethanone
CAS编号704-00-7
MFCD编号:MFCD00008733
EINECS号:211-877-6
分子式:C10H10O2
分子量:162.19
产品CID: 1697940
产品分类化学试剂 → 有机试剂 → 芳烃

相似结构搜索
产品信息参考;;
InChIKey: LVQFKRXRTXCQCZ-UHFFFAOYSA-N
InChI=1S/C10H10O2/c1-7(11)9-5-3-4-6-10(9)8(2)12/h3-6H,1-2H3…
计算化学: 氢键受体数2.0氢键供体数0.0可旋转键数2.0

物理性质

熔点39-41 °C(文献)
沸点110 °C0.1 mm Hg(文献)
闪点>230 °F
密度110 C 0.1 mm Hg(文献)
PSA:34.14
LogP:2.0918
折射率1.519
蒸汽压5.17E-05 mmHg at 25 °C
溶解性Dichloromethane: Soluble50mg/mL, Clear, Colorless To Yellow
敏感性常温常压下稳定，避免与不相容材料，强氧化剂接触。与强氧化剂，强碱反应。
外观形态固体
储存条件2-8°C

上下游产品

合成工艺路线路线简述

N'-(1-(2-Hydroxyphenyl) Ethylidene) Acetohydrazide置于碘苯二乙酸体系中,用二氯甲烷作为反应溶剂,化学反应 44.0H,以70%的收率获得产物1,2-二乙酰苯
参考文献:Synthesis Of 1,2-Diacylbenzenes Fromo-Hydroxyaryl Ketone Acylhydrazones Using [(Diacetoxy)Iodo]Benzene
标题:Synthesis Of 1,2-Diacylbenzenes Fromo-Hydroxyaryl Ketone Acylhydrazones Using [(Diacetoxy)Iodo]Benzene
摘要:2'-羟基乙酰苯和2'-羟基丙酰苯肼酮3在室温下使用[(二乙酸氧基)-碘]苯在二氯甲烷中氧化为1,2-二酰基苯4,反应具有合成实用性和高产率.
DOI:10.1055/s-1993-25857

海关参考信息

2902600000-乙苯
2912110000-甲醛
2912120000-乙醛
2912210000-苯甲醛
💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
详情请参考：📖 海关编码查询和海关进出口税则

专利信息

专利号:US-7173059-B2
优先权日:2003-05-08
标题:Intermediates useful in the synthesis of HIV-protease inhibitors and methods for preparing the same
发明人：ALBIZATI KIM FRANCIS; BABU SRINIVASAN
权利人:AGOURON PHARMA
摘要:Optically active 3-amino-butene and 1,2-dihydroxy-3-amino-butane intermediate compounds, useful in the synthesis of HIV-protease inhibitors and methods of preparing these intermediate compounds are disclosed.

专利号:US-2024001335-A1
优先权日:2022-07-01
标题:High solids concentration synthesis of metal-organic frameworks
发明人：IVASHKO ANNA C; PETERS AARON W; KAMAKOTI PREETI; WEIGEL SCOTT J; KAPELEWSKI MATTHEW T; HERB NICOLE M; PEREZ VELEZ ROXANA; ANTHONIS MARC H; LEVIN DORON; REDDINGTON TARA L
权利人:EXXONMOBIL TECHNOLOGY & ENGINEERING COMPANY
摘要:Methods are provided for synthesizing metal-organic framework compositions using synthesis mixtures with elevated solids content and/or elevated kinematic viscosity. The methods can allow for formation of MOF-274 metal-organic framework compositions, such as EMM-67 (a mixed-metal MOF-274 metal-organic composition). More generally, the methods can allow for formation of MOF structures that include multi-ring disalicylate organic linkers using synthesis mixtures that contain a reduced or minimized amount of solvent, such as down to having substantially no solvent in the synthesis mixture.

专利号:WO-2024005838-A1
优先权日:2022-07-01
标题 :High solids concentration synthesis of metal-organic frameworks
发明人：IVASHKO ANNA; PETERS AARON; KAMAKOTI PREETI; WEIGEL SCOTT; KAPELEWSKI MATTHEW; HERB NICOLE; PEREZ VELEZ ROXANA; ANTHONIS MARC; LEVIN DORON; REDDINGTON TARA
权利人:EXXONMOBIL TECHNOLOGY & ENGINEERING COMPANY
摘要:Methods are provided for synthesizing metal-organic framework compositions using synthesis mixtures with elevated solids content and/or elevated kinematic viscosity. The methods can allow for formation of MOF-274 metal-organic framework compositions, such as EMM-67 (a mixed-metal MOF-274 metal-organic composition). More generally, the methods can allow for formation of MOF structures that include multi-ring disalicylate organic linkers using synthesis mixtures that contain a reduced or minimized amount of solvent, such as down to having substantially no solvent in the synthesis mixture.

专利号:WO-2011091548-A1
优先权日:2010-01-27
标题:Method for cucurbitine synthesis
发明人：CHANG XIAOWEI; KHOSHDEL EZAT; PENG WEIMIN; WANG JINFANG; YAO YINFANG
权利人:UNILEVER PLC; UNILEVER NV; UNILEVER HINDUSTAN; CHANG XIAOWEI; KHOSHDEL EZAT; PENG WEIMIN; WANG JINFANG; YAO YINFANG
摘要:A method for the synthesis of cucurbitine comprising the step of forming a pyrrolidine ring by a 1,3 dipolar cycloaddition reaction.

专利号:US-2024002417-A1
优先权日:2022-07-01
标题 :Aqueous-based synthesis of metal organic frameworks
发明人：IVASHKO ANNA C; ABNEY CARTER W; HERB NICOLE M; KAMAKOTI PREETI; PETERS AARON W; KAPELEWSKI MATTHEW T; ANTHONIS MARC H; PEREZ VELEZ ROXANA; HRYCENKO NADYA A; LEVIN DORON; REDDINGTON TARA L; WEIGEL SCOTT J
权利人:EXXONMOBIL TECHNOLOGY & ENGINEERING COMPANY
摘要:Methods are provided for synthesizing metal organic framework compositions in an aqueous environment and/or in a mixed alcohol/water solvent. The methods can allow for formation of MOF-274 metal organic framework compositions, such as EMM-67 (a mixed metal MOF-274 metal organic framework composition). More generally, the methods can allow for formation of MOF structures that include disalicylate linkers in an aqueous environment and/or in a mixed alcohol/water solvent.

专利号:US-2023174490-A1
优先权日:2020-03-18
标题 :Improved synthesis of 6-aryl-4-aminopicolinates
发明人：ZHANG CHUNMING; TU SIYU; LENG RONALD B; IRVINE NICHOLAS; SCHUITMAN ABRAHAM; SHINKLE AARON; DEVARAJ JAYACHANDRAN; ZU CHENGLI
权利人:CORTEVA AGRISCIENCE LLC
摘要:The present disclosure relates to improved methods of synthesizing 6-aryl-4-aminopicolinates, such as arylalkyl and alkyl 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylates.