CAS: 5931-53-3; Diphenyl(O-Tolyl)Phosphine

上下游产品

ortho-tolylmagnesium bromide chloro-diphenylphosphine 2-methylphenyl bromide diphenylphosphane2-[2-(diphenylphosphino)phenyl]acetic acid (2-methylphenyl)diphenylphosphine sulfide toluene2-(diphenylphosphinoyl)-α-(2S,3S)-2,3-diphenylaziridine-1-yltoluene (o-carboxyphenyl)diphenylphosphine oxide

📜Diphenyl-O-Tolyl-Phosphine Oxide置于草酰氯,氢气体系中,用 氘代氯仿 作为反应溶剂,130.0 °C,8.0 Mpa 条件下,反应 18.0H,以88%的收率获得产物二苯基(O-甲苯基)膦
参考文献:使用草酰氯和氢气还原亲电性磷阳离子介导的氧化膦
标题:使用草酰氯和氢气还原亲电性磷阳离子介导的氧化膦
摘要:使用草酰氯作为活化剂,实现了以分子氢(h 2)对金属氧化物氧化物的无金属还原.量子力学研究支持通过原位形成的亲电phospho阳离子(epc)和氧化膦进行h 2的杂化裂解,以及随后的无阻转化为膦和hcl.该反应还可以通过由b(2,6-F 2 C 6 H 3)3和2,6-二甲基吡啶或氧化膦作为lewis碱组成的沮丧lewis对(flp)催化.三芳基和二芳基氧化膦证明了这种新颖的还原方法,提供了以非常好至极佳收率(51%至93%)的膦原子.
DOI:10.1002/anie.201809275

专利信息

专利号:US-3682970-A
优先权日:1969-03-27
标 题:Production of unsaturated carbocyclic ketones
发明人：HENRICK CLIVE A; EDWARDS JOHN A; FRIED JOHN H
权利人:SYNTEX CORP
摘要:Preparation of Alpha , Beta -unsaturated carbocyclic ketones by reacting a methylene or methine phosphonium ylid with a delta keto carboxylic acid ester, anhydride or acyl halide. The reaction is useful for producing intermediates for synthesis of known steroids having estrogenic, progestational, or anabolic activity, for example.

专利号:US-2021284668-A1
优先权日:2018-06-19
标题:Gold (i)-phosphine 1,2,3-triazole derivatives with antibiotic properties
发明人：MISLIN GAËTAN; SCHALK ISABELLE; PLÉSIAT PATRICK; PAULEN AURÉLIE
权利人:CENTRE NAT RECH SCIENT; UNIV FRANCHE COMTE; CENTRE HOSPITALIER REGIONAL UNIV DE BESANCON; UNIV STRASBOURG
摘要:The present invention relates to gold (I)-phosphine 1,2,3-triazole compounds, and their use in a human or animal medicine. The present invention also relates to using such compounds for the prevention and/or treatment of an infection, i.e. inhibitors of growth of Gram-positive and/or Gram-negative bacteria. On another aspect the invention relates to the synthesis of the gold (I)-phosphine compounds of the invention and to their synthesis intermediates. The present invention finds applications in the medical, veterinary and/or chemical fields.

专利号:DE-112020000129-T5
优先权日:2019-04-29
标题:Process for the synthesis of isopentenal by isomerization of methylbutynol

专利号:US-6476233-B1
优先权日:1998-11-12
标 题 :Transition metal-catalyzed reactions based on chiral amine oxazolinyl ligands and related compounds
发明人：ZHANG XUMU
权利人:PENN STATE RES FOUND
摘要:This invention is to develop novel transition metal catalysts for the practical synthesis of important chiral molecules. The invention emphasizes asymmetric catalysis based on chiral amine oxazolinyl ligands and related ligands. Specially, a direct asymmetric hydrogenation system based on Ru-Ambox catalyst was discovered.

专利号:DE-112020000129-B4
优先权日:2019-04-29
标 题:Process for the synthesis of isopentenal by isomerization of methylbutynol

专利号:KR-850000047-B1
优先权日:1980-08-25
标 题:1RS, 4SR, 5RS-4- (4,8-dimethyl-5-hydroxy-7-nonen-1-yl) -4-methyl-3,8-dioxabicyclo [3.2.1] octane-1- Total synthesis method of acetic acid