2,6-二溴-4-硝基苯胺置于正丁基锂,硫酸,Tin(Ll) Chloride,Sodium Nitrite体系中,用 四氢呋喃,乙醇 作为反应溶剂,化学反应 60.75H,反应生成 3,5-二溴苯甲醛 参考文献:Synthesis Of Anthropomorphic Molecules: The Nanoputians 标题:Synthesis Of Anthropomorphic Molecules: The Nanoputians 摘要:Described Here Are The Synthetic Details En Route To An Array Of 2-Nm-Tall Anthropomorphic Molecules In Monomeric,Dimeric,And Polymeric Form. These Anthropomorphic Figures Are Called,As A Class,Nanoputians. Using Tools Of Chemical Synthesis,The Ultimate In Designed Miniaturization Can Be Attained While Preparing The Most Widely Recognized Structures: Those That Resemble Humans. DOI:10.1021/jo0349227
专利号:US-6916982-B2 优先权日:2000-07-21 标题:Synthesis of perylene-porphyrin building blocks and polymers thereof for the production of light-harvesting arrays 发明人:LOEWE ROBERT S; TOMIZAKI KIN-YA; LINDSEY JONATHAN S 权利人:UNIV NORTH CAROLINA STATE 摘要:The present invention provides methods, compounds, and compositions for the synthesis of light harvesting arrays, such arrays comprising: (a) a first substrate comprising a first electrode; and (b) a layer of light harvesting rods electrically coupled to said first electrode, each of said light harvesting rods comprising a polymer of Formula I:n nX 1 X m+1 ) m   (I)n nwherein m is at least 1; X 1 is a charge separation group, and X 2 through X m+1 are chromophores. At least one of X 2 through X m+1 has at least one perylene group coupled thereto.
专利号:US-2003075216-A1 优先权日:2000-07-21 标题 :Synthesis of perylene-porphyrin building blocks and polymers thereof for the production of light-harvesting arrays
专利号:WO-03105237-A1 优先权日:2002-06-06 标 题:Synthesis of perylene-porphyrin building blocks and polymers thereof for the production of light-harvesting arrays
专利号:CN-104650041-B 优先权日:2013-11-20 标 题 :A kind of fluorine-containing phenanthroimidazole derivatives and its synthesis method and application
[参考文献]: Jakub Saadi, Et Al. β-Siloxy-α-Haloketones Through Highly Diastereoselective Single And Double Mukaiyama Aldol Reactions. Chemistry. 2013 Mar 18;19(12):3842-5.
合成参考文献
摘要:Duschmalé, J.; Arakawa, Y.; Wennemers, H., Science of Synthesis: Asymmetric Organocatalysis, (2012) 2, 770. 摘要:Bernardi, L.; Ricci, A., Science of Synthesis: Multicomponent Reactions, (2013) 1, 140.