CAS: 19398-88-0; Cis-4-Decene

上下游产品

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📜4-癸炔置于喹啉,氢气体系中,用 甲苯 用作溶剂,化学反应 2.5H,反应生成顺式-4-癸烷
参考文献:转移加氢条件下炔烃选择性ru催化半还原为z烯烃
标题:转移加氢条件下炔烃选择性ru催化半还原为z烯烃
摘要:通过使用一种容易获得的,空气和水分稳定的二氢-Ru络合物,可以在转移加氢条件下以甲酸为氢源获得各种z烯烃,并具有出色的收率和z / E选择性.
Doi:10.1002/chem.201001143

专利信息

专利号:US-5358860-A
优先权日:1993-04-05
标题:Stereoselective epoxidation of alkenes by chloroperoxidase
发明人：HAGER LOWELL P; ALLAIN ERIC J
权利人:UNIV ILLINOIS
摘要:A method of converting olefins to chiral epoxides comprises combining an asymmetric aliphatic or aryl alkene substrate with a buffered chloroperoxidase solution to form a stabilized reaction mixture, and gradually adding hydrogen peroxide as a substrate oxidant, such that the chloroperoxidase catalyzes the conversion of the substrate to the corresponding epoxide in enantiomeric excess. The products of the invention are alkyl and aryl non-primary epoxides. The resulting preparations are enantiomerically pure, and may greatly enhance large-scale synthesis of stereoisomer products such as pharmaceuticals and pesticides.

专利号:JP-5568470-B2
优先权日:2007-06-13
标 题:Process for the synthesis of diacids or diesters from natural fatty acids and / or esters

专利号:JP-2010529180-A
优先权日:2007-06-13
标 题:Process for the synthesis of diacids or diesters from natural fatty acids and / or esters

专利号:ES-2394263-T3
优先权日:2008-07-10
标题 :Synthesis procedure of omega-amino-alkanoic acids or their esters from natural fatty acids