CAS: 16523-89-0; Triallylphosphine

该化合物是一种三级磷化合物,其组成结构在交叉相交和聚合反应中具有回活性,在有机金属催化中具有多种性悬离和分解作用;所有基组增强有机溶剂的溶解性,并促进机能化,使其在合成基于磷的聚合物或协调综合体中有用;试验性磷素因其不饱和的粘合性而具有稳定过渡性金属催化剂的能力,同时能够进一步衍生,因此特别受到重视;建议由于空气敏感性和潜在易燃性,在惰性条件下进行适当处理.

结构式图片

上下游产品

CAS号119841-34-8 cis-2,10-dimeth... | CAS号1730-25-2 烯丙基溴化镁 | CAS号106-95-6 烯丙基溴

合成工艺路线路线简述

    📜烯丙基溴化镁置于乙醚,三氯化磷体系中,化学反应生成三烯丙膦
    参考文献:Jones Et Al.,Journal Of The Chemical Society,1947,P. 1446,1449
    标题:Jones Et Al.,Journal Of The Chemical Society,1947,P. 1446,1449

    海关参考信息

    专利信息


    专利号:US-11548898-B2
    优先权日:2017-07-06
    标题 :Synthesis of halichondrins
    发明人:KISHI YOSHITO; AI YANRAN; YE NING; WANG QIAOYI; YAHATA KENZO; ISO Kentaro; NAINI SANTHOSH REDDY; YAMASHITA SHUJI; LEE JIHOON; OHASHI ISAO; FUKUYAMA TAKASHI
    权利人:HARVARD COLLEGE; EISAI R&D MAN CO LTD
    摘要:The present invention provides methods for the synthesis of ketones involving a Ni/Zr-mediated coupling reaction. The Ni/Zr-mediated ketolization reactions can be used in the synthesis of halichondrins (e.g., halichondrin A, B, C; homohalichondrin A, B, C; norhalichondrin A, B, C), and analogs thereof. Therefore, the present invention also provides synthetic methods useful for the synthesis of halichondrins, and analogs thereof. Also provided herein are compounds (i.e., intermediates) useful in the synthesis of halichondrins, and analogs thereof. In particular, the present invention provides methods and compounds useful in the synthesis of compound of Formula (H3-A).

    专利号:US-7241399-B2
    优先权日:2000-09-08
    标题 :Synthesis of nanoparticles
    发明人:HAUBOLD STEPHAN; HAASE MARKUS; RIWOTZKI KARSTEN; WELLER HORST; MEYSSAMY HEIKE; IBARRA FERNANDO
    权利人:CT ANGEWANDTE NANOTECH CAN
    摘要:Methods for the preparation of inorganic nanoparticles capable of fluorescence, wherein the nanoparticles consist of a host material that comprises at least one dopant. The synthesis of the invention in organic solvents allows to gain a considerably higher yield compared to the prior art synthesis in water. All kinds of objects can advantageously be marked and reliably authenticated by using an automated method on the basis of a characteristic emission. Further, the size distribution of the prepared nanoparticles is nartower which renders a subsequent size-selected separation process superfluous.

    专利号:US-7615169-B2
    优先权日:2004-09-20
    标题 :Method for synthesis of colloidal nanoparticles
    发明人:STROUSE GEOFFREY FIELDING; GERBEC JEFFREY A; MAGANA DONNY
    权利人:UNIV CALIFORNIA
    摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.

    专利号:US-11542269-B2
    优先权日:2018-01-03
    标 题:Prins reaction and compounds useful in the synthesis of halichondrin macrolides and analogs thereof
    发明人:CHOI HYEONG-WOOK; FANG FRANCIS G
    权利人:EISAI R&D MAN CO LTD
    摘要:The invention provides methods utilizing Prins reaction in the preparation of compounds that may be useful as intermediates in the synthesis of halichondrin macrolides and analogs thereof. The invention also provides compounds that may be useful as intermediates in the synthesis of a halichondrin macrolides and methods for preparing the same.

    专利号:US-7927516-B2
    优先权日:2004-09-20
    标题 :Method for synthesis of colloidal nanoparticles
    发明人:STROUSE GEOFFREY F; GERBEC JEFFREY A; MAGANA DONNY
    权利人:UNIV CALIFORNIA
    摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.

    专利号:US-2014194584-A1
    优先权日:2013-01-07
    标题 :Process for the synthesis of w-Unsaturated nitrile-acid/ester in which two types of cross metathesis are alternated consecutively swing process
    发明人:DUBOIS JEAN-LUC; COUTURIER JEAN-LUC
    权利人:ARKEMA FRANCE
    摘要:The invention relates to a process for the synthesis of a monounsaturated nitrile-ester (acid) by cross metathesis starting from an unsaturated compound I comprising at least one trivalent nitrile, acid or ester functional group, characterized in that it comprises a stage in which two types of cross metathesis are alternated consecutively:n a first type of cross metathesis cm1 with an acrylic compound II chosen from acrylonitrile, acrylic acid or an acrylic ester, one of the compounds I or II comprising a nitrile functional group and the other of these compounds II or I comprising an acid or ester functional group, and a second type of cross metathesis cm2 with a light C 2 to C 4 alkene compound III, preferably with ethylene. nn The invention also relates to a process for the synthesis of an α,ω-amino ester (acid) obtained by a process comprising a stage in which the two types of cross metathesis defined above are alternated consecutively, followed by a hydrogenation stage.

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    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Gaumont, A. C.; Carboni, B., Science of Synthesis, (2005) 6, 494.
    摘要:Bergstrer, U., Science of Synthesis, (2004) 19, 434.
    摘要:Hey-Hawkins, E.; Karasik, A. A., Science of Synthesis, (2009) 42, 83.
    摘要:Hey-Hawkins, E.; Karasik, A. A., Science of Synthesis, (2009) 42, 137.
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