CAS: 98-05-5; Phenylarsonic Acid

该化合物是有机石化合物,其特点是存在一个与苯环相连的砷原子和一个碳酸功能组,该化合物一般是白到光黄色晶状固体,在水和有机溶剂中可溶解,其分子结构是一个芳香环,有助于其稳定性和潜在再活性,苯氮酸因在各种用途中使用而闻名,包括作为除草剂和其他有机石化合物合成.然而,由于砷的毒性,其处理需要小心谨慎,并须接受监管审查.化合物具有芳香化合物和有机金属的典型特性,包括潜在的生物活动和环境持久性.在与该物质合作时,安全措施至关重要,因为砷化合物可能对健康造成重大风险.

结构式图片

欧盟法规

《欧盟PIC法规》ECHA物质ECHA物质OtherC&L通报REACH预注册

上下游产品

p-aminophenylarsonic acid benzenediazonium phenyl-arsonic acid-dichloride Diphenyldiarsenic acidnonan2,2,3,3,7,7,8,8-°Ctamethyl-5-phenyl-1,4,6,9-tetraoxa-5-arsaspiro4.4nonan 5-arsa-spiro[4.4]nonane-2,7-dione3,3,8,8-tetramethyl-5-phenyl-1,4,6,9-tetraoxa-5λ5-arsa-spiro[4.4]nonane-2,7-dione phenyl-arsonic acid bis-triphenylsilanyl ester tetrafluoro-phenyl-arsorane

合成工艺路线路线简述

    二氯苯胂置于sodium Hydroxide体系中,化学反应生成 苯胂酸
    参考文献:Jakubowitsch,Journal Fur Praktische Chemie (Leipzig 1954),1933,Vol. <2>138,P. 166
    标题:Jakubowitsch,Journal Fur Praktische Chemie (Leipzig 1954),1933,Vol. <2>138,P. 166

    海关参考信息

    专利信息


    专利号:US-5068372-A
    优先权日:1990-07-16
    标 题:Method for the synthesis of primary arsines
    发明人:KANJOLIA RAVINDRA K; HUI BENJAMIN C
    权利人:CVD INC
    摘要:Disclosed is a method for producing, from an aqueous basic composition, a primary arsine having one hydrocarbyl group bonded directly to As, the basic composition having been obtained from the combination of components comprising an alkali metal arsenite and a reactive hydrocarbyl halide by combining the aqueous composition with an acidic, nascent hydrogen-generating reducing agent to produce the primary arsine directly from the aqueous composition without isolation of the primary arsonic acid intermediate.

    专利号:US-9768333-B2
    优先权日:2009-02-03
    标题:Microbially-mediated method for synthesis of non-oxide semiconductor nanoparticles
    发明人:PHELPS TOMMY J; LAUF ROBERT J; MOON JI-WON; RONDINONE ADAM JUSTIN; LOVE LONNIE J; DUTY CHAD EDWARD; MADDEN ANDREW STEPHEN; LI YILIANG; IVANOV ILIA N; RAWN CLAUDIA JEANETTE
    权利人:UT BATTELLE LLC; UNIV TENNESSEE RES FOUND
    摘要:The invention is directed to a method for producing non-oxide semiconductor nanoparticles, the method comprising: (a) subjecting a combination of reaction components to conditions conducive to microbially-mediated formation of non-oxide semiconductor nanoparticles, wherein said combination of reaction components comprises i) anaerobic microbes, ii) a culture medium suitable for sustaining said anaerobic microbes, iii) a metal component comprising at least one type of metal ion, iv) a non-metal component comprising at least one non-metal selected from the group consisting of S, Se, Te, and As, and v) one or more electron donors that provide donatable electrons to said anaerobic microbes during consumption of the electron donor by said anaerobic microbes; and (b) isolating said non-oxide semiconductor nanoparticles, which contain at least one of said metal ions and at least one of said non-metals. The invention is also directed to non-oxide semiconductor nanoparticle compositions produced as above and having distinctive properties.

    专利号:US-4473708-A
    优先权日:1981-07-09
    标题:Preparation of ketozines using organoarsenic compounds
    发明人:KURIYAMA YASUHISA; KAKUDA MINORU; NITOH SHOICHI
    权利人:MITSUBISHI GAS CHEMICAL CO
    摘要:A process for preparing a ketazine useful as an intermediate for the synthesis of hydrazine is disclosed. The process comprises reacting an aliphatic or aromatic ketone with ammonia and hydrogen peroxide in the presence of a catalyst of an arsenic compound to produce a corresponding ketazine.

    专利号:WO-2012030642-A2
    优先权日:2010-09-02
    标 题:Microbially-mediated method for synthesis of non-oxide semiconductor nanoparticles

    专利号:US-2010330367-A1
    优先权日:2009-02-03
    标题:Microbially-mediated method for synthesis of non-oxide semiconductor nanoparticles

    专利号:UA-120311-C2
    优先权日:2018-01-10
    标 题 :METHOD OF SYNTHESIS OF 3,4- AND 3,6-DIHYDRO-2H-THIOPYRAN-1,1-DIOXIDES
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    主要参考文献


    1: Jaworek K, Czaplicka M, Bratek Ł. Decomposition of phenylarsonic acid by AOP processes: degradation rate constants and by-products. Environ Sci Pollut Res Int. 2014 Oct;21(20):11917-23. doi: 10.1007/s11356-014-2983-8. Epub 2014 May 15.
    3: HOEKENGA MT. Trial of poly(methylene-4-hydroxy-benzenearsonic acid) in amebiasis. South Med J. 1957 Apr;50(4):536-9. doi: 10.1371/journal.pone.0107147. eCollection 2014.
    6: Nakayama T, Isobe T, Nakamiya K, Edmonds JS, Shibata Y, Morita M. Complexes of diphenylarsinic acid and phenylarsonic acid with thiols: a 1H and 13C NMR study. Magn Reson Chem. 2005 Jul;43(7):543-50. doi: 10.1016/j.bmc.2015.05.007. Epub 2015 May 13.

    合成参考文献

    合成方法参考DOI号:10.1016/j.jorganchem.2008.04.033
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