专利号:US-5068372-A 优先权日:1990-07-16 标 题:Method for the synthesis of primary arsines 发明人:KANJOLIA RAVINDRA K; HUI BENJAMIN C 权利人:CVD INC 摘要:Disclosed is a method for producing, from an aqueous basic composition, a primary arsine having one hydrocarbyl group bonded directly to As, the basic composition having been obtained from the combination of components comprising an alkali metal arsenite and a reactive hydrocarbyl halide by combining the aqueous composition with an acidic, nascent hydrogen-generating reducing agent to produce the primary arsine directly from the aqueous composition without isolation of the primary arsonic acid intermediate.
专利号:US-9768333-B2 优先权日:2009-02-03 标题:Microbially-mediated method for synthesis of non-oxide semiconductor nanoparticles 发明人:PHELPS TOMMY J; LAUF ROBERT J; MOON JI-WON; RONDINONE ADAM JUSTIN; LOVE LONNIE J; DUTY CHAD EDWARD; MADDEN ANDREW STEPHEN; LI YILIANG; IVANOV ILIA N; RAWN CLAUDIA JEANETTE 权利人:UT BATTELLE LLC; UNIV TENNESSEE RES FOUND 摘要:The invention is directed to a method for producing non-oxide semiconductor nanoparticles, the method comprising: (a) subjecting a combination of reaction components to conditions conducive to microbially-mediated formation of non-oxide semiconductor nanoparticles, wherein said combination of reaction components comprises i) anaerobic microbes, ii) a culture medium suitable for sustaining said anaerobic microbes, iii) a metal component comprising at least one type of metal ion, iv) a non-metal component comprising at least one non-metal selected from the group consisting of S, Se, Te, and As, and v) one or more electron donors that provide donatable electrons to said anaerobic microbes during consumption of the electron donor by said anaerobic microbes; and (b) isolating said non-oxide semiconductor nanoparticles, which contain at least one of said metal ions and at least one of said non-metals. The invention is also directed to non-oxide semiconductor nanoparticle compositions produced as above and having distinctive properties.
专利号:US-4473708-A 优先权日:1981-07-09 标题:Preparation of ketozines using organoarsenic compounds 发明人:KURIYAMA YASUHISA; KAKUDA MINORU; NITOH SHOICHI 权利人:MITSUBISHI GAS CHEMICAL CO 摘要:A process for preparing a ketazine useful as an intermediate for the synthesis of hydrazine is disclosed. The process comprises reacting an aliphatic or aromatic ketone with ammonia and hydrogen peroxide in the presence of a catalyst of an arsenic compound to produce a corresponding ketazine.
专利号:WO-2012030642-A2 优先权日:2010-09-02 标 题:Microbially-mediated method for synthesis of non-oxide semiconductor nanoparticles
专利号:US-2010330367-A1 优先权日:2009-02-03 标题:Microbially-mediated method for synthesis of non-oxide semiconductor nanoparticles
专利号:UA-120311-C2 优先权日:2018-01-10 标 题 :METHOD OF SYNTHESIS OF 3,4- AND 3,6-DIHYDRO-2H-THIOPYRAN-1,1-DIOXIDES
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