专利号:US-6551568-B2 优先权日:1998-10-13 标题:Process for the preparation of hydrazine 发明人:BRENGUER GEORGES; JULLIN REMI; RICARD JEAN-PHILIPPE 权利人:ATOFINA 摘要:Process for the preparation of azine and of hydrazine by bringing ammonia, hydrogen peroxide and a reactant carrying a carbonyl group into contact with a working solution, comprising:the treatment of an aqueous stream resulting from the circuit for the regeneration of the said working solution with an amount of acid such that the pH of the said stream is brought to a value of less than 6.4, thenthe recycling of the said stream in the reactor for the synthesis of the azine.
专利号:US-4473708-A 优先权日:1981-07-09 标题:Preparation of ketozines using organoarsenic compounds 发明人:KURIYAMA YASUHISA; KAKUDA MINORU; NITOH SHOICHI 权利人:MITSUBISHI GAS CHEMICAL CO 摘要:A process for preparing a ketazine useful as an intermediate for the synthesis of hydrazine is disclosed. The process comprises reacting an aliphatic or aromatic ketone with ammonia and hydrogen peroxide in the presence of a catalyst of an arsenic compound to produce a corresponding ketazine.
专利号:US-4005179-A 优先权日:1974-07-27 标 题 :Working up synthesis solutions obtained in production of hydrazine 发明人:EICHENHOFER KURT-WILHELM; SCHLIEBS REINHARD; BRANDL HERMANN; KOHNEN HEINRICH 权利人:BAYER AG 摘要:In the production of hydrazine wherein aqueous ammonia is oxidized in the presence of a ketone to form an aqueous solution containing at least one of a hydrazone and a ketazine along with ammonia, the hydrazone and ketazine are concentrated and the hydrazone and ketazine are subsequently hydrolyzed to hydrazine and ketone, the improvement which comprises effecting the concentration of the hydrazone and ketazine by extracting the aqueous solution with a substantially water-immiscible organic solvent whereby the hydrazone and ketazine preferentially enter the water-immiscible solvent, and separating the water-immiscible solvent extract from the aqueous solution. The organic solvent is preferably a higher alcohol, a chlorinated hydrocarbon, benzene or a substitution product thereof. The organic solvent extract, in one or more stages, and optionally with addition of ketone, can be re-extracted with water, hydrolyzed with aqueous acid or subjected to distillation to separate the hydrazine values from the organic solvent.
专利号:FR-2950887-A1 优先权日:2009-10-01 标题:Synthesizing azine compound, useful as an intermediate in industrial process for synthesis of hydrazine hydrate, comprises reacting hydrogen peroxide, nitrogen source and organic compound having carbonyl group, in presence of catalyst
专利号:CN-1081180-A 优先权日:1992-07-10 标题:Synthesis of Hydrazine Hydrate by Catalyzed Oxidation of Ammonia Sodium Hypochlorite
专利号:CN-106995388-A 优先权日:2016-01-26 标题:One-step Synthesis of Hydrazine Hydrate or Carbodiimide by Air Oxidation of Ammonia
参考标题:A Short Synthesis Of The Parp Inhibitor 2-(4-Trifluoro-Methylphenyl)Benzimidazole-4-Carboxamide (Nu1077) 作者:Steven C. Austen,John M. Kane |发布日期:2001.7 摘要:A Four-Step Synthesis Of The Parp Inhibitor 2-(4-Trifluoromethylphenyl)Benzimidazole-4-Carboxamide (1, Nu1077) Is Presented. Condensation Of 2,3-Diaminotoluene And 4-Trifluoromethylbenzaldehyde Afforded 4-Methyl-2-(4-Trifluoromethylphenyl)Benzimidazole. Oxidation Of The Methyl Group With Potassium Permanganate In Warm T-Butanol Afforded The Carboxylic Acid That Was Converted To The Corresponding Carboxamide
合成参考文献
摘要:Inoue, S.; Driess, M., Science of Synthesis Knowledge Updates, (2012) 4, 255. 摘要:Nodzewska, A.; Łaźny, R., Science of Synthesis Knowledge Updates, (2012) 3, 455. 摘要:Nodzewska, A.; Łaźny, R., Science of Synthesis Knowledge Updates, (2012) 3, 457. 摘要:Zhang, F.-G.; Ma, J.-A., Science of Synthesis: Knowledge Updates, (2025) 2.