CAS: 627-70-3; N-(Propan-2-Ylideneamino)Propan-2-Imine

该化合物是一个有机化合物,其特征是存在一个氢化区功能组,该化合物来自2-丙酮(丙酮)和1-甲基乙基羟酸的凝结反应,其典型特征是无色的黄色液体,在有机溶剂中可溶解.该结构的特征是,一个碳基(C=O)组,与一个氢化区连接(C=N-NH)相邻,有助于其再活动,并有可能在有机合成中应用.该化合物在标准条件下可能具有中等波动性和稳定性等特性,但可能对湿度和光度敏感.其氢化区功能允许在各个领域,包括制药和农用化学品领域的潜在应用,在其中它可作为较复杂的分子的中间或建筑块.与许多有机化合物一样,在处理时应采取安全防范措施,因为如果浸入或吸入,可能会对健康造成危害.

结构式图片

欧盟法规

ECHA物质C&L通报REACH预注册

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合成工艺路线路线简述

    📜Trans-Mo(N2)2Me8{16}Anes4置于ch3Oh,(Ch3)2Co体系中,化学反应生成 二丙酮腙
    参考文献:Yoshida,Toshikatsu; Adachi,Tomohiro; Ueda,Tatsuo,Angewandte Chemie,1989,Vol. 101,P. 1053-1055
    标题:Yoshida,Toshikatsu; Adachi,Tomohiro; Ueda,Tatsuo,Angewandte Chemie,1989,Vol. 101,P. 1053-1055

    专利信息


    专利号:US-6551568-B2
    优先权日:1998-10-13
    标题:Process for the preparation of hydrazine
    发明人:BRENGUER GEORGES; JULLIN REMI; RICARD JEAN-PHILIPPE
    权利人:ATOFINA
    摘要:Process for the preparation of azine and of hydrazine by bringing ammonia, hydrogen peroxide and a reactant carrying a carbonyl group into contact with a working solution, comprising:the treatment of an aqueous stream resulting from the circuit for the regeneration of the said working solution with an amount of acid such that the pH of the said stream is brought to a value of less than 6.4, thenthe recycling of the said stream in the reactor for the synthesis of the azine.

    专利号:US-4473708-A
    优先权日:1981-07-09
    标题:Preparation of ketozines using organoarsenic compounds
    发明人:KURIYAMA YASUHISA; KAKUDA MINORU; NITOH SHOICHI
    权利人:MITSUBISHI GAS CHEMICAL CO
    摘要:A process for preparing a ketazine useful as an intermediate for the synthesis of hydrazine is disclosed. The process comprises reacting an aliphatic or aromatic ketone with ammonia and hydrogen peroxide in the presence of a catalyst of an arsenic compound to produce a corresponding ketazine.

    专利号:US-4005179-A
    优先权日:1974-07-27
    标 题 :Working up synthesis solutions obtained in production of hydrazine
    发明人:EICHENHOFER KURT-WILHELM; SCHLIEBS REINHARD; BRANDL HERMANN; KOHNEN HEINRICH
    权利人:BAYER AG
    摘要:In the production of hydrazine wherein aqueous ammonia is oxidized in the presence of a ketone to form an aqueous solution containing at least one of a hydrazone and a ketazine along with ammonia, the hydrazone and ketazine are concentrated and the hydrazone and ketazine are subsequently hydrolyzed to hydrazine and ketone, the improvement which comprises effecting the concentration of the hydrazone and ketazine by extracting the aqueous solution with a substantially water-immiscible organic solvent whereby the hydrazone and ketazine preferentially enter the water-immiscible solvent, and separating the water-immiscible solvent extract from the aqueous solution. The organic solvent is preferably a higher alcohol, a chlorinated hydrocarbon, benzene or a substitution product thereof. The organic solvent extract, in one or more stages, and optionally with addition of ketone, can be re-extracted with water, hydrolyzed with aqueous acid or subjected to distillation to separate the hydrazine values from the organic solvent.

    专利号:FR-2950887-A1
    优先权日:2009-10-01
    标题:Synthesizing azine compound, useful as an intermediate in industrial process for synthesis of hydrazine hydrate, comprises reacting hydrogen peroxide, nitrogen source and organic compound having carbonyl group, in presence of catalyst

    专利号:CN-1081180-A
    优先权日:1992-07-10
    标题:Synthesis of Hydrazine Hydrate by Catalyzed Oxidation of Ammonia Sodium Hypochlorite

    专利号:CN-106995388-A
    优先权日:2016-01-26
    标题:One-step Synthesis of Hydrazine Hydrate or Carbodiimide by Air Oxidation of Ammonia

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    参考标题:A Short Synthesis Of The Parp Inhibitor 2-(4-Trifluoro-Methylphenyl)Benzimidazole-4-Carboxamide (Nu1077)
    作者:Steven C. Austen,John M. Kane |发布日期:2001.7
    摘要:A Four-Step Synthesis Of The Parp Inhibitor 2-(4-Trifluoromethylphenyl)Benzimidazole-4-Carboxamide (1, Nu1077) Is Presented. Condensation Of 2,3-Diaminotoluene And 4-Trifluoromethylbenzaldehyde Afforded 4-Methyl-2-(4-Trifluoromethylphenyl)Benzimidazole. Oxidation Of The Methyl Group With Potassium Permanganate In Warm T-Butanol Afforded The Carboxylic Acid That Was Converted To The Corresponding Carboxamide

    合成参考文献


    摘要:Inoue, S.; Driess, M., Science of Synthesis Knowledge Updates, (2012) 4, 255.
    摘要:Nodzewska, A.; Łaźny, R., Science of Synthesis Knowledge Updates, (2012) 3, 455.
    摘要:Nodzewska, A.; Łaźny, R., Science of Synthesis Knowledge Updates, (2012) 3, 457.
    摘要:Zhang, F.-G.; Ma, J.-A., Science of Synthesis: Knowledge Updates, (2025) 2.
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