CAS: 51694-22-5; (2-Nitrophenyl) Selenocyanate

该化合物是一种有机化合物,其特征是带有硝基化合物和联苯环附属的内聚物功能组;其分子结构特征是,与氰酸盐组(欧元氯化萘)和硝基化合物组(二氧化二氮)结合,位于与苯基环上的内聚亚酸盐相对的圆形位置;该化合物一般是黄色至橙色固体,反映硝基化合物的存在,可能影响其再活动性和溶性. 2-硝基苯乙烯氰酸盐因其在有机合成中的应用而闻名,特别是在制作各种含有蛋白的化合物和作为核聚代作用的试剂时;其结构中的具有独特的特性,例如潜在的生物活动和材料科学中的效用.与许多有机糖化合物一样,必须谨慎处理该物质,并顾及潜在的毒性和环境因素.

结构式图片

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

phenyl selen°Cyanate ethanol potassium cyanide o-nitrobenzeneselenenyl isothi°Cyanate bis(o-nitrophenyl) diselenide 2-nitro-benzenethioselenenic acid-(2-nitro-phenyl ester) o-nitrophenyl selenide 2-nitrobenzeneseleninic acid

合成工艺路线路线简述

    📜偶氮苯六氟磷酸盐置于硝酸,溶剂黄146体系中,化学反应生成 2-硝基苯基丝氰酸酯
    参考文献:Challenger; Peters,Journal Of The Chemical Society,1928,P. 1368
    标题:Challenger; Peters,Journal Of The Chemical Society,1928,P. 1368

    专利信息


    专利号:US-4339388-A
    优先权日:1980-04-22
    标题 :Synthesis of periplanone-B
    发明人:STILL W CLARK
    权利人:STILL W CLARK
    摘要:A synthesis of periplanone-B, a female sex pheromone of the American cockroach, P. americana, is described. Novel compounds which are useful as intermediates in the synthesis of periplanone-B are described including the precursor alcohol, periplanol-B.

    专利号:US-2025171493-A1
    优先权日:2022-03-05
    标题 :Processes for synthesis of withanolides and withaferins and analogs thereof
    发明人:LOPCHUK JUSTIN MATTHEW
    权利人:H LEE MOFFITT CANCER CT & RES
    摘要:The present disclosure provides processes for the synthesis of withanolides such as Withanolide A and Withanolide D.

    专利号:US-5597931-A
    优先权日:1992-03-30
    标 题:Total synthesis of taxol and analogues thereof
    发明人:DANISHEFSKY SAMUEL J; MASTERS JOHN; YOUNG WENDY; LINK J THOMAS; ISAACS RICHARD; SNYDER LAWRENCE B
    权利人:SLOAN KETTERING INST CANCER
    摘要:The present invention provides three basic routes for the total synthesis of taxol having the structure: ##STR1## The present invention also provides the intermediates produced in the above processes, processes for synthesizing these intermediates as well as analogues of taxol and nortaxol.

    专利号:US-2009131498-A1
    优先权日:2005-01-18
    标题 :Enantioselective Synthesis of Merrilactone and Its Analogs
    发明人:DANISHEFSKY SAMUEL J; MENG ZHAOYANG; BIRMAN VLADIMIR
    权利人:DANISHEFSKY SAMUEL J; MENG ZHAOYANG; BIRMAN VLADIMIR
    摘要:This invention provides a method of synthesizing enantioenriched merrilactone A and enantiopure merrilactone A, as well as an improved method of synthesizing racemic merrilactone. This invention also provides intermediate compounds and methods of treating peripheral neuropathies

    专利号:US-8309599-B2
    优先权日:2006-09-08
    标题 :Synthesis of FR901464 and analogs with antitumor activity
    发明人:KOIDE KAZUNORI; ALBERT BRIAN J; SIVARAMAKRISHNAN ANANTHAPADMANABHAN
    权利人:KOIDE KAZUNORI; ALBERT BRIAN J; SIVARAMAKRISHNAN ANANTHAPADMANABHAN; UNIV PITTSBURGH
    摘要:The present invention provides novel analogs of FR901464, as well as an improved methodology for preparing FR901464 and its analogs. These compounds display an anti-cancer activity and are candidates for therapies against a number of disease states associated with dysfunctional RNA splicing.

    专利号:US-4552955-A
    优先权日:1981-06-29
    标题 :Process for the synthesis of 4',5'-unsaturated nucleosides
    发明人:TAKAKU HIROSHI; NODA TAKESHI
    权利人:SANKYO CHEMICAL COMPANY LIMITE
    摘要:Process for the production of 4',5'-unsaturated nucleosides via a novel compound, 5'-Se-(2- or 4-nitrophenyl)-selenonucleoside, is disclosed, said selenonucleoside being represented by the formula ##STR1## wherein R is a hydrogen atom or a hydroxyl group, A is 2- or 4-nitrophenyl group and B is a base.

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Snaith, J. S., Science of Synthesis Knowledge Updates, (2011) 2, 221.
    摘要:Lloyd, C. M.; Dowell, K. F.; Brittain, W. D. G., Science of Synthesis: Modern Strategies in Organofluorine Chemistry, (2025) 2.
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