CAS: 29804-22-6; Disparlure
该化合物是用于控制突飞蛾(Lymantria deppar)的合成异己酮,该化合物的特点是其特定的分子结构,它能够模仿雌性突飞蛾产生的天然异己素以吸引雄性进行交配.分泌物一般是无色的,可粉黄黄色液体,有微弱的气味.它非常有效地扰乱交配模式,从而减少了这种入侵物种的数量.该物质一般用于陷阱或作为交配战略的一部分,使其成为传统杀虫剂的一种无害环境的替代物,它对非目标生物的毒性低及其与目标虫害的特性在综合虫害管理方案中具有重大优势.此外,分泌物在正常环境条件下是稳定的,有助于其在实地应用的有效性.
- 英文名称Disparlure
- 中文名称顺式-7,8-环氧-2-甲基十八烷
- IUPAC名称cis-7,8-Epoxy-2-methyloctadecane
- 其它别名°Ctadecane,7,8-epoxy-2-methyl-, cis- (8CI); Oxirane, 2-decyl-3-(5-methylhexyl)-, cis-; (Z)-7,8-Epoxy-2-methyl°Ctadecane; (?à)-Disparlure; (?à)-cis-Disparlure; 7,8-cis-Epoxy-2-methyl°Ctadecane; Atralymon; Disparlure; Epoxan; cis-7,8-Epoxy-2-methyl°Ctadecane
- CAS编号29804-22-6
- MFCD编号:MFCD00010528
- EINECS号:249-861-6
- FDA UNII编号:1FU18G2315
- 分子式:C19H38O分子量:282.5
- 产品CID: 1279892
物理性质
- 沸点340.6 °C at 760mmHg
- 闪点139.7 °C
- 密度0.844g/cm3
- PSA:12.53
- LogP:6.501
- 折射率1.448
- 蒸汽压0.000168mmHg at 25°C
- 溶解性Chloroform (Slightly), Dichloromethane (Slightly), Hexane (Slightly)
- 外观形态无色油状物
- 储存条件2-8°C
- 产品应用顺式-7,8-环氧-2-甲基十八烷(29804-22-6)的用途:用于有机合成.
- 性质描述顺式-7,8-环氧-2-甲基十八烷(29804-22-6)的性状:有粘性的无色油状液体.沸点(0.25毫米汞柱)146～148°C.闪点61°C.折光率1.4450.比旋光度[α]20D+0.8±0.2°(C＝10,于四氯化碳中).半数致死量(大鼠,经口)＞34600mg/kg(Beroza).
MSDS等安全信息
欧盟法规
ECHA物质C&L通报REACH预注册上下游产品
CAS号51050-50-1 2-Methyl-7-°Cta... | CAS号35354-39-3 顺-2-甲基-7-十八烯 | CAS号35354-38-2 2-甲基-7-十八炔 | CAS号112-29-8 溴代正癸烷 | CAS号870-63-3 1-溴-3-甲基-2-丁烯 | CAS号35354-37-1 1-溴-5-甲基己烷 | CAS号51887-25-3 2-十三炔-1-醇 | CAS号112-54-9 十二醛 | CAS号78389-78-3 2-bromododecanal | CAS号35354-39-3 顺-2-甲基-7-十八烯 | CAS号40302-56-5 2-methyl-cis-7-...合成工艺路线路线简述
海关参考信息
- 2905122000-异丙醇
2909110000-乙醚
2910100000-环氧乙烷
2910200000-氧化丙烯 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:CN-116283834-A
优先权日:2022-09-07
标 题:Synthesis of (2S,3R)-2,3-epoxy-8-methyl-1-nonanol and gypsy moth sex pheromone
专利号:US-2013231499-A1
优先权日:2012-03-05
标题 :Synthesis of z-olefin-containing lepidopteran insect pheromones
专利号:CN-115353437-B
优先权日:2022-08-24
标 题:A kind of synthesis method of cis-2-methyl-7-octadecane and cis-7,8-epoxy-2-methyloctadecane
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
主要参考文献
1: Klosowski DW, Hethcox JC, Paull DH, Fang C, Donald JR, Shugrue CR, Pansick AD, Martin SF. Enantioselective Halolactonization Reactions using BINOL-Derived Bifunctional Catalysts: Methodology, Diversification, and Applications. J Org Chem. 2018 Jun 1;83(11):5954-5968. doi: 10.1021/acs.joc.8b00490. Epub 2018 May 22.
2: Klosowski DW, Martin SF. Correction to "Synthesis of (+)-Disparlure via Enantioselective Iodolactonization". Org Lett. 2018 May 4;20(9):2796. doi: 10.1021/acs.orglett.8b00999. Epub 2018 Apr 11. doi: 10.1021/acs.orglett.7b03911. Epub 2018 Feb 12. Erratum in: Org Lett. 2018 May 4;20(9):2796.
4: Cardé RT, Bau J, Elkinton JS. Comparison of Attraction and Trapping Capabilities of Bucket- and Delta-Style Traps With Different Pheromone Emission Rates for Gypsy Moths (Lepidoptera: Erebidae): Implications for Understanding Range of Attraction and Utility in Surveillance. Environ Entomol. 2018 Feb 8;47(1):107-113. doi: 10.1093/ee/nvx185. doi: 10.1007/s10886-016-0732-9. Epub 2016 Aug 4. Review. doi: 10.1016/j.abb.2016.07.008. Epub 2016 Jul 16. doi: 10.1111/1744-7917.12350. Epub 2016 Jun 21. doi: 10.1007/s10886-014-0396-2. doi: 10.3390/insects6010001.
合成参考文献
参考文献:10.1021/acs.joc.8b00490
摘要:Klosowski DW, Hethcox JC, Paull DH, Fang C, Donald JR, Shugrue CR, Pansick AD, Martin SF. Enantioselective Halolactonization Reactions using BINOL-Derived Bifunctional Catalysts: Methodology, Diversification, and Applications. J Org Chem. 2018 Jun 01;83(11):5954–68.
参考文献:10.1007/s10886-021-01318-2
摘要:Pinnelli GR, Plettner E. Design and Synthesis of Fluorophore-Tagged Disparlure Enantiomers to Study Pheromone Enantiomer Discrimination in the Pheromone-Binding Proteins from the Gypsy Moth, Lymantria dispar. Journal of Chemical Ecology. 2021 Oct 11;48(3):312–22. doi: 10.1007/s10886-021-01318-2.
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