CAS: 16507-61-2; (Z)-1-Chlorooctadec-9-Ene

相似化合物

1002-69-3 112-52-7 2425-54-9

上下游产品

oleoyl alcohol pyridine thionyl chloride benzenec-enyloxy-2-phenyl-2H-phthalazin-1-one4-°Ctadec-9c-enyloxy-2-phenyl-2H-phthalazin-1-one N,N-bis(2-hydroxyethyl)oleylamine 1-Decene 10-chloro-1-decene

📜油醇置于四己基氯化铵,三苯基膦,2,3-二氯-5,6-二氰基-1,4-苯醌体系中,用 二氯甲烷 用作溶剂,以83%的收率获得油酰氯
参考文献:三苯基膦/ 2,3-二氯-5,6-二氰基苯并醌是一种新的,选择性的中性体系,可在卤离子存在下将醇,硫醇和硒醇轻松转化为卤代烷
标题:三苯基膦/ 2,3-二氯-5,6-二氰基苯并醌是一种新的,选择性的中性体系,可在卤离子存在下将醇,硫醇和硒醇轻松转化为卤代烷
摘要:在ch 2 Cl 2中的三苯膦(ph 3 P)和2,3-二氯-5,6-二氰基苯并醌的混合物提供了一种络合物,该络合物在r 4 Nx(x = Cl,Br,I)存在下转化为醇,硫醇在室温下以高收率将硒醇和硒醇转化为其相应的烷基卤.该方法对于在2°的醇存在下1°醇的转化以及在3°的醇,硫醇,环氧化物,三甲基甲硅烷基和四氢吡喃基醚,1,3二噻烷,二硫化物和酰胺.
Doi:10.1016/s0040-4020(02)01089-X

专利信息

专利号:US-8067623-B2
优先权日:2006-07-12
标 题:Ring opening cross-metathesis reaction of cyclic olefins with seed oils and the like
发明人：LEE CHOON WOO
权利人:LEE CHOON WOO; ELEVANCE RENEWABLE SCIENCES
摘要:This invention relates generally to olefin metathesis, and more particularly relates to the ring-opening, ring insertion cross-metathesis of cyclic olefins with internal olefins such as seed oils and the like. In one embodiment, a method is provided for carrying out a catalytic ring-opening cross-metathesis reaction, comprising contacting at least one olefinic substrate with at least one cyclic olefin as a cross metathesis partner, in the presence of a ruthenium alkylidene olefin metathesis catalyst under conditions effective to allow ring insertion cross metathesis whereby the cyclic olefin is simultaneously opened and inserted into the olefinic substrate. The invention has utility in the fields of catalysis, organic synthesis, and industrial chemistry.

专利号:WO-2005049549-A1
优先权日:2003-11-12
标题:Process for the synthesis of cationic lipids

专利号:EP-2271614-A2
优先权日:2008-03-28
标 题:Method for the continuous synthesis of an n-acylated compound, and equipment for implementing said method

专利号:WO-2009118493-A2
优先权日:2008-03-28
标题 :Method for the continuous synthesis of an n-acylated compound, and equipment for implementing said method

专利号:US-2013231499-A1
优先权日:2012-03-05
标题 :Synthesis of z-olefin-containing lepidopteran insect pheromones

专利号:US-8324334-B2
优先权日:2008-08-21
标题 :Telechelic olefin metathesis polymers from renewable feedstocks
发明人：JONES SIMON C; MOTAMEDI FARSHAD J; WANG LI-SHENG; EDGECOMBE BRIAN; GIARDELLO MICHAEL A
权利人:JONES SIMON C; MOTAMEDI FARSHAD J; WANG LI-SHENG; EDGECOMBE BRIAN; GIARDELLO MICHAEL A; MATERIA INC
摘要:Olefin metathesis polymerization reactions are disclosed, and more particularly ring-opening metathesis polymerization of cyclic olefins with olefinic compounds, such as are derived from seed oils and the like, to form telechelic polymers. In one aspect, a method is provided for carrying out a catalytic ring-opening metathesis polymerization reaction, comprising contacting at least one olefinic compound with at least one cyclic olefin, in the presence of a ruthenium alkylidene olefin metathesis catalyst under conditions effective to allow ring-opening metathesis polymerization of the cyclic olefin, whereby the cyclic olefin polymer formed is terminated with the olefinic compound. The invention has utility in the fields of catalysis, organic synthesis, polymer chemistry, and industrial chemistry.