📜八氟丙烷置于溴体系中,化学反应生成 三氟溴甲烷 参考文献:Brice; Pearlson; Simons,Journal Of The American Chemical Society,1949,Vol. 71,P. 2500 标题:Brice; Pearlson; Simons,Journal Of The American Chemical Society,1949,Vol. 71,P. 2500
专利号:US-5859288-A 优先权日:1995-03-24 标 题:Reagent and process for the synthesis of oxysulphide-containing fluorine-containing organic derivatives 发明人:FORAT GERARD; MAS JEAN-MANUEL; SAINT-JALMES LAURENT 权利人:RHONE POULENC CHIMIE 摘要:The invention relates to a reagent which is useful for the synthesis of oxysulphide-containing fluorine-containing organic derivatives by reacting with an oxide of sulphur, especially sulphur dioxide, characterized in that it comprises: a) a fluorocarboxylic acid of formula Ew-CF2-COOH where Ew is an electron-withdrawing group or atom which is at least partially salified by an organic or inorganic cation, and b) an aprotic polar solvent; and in that the content of releasable protons carried by its various components, including their impurities, is at most equal to half the initial molar concentration of the said fluorocarboxylic acid. This reagent can be used by heating in order to form fluorine-containing sulphinic or sulphonic acids.
专利号:US-7371904-B2 优先权日:2004-04-29 标题:Processes for synthesis of 1,3,3,3-tetrafluoropropene 发明人:MA JING JI; MUKHOPADHYAY SUDIP; NAIR HARIDASAN K; TUNG HSUEH S; VAN DER PUY MICHAEL 权利人:HONEYWELL INT INC 摘要:Disclosed is a process for the synthesis of 1,3,3,3-tetrafluoropropene which comprises, in one embodiment, reacting a compound of CF 3 X 1 with a compound of CX 2 Hâ•?CHX 3 , wherein X 1 , X 2 , and X 3 are each independently selected from the group consisting of fluorine, chlorine, bromine and iodine, to produce a reaction product comprising a compound of CF 3 CHâ•?CHX 3 , wherein X 3 is as described above; and when X 3 is not fluorine, fluorinating the compound to produce 1,3,3,3-tetrafluoropropene. The process in another embodiment comprises preparing tetrafluoropropene comprising thermally cracking one or more compounds capable of producing a reaction mixture which preferably comprises diflurocarbene radicals and vinylidene fluoride, and converting said reaction mixture into—tetrafluoropropene (1,3,3,3-tetrafluoropropene).
专利号:US-4756739-A 优先权日:1985-12-21 标题 :Pyridine derivatives and the N-oxides thereof, and the use thereof as intermediates for the synthesis of plant protecting agents 发明人:FUSS ANDREAS; KOCH VOLKER 权利人:HOECHST AG 摘要:The compounds of the formula I (I) in which A denotes N or N->O, Z denotes O or NH, R denotes H, (halo)alkyl, (halo)alkenyl, (halo)alkynyl or alkoxycarbonyl, R1 denotes hydrogen, halogen, amino, -NHOH, hydroxyl, (substituted) phenylazo or a radical of the formulae Y=C=N-, Y1Y2C=N-, Y3NH- or K denotes 0 or 1, and m and n, independently of one another, denote a number from 1 to 4, with the proviso that, when Z-R denotes OH or NH2, (R1)n denotes at least one radical of the formula or represents two radicals, in the 5 or 6 position of the heterocyclic ring, which, in the 5 position, denote halogen and, in the 6 position, denote a radical of the group comprising halogen, amino, hydroxyl or phenylazo, which may be substituted as specified above, are valuable intermediates in the synthesis of plant protection agents.
专利号:US-7714177-B2 优先权日:2004-04-29 标题:Processes for synthesis of 1,3,3,3-tetrafluoropropene 发明人:MUKHOPADHYAY SUDIP; NAIR HARIDASAN K; TUNG HSUEH S; VAN DER PUY MICHAEL 权利人:HONEYWELL INT INC 摘要:Disclosed is a process for the synthesis of 1,3,3,3-tetrafluoropropene comprising: a) reacting a compound of the formula (I) CHFX 2 with a compound of formula (II) CH 2 â•?CF 2 to produce a reaction product comprising a compound of formula (III) CHXFCH 2 CXF 2 , wherein each X is independently selected from the group consisting of chlorine, bromine and iodine; and (b) exposing said compound of formula (III) to reaction conditions effective to convert said compound to 1,3,3,3-tetrafluoropropene.
专利号:US-8128902-B2 优先权日:2011-04-12 标题:Method for the synthesis of anhydrous hydrogen halide and anhydrous carbon dioxide 发明人:TARANCON III GREGORIO 权利人:TARANCON III GREGORIO; MIDWEST REFRIGERANTS LLC 摘要:A method for the synthesis of anhydrous hydrogen halide fluids from organic halide fluids, such as perfluorocarbon fluids and refrigerant fluids, and anhydrous carbon dioxide for the environmentally safe disposition thereof.
专利号:US-8043574-B1 优先权日:2011-04-12 标 题:Apparatus for the synthesis of anhydrous hydrogen halide and anhydrous carbon dioxide 发明人:TARANCON III GREGORIO 权利人:MIDWEST REFRIGERANTS LLC 摘要:An apparatus for the synthesis of anhydrous hydrogen halide fluids from organic halide fluids, such as perfluorocarbon fluids and refrigerant fluids, and anhydrous carbon dioxide for the environmentally safe disposition thereof.