CAS: 70051-38-6; (1Ar,4R,4Ar,7S,7As,7Br)-1,1,4,7-Tetramethyldecahydro-1H-Cyclopropa[e]Azulene-4,7-Diol
该化合物是一种复杂的有机化合物,其特征是独特的双环结构,包括多个手艺中心.该化合物具有一个十氢框架,表明一种完全饱和的碳氢化合物结构,附着多个甲基组,有助于其总体稳定性和缺水性.在4和7个位置上存在氢化物(-OH)组,表明它具有酒精特性,可能影响其溶解性和再活动.分子的立体化学学,以特定的R和结构为标志,在确定其生物活动和与其他物质的相互作用方面发挥着关键作用.这些化合物经常被研究用于制药,香料或有机合成的中间体.
- 英文名称(1Ar,4R,4Ar,7S,7As,7Br)-1,1,4,7-Tetramethyldecahydro-1H-Cyclopropa[e]Azulene-4,7-Diol
- 中文名称4,10-香木兰烷二醇
- IUPAC名称(1aR,4R,4aR,7S,7aS,7bR)-1,1,4,7-tetramethyldecahydro-1H-cyclopropa[e]azulene-4,7-diol
- 其它别名4,10-Aromadendranediol; Aromadendrane-4β,10α-Diol; 10-Aromadendranediol; 1H-Cycloprop[e]Azulene-4,7-Diol, Decahydro-1,1,4,7-Tetramethyl-, (1Ar,4R,4Ar,7S,7As,7Br)-; 10α-Diol; Aromadendrane-4β
- CAS编号70051-38-6
- MFCD编号:MFCD20274807
- 分子式:C15H26O2分子量:238.37
- 产品CID: 1694504
- 产品分类天然产物 → 倍半萜
物理性质
MSDS等安全信息
上下游产品
spathulenol methyl magnesium iodide (+)-11β-hydroxy-apoaromadendrone (-)-apoaromadendrone合成工艺路线路线简述
📜(+)-11β-Hydroxy-Apoaromadendrone置于oxone,Lithium Aluminium Tetrahydride,18-冠醚-6,硫酸,碘,碳酸氢钠,Magnesium,丙酮体系中,化学反应 2.0H,反应生成 4,10-香木兰烷二醇
参考文献:The Synthesis Of Mono-And Dihydroxy Aromadendrane Sesquiterpenes,Starting From Natural (+)-Aromadendrene-Iii
标题:The Synthesis Of Mono-And Dihydroxy Aromadendrane Sesquiterpenes,Starting From Natural (+)-Aromadendrene-Iii
摘要:The Monoalcohols (-)-Globulol (2),(-)-Epiglobulol (3),(-)-Ledol (4),And (+)-Viridiflorol (5) Were Synthesized From (+)-Aromadendrene (1). The Cis-Fused Alloaromadendrone (14),The Key Intermediate Used In The Synthesis Of 4 And 5,Was Obtained From The Trans-Fused Apoaromadendrone (13) Via A Selective Protonation Of The Thermodynamic Enol Trimethylsilylether 15. After Hydroxylation Of The Tertiary C11 Of 13 With Ruo4,(+)-Spathulenol (6),(-)-Allospathulenol (7),And The Aromadendrane Diols 8-11 Could Be Prepared. Compounds 2-11 Were Tested For Antifungal Properties,But Their Activity Was Only Moderate.
DOI:10.1016/s0040-4020(01)88765-2
海关参考信息
- 2905122000-异丙醇
2905143000-叔丁醇
2905399002-1,4-丁二醇
2905141000-异丁醇 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
合成参考文献
参考文献:10.1016/0040-4020(95)00655-r
摘要:Anjaneyulu ASR, Sagar KS, Venugopal MJRV. Terpenoid and steroid constituents of the Indian ocean soft coral Sinularia maxima. Tetrahedron. 1995 Oct;51(40):10997–1010. doi: 10.1016/0040-4020(95)00655-r.
参考文献:10.1248/cpb.37.509
摘要:IWABUCHI H, YOSHIKURA M, KAMISAKO W. Studies on the sesquiterpenoids of Panax ginseng C.A. MEYER. III. Chem. Pharm. Bull. 1989;37(2):509–10. doi: 10.1248/cpb.37.509.
参考文献:10.1016/j.tet.2011.11.058
摘要:Salae A, Rodjun A, Karalai C, Ponglimanont C, Chantrapromma S, Kanjana-Opas A, Tewtrakul S, Fun H. Potential anti-inflammatory diterpenes from Premna obtusifolia. Tetrahedron. 2012 Jan;68(3):819–29. doi: 10.1016/j.tet.2011.11.058.
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