CAS: 4433-01-6; [2,2'-Bipyridine]-3,3'-Dicarboxylic Acid

相似化合物

1762-36-3 39775-31-0 71353-94-1

上下游产品

CAS号2942-59-8 2-氯烟酸 | CAS号66-71-7 1,10-菲罗啉 | CAS号27318-90-7 1,10-菲啰啉-5,6-二酮 | CAS号136869-49-3 2,2’-联吡啶-3,3’-二甲腈 | CAS号39775-31-0 2,2'-联吡啶-3,3'-二羧酸甲酯

2-氯烟酸置于钯 盐酸,Sodium Hydroxide体系中,用 甲醇,水 作为反应溶剂,以48%的收率获得产物2,2'-联吡啶-3,3'-二羧酸
参考文献:Method For The Catalytic Production Of Substituted Bipyridyl Derivatives
标题:Method For The Catalytic Production Of Substituted Bipyridyl Derivatives
摘要:该发明涉及一种通过在酒精存在下,在0-200oc的温度下,将式(iii)的至少一个吡啶转化为双吡啶的制备过程.在该式中,S',S",S'',S"'和s''',独立于彼此,相同或不同,并且为氢,(c1-C18)-烷基,烷氧基-(C1-C18),酰氧基-(C1-C18),芳氧基-(C1-C18),全氟酰氧基-(C1-C8),No2,(c1-C18)-芳基,(c1-C18)-杂环烷基,卤素,羟基,硝基,亚硝基,Cn,Cooh,Cho,Po3H2,So3H,So2R,Sor,Nh2,Nh-烷基-(C1-C18),N-烷基2-(C1-C18),保护胺基,Cf3,Nhco-烷基-(C1-C4),N-烷基-(C1-C4)-Co-烷基-(C1-C4),Coo-烷基-(C1-C18),Conh2,Co-烷基-(C1-C18),Nhcoh,Nhcoo-烷基-(C1-C4),Co-(C1-C18)-芳基,Coo-(C1-C18)-芳基,Chch-Co2-烷基-(C1-C18),Chchco2H,Po-苯基2,Po-烷基2-(C1-C4),(coo−)n(阳离子)n+,(po32−)n(阳离子)2N+,(so3−)n(阳离子)n+和/或(o−)n(阳离子)n+,其中可选地s',S",S'',S"'和/或s''''中的其中一个在彼此之间组成一个或多个脂肪和/或芳香环和/或其中可选地s',S",S'',S"'和/或s''''形成至少一个进一步的式(iii)吡啶的桥梁和/或其中可选地基团s',S",S'',S"'和/或s''''具有上述给定的含义,并且被至少一个基团取代,该基团具有上述给定的s',S",S'',S"'和/或s''''的含义.

专利信息

专利号:US-8759245-B2
优先权日:2006-11-27
标题:Method for preparing porous organic-inorganic hybrid materials, porous organic-inorganic hybrid materials obtained by the method and catalytic uses of the materials
发明人：CHANG JONG-SAN; HWANG YOUNG KYU; JHUNG SUNG HWA; HONG DO-YOUNG; SEO YOU-KYUNG; FEREY GERARD; SERRE CHRISTIAN
权利人:CHANG JONG-SAN; HWANG YOUNG KYU; JHUNG SUNG HWA; HONG DO-YOUNG; SEO YOU-KYUNG; FEREY GERARD; SERRE CHRISTIAN; KOREA RES INST CHEM TECH
摘要:The present invention relates to a method for preparing iron-containing porous organic-inorganic hybrid materials where the organic compound ligand is bonded to a central metal and has a large surface area and pores of molecular size or nano size, by irradiating microwaves instead of heat treatments such as the conventional electric heating, etc. as the heat source of the hydrothermal or solvothermal synthesis reaction, after reacting a metal or metal salt and organic compound to form crystal nuclei by a predetermined pre-treatment operation in the presence of a solvent. In another aspect, a method of the present invention further comprises the step of purifying the obtained porous organic-inorganic hybrid materials by treating them with inorganic salt. In particular, a method of the present invention is characterized by not using a hydrofluoric acid.

专利号:CN-105669729-B
优先权日:2016-03-09
标题 :A heterometallic organic framework material of 2,2'-bipyridine-3,3'dicarboxylic acid and its synthesis method

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优先权日:2008-12-24
标题:Synthesis and Structure of an Inorganic-Organic Coordination Polymer Containing Praseodymium

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优先权日:2016-05-09
标 题:A kind of metal organic framework material containing bipyridine carboxylic acid and synthesis method thereof

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优先权日:2014-05-05
标题 :A kind of carboxylic acid double-ligand rare earth coordination polymer photoluminescent body and its synthesis method