CAS: 2234-20-0; 2,4-Dimethyl-1-Vinylbenzene

该化合物是一种有机化合物,其特征是附于m-xyle结构的乙烯(-CH=CH2)组,该组由含有两个甲基组组成的苯环组成,其元体位置为两个甲基组组成.该化合物无色可粉黄,具有典型的芳香气味,在有机溶剂中可溶解,但在水中的溶解度有限.4-Vinyl-m-xyne主要用作聚合物和共聚物生产中的单体,特别是在交叉关联材料和树脂的合成中.它可以通过其乙烯组进行聚合,使其在各种工业应用中具有价值,包括涂层,粘合剂和塑料.此外,它可能具有中度的毒性,在处理时应当采取适当的安全措施.与许多芳烃化合物一样,重要的是考虑其对环境的影响及其在使用和处置过程中的潜在健康影响.

结构式图片

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

CAS号193277-05-3 2,4-dimethyl-1-... | CAS号10224-95-0 1,1-bis-(2,4-di... | CAS号108-38-3 间二甲苯 | CAS号6597-59-7 2,4-二甲基苯乙基乙醇 | CAS号14352-93-3 2-(2,4-dimethyl... | CAS号1779-49-3 甲基三苯基溴化膦 | CAS号15764-16-6 2,4-二甲基苯甲醛 | CAS号6331-04-0 2,4-二甲基苯乙酸 | CAS号611-01-8 2,4-二甲基苯甲酸 | CAS号1811-85-4 3-(2,4-二甲基苯基)丙酸 | CAS号150254-19-6 2-(2,4-dimethyl... | CAS号874-41-9 4-乙基间二甲苯 | CAS号50-00-0 甲醛 | CAS号15764-16-6 2,4-二甲基苯甲醛 | CAS号898759-33-6 2,4-DIMETHYL(1,... | CAS号51042-16-1 1-[2-(2,4-dimet... | CAS号103-30-0 反式-1,2二苯乙烯 | CAS号24942-82-3 trans-1-phenyl-...

合成工艺路线路线简述

    📜2-(2,4-二甲基苯基)乙酸甲酯置于氢氧化钾,乙醇,Sodium体系中,化学反应生成2,4-二甲基苯乙烯
    参考文献:Harispe,Annales De Chimie (Cachan,France),1936,Vol. <11>6,P. 249,303
    标题:Harispe,Annales De Chimie (Cachan,France),1936,Vol. <11>6,P. 249,303

    海关参考信息

    专利信息


    专利号:US-6794534-B2
    优先权日:2000-06-23
    标题:Synthesis of functionalized and unfunctionalized olefins via cross and ring-closing metathesis
    发明人:GRUBBS ROBERT H; CHATTERJEE ARNAB K; MORGAN JOHN P; SCHOLL MATTHIAS; CHOI TAE-LIM
    权利人:CALIFORNIA INST OF TECHN
    摘要:The invention is directed to the cross-metathesis and ring-closing metathesis reactions between geminal disubstituted olefins and terminal olefins, wherein the reaction employs a Ruthenium or Osmium metal carbene complex. Specifically, the invention relates to the synthesis of α-functionalized or unfunctionalized olefins via intermolecular cross-metathesis and intramolecular ring-closing metathesis using a ruthenium alkylidene complex. The catalysts preferably used in the invention are of the general formula n wherein: n M is ruthenium or osmium; n X and X 1 are each independently an anionic ligand; n L is a neutral electron donor ligand; and, n R, R 1 R 6 , R 7 , R 8 , and R 9 are each independently hydrogen or a substituent selected from the group consisting of C 1 -C 20 alkyl, C 2 -C 20 alkenyl, C 2 -C 20 alkynyl, aryl, C 1 -C 20 carboxylate, C 1 -C 20 alkoxy, C 2 -C 20 alkenyloxy, C 2 -C 20 alkynyloxy, aryloxy, C 2 -C 20 alkoxycarbonyl, C 1 -C 20 alkylthio, C 1 -C 20 alkylsulfonyl and C 1 -C 20 alkylsulfinyl.

    专利号:US-8669356-B2
    优先权日:2009-10-21
    标 题 :Linker and support for solid phase synthesis of nucleic acid
    发明人:HAYAKAWA YOSHIHIRO; TSUKAMOTO MASAKI; MORI KENJIRO; MINOMI KENJIRO; MAETA ERI; KONISHI TATSUYA
    权利人:HAYAKAWA YOSHIHIRO; TSUKAMOTO MASAKI; MORI KENJIRO; MINOMI KENJIRO; MAETA ERI; KONISHI TATSUYA; NITTO DENKO CORP; UNIV NAGOYA NAT UNIV CORP
    摘要:The invention provides a universal linker capable of synthesizing nucleic acid having a phosphate group at the 3′ terminal, a universal support carrying the linker, and a synthesis method of nucleic acid using the universal support. The linker for solid phase synthesis of nucleic acid contains a compound represented by at least one of the following formulae n nwherein each symbol is as defined in the specification.

    专利号:US-8835656-B2
    优先权日:2012-01-30
    标 题 :Linker and support for solid phase synthesis of nucleic acid
    发明人:TSUKAMOTO MASAKI; SUZUKI NORITAKA; HAYAKAWA YOSHIHIRO; MAETA ERI; MORI KENJIRO; MINOMI KENJIRO
    权利人:NITTO DENKO CORP; UNIV NAGOYA NAT UNIV CORP
    摘要:The invention provides a universal linker capable of synthesizing nucleic acid having a hydroxy group at the 3′ terminal, a universal support carrying the linker, and a synthesis method of nucleic acid using the universal support. The linker contains a compound represented by the formula n nwherein each symbol is as defined in the specification.

    专利号:US-2004241251-A1
    优先权日:2001-05-04
    标 题:Random or block co-or terpolymers produced by using of metal complex catalysts
    发明人:THIELE SVEN K H; MONROY VICTOR M; WILSON DAVID R
    摘要:Random or block co- or terpolymers produced by using metal complex catalysts in a reaction of one conjugated diene monomer with one aromatic Random or block co- or terpolymers produced by using metomers with one aromatic α-olefin or terpolymers of one conjugated diene monomer with one aromatic α-olefin and one aliphatic α-olefin by using metal complexes comprising metals of group 3 to 10 of the Periodic System of the Elements in combination with activators and optionally a support material. More particularly the metal complexes used for the synthesis of co- or terpolymer are lanthanide metals. Even more particularly diene monomer(s) and aromatic α-olefin monomer(s) such as, but not limited to, butadiene and styrene or isoprene and styrene are copolymerized giving random or block copolymers or butadiene, styrene and isoprene are terpolymerized giving random or block terpolymers using metal complexes comprising lanthanide metals in combination with activators and optionally a support material. Preferably random co- or terpolymers are formed.

    专利号:US-11098145-B2
    优先权日:2015-05-12
    标题:Method for the synthesis of a copolymer, copolymer, rubber mixture, and use thereof
    发明人:HERZOG KATHARINA; MUELLER LENA; RECKER CARLA; PRUSS NOA; CONRAD CATHRIN SONJA; VANA PHILLIPP
    权利人:CONTINENTAL REIFEN DEUTSCHLAND GMBH
    摘要:Disclosed are processes for preparing a copolymer, a copolymer prepared by the process, a sulfur-crosslinkable rubber mixture, and the use of the sulfur-crosslinkable rubber mixture for production of motor vehicle tires. In one embodiment, the monomer has the formula: A-S-P, wherein A is a chemical group containing at least one aliphatic double bond, S is a sulfur atom, and P is a protecting group.

    专利号:US-10494336-B2
    优先权日:2015-05-12
    标题:Monomer for copolymerization with alkenes, dienes, vinyl compounds and/or vinylidene compounds, method for the synthesis of a copolymer, copolymer, rubber mixture and use thereof
    发明人:HERZOG KATHARINA; MUELLER LENA; RECKER CARLA; PRUSS NOA; CONRAD CATHRIN SONJA; VANA PHILLIPP
    权利人:CONTINENTAL REIFEN DEUTSCHLAND GMBH
    摘要:Disclosed are monomers for copolymerization with alkenes, dienes, vinyl compounds, and/or vinylidene compounds, a process for preparing a copolymer, a copolymer prepared by the process, a sulfur-crosslinkable rubber mixture, and the use of the sulfur-crosslinkable rubber mixture for production of motor vehicle tires. In one embodiment, the monomer has the formula A-S—P, wherein A is a chemical group containing at least one Câ•?C aliphatic double bond, S is a sulfur atom, and P is a protecting group.

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    合成参考文献


    摘要:Amatore, M.; Aubert, C.; Malacria, M.; Petit, M., Science of Synthesis Knowledge Updates, (2012) 3, 88.
    摘要:Uemura, M., Science of Synthesis Knowledge Updates, (2010) 4, 20.
    摘要:Wirth, T.; Singh, F. V., Science of Synthesis Knowledge Updates, (2017) 1, 406.
    摘要:Brown, J. M.; Nguyen, B. N., Science of Synthesis: Stereoselective Synthesis, (2011) 1, 306.
    摘要:Huang, H.; Deng, G.-J.; Ji, X., Science of Synthesis: Knowledge Updates, (2024) 2, 461.
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