2-Chlorosulfonyl-7-Fluoro-5-Ethoxy[1,2,4]Triazolo[1,5-C]-Pyrimidine,2-氨基-3-氯苯甲酸甲酯置于s,S-Dimethyl-N-(2-Methoxycarbonyl-6-Chlorophenyl)Sulfilimine 吡啶体系中,用 二氯甲烷 用作溶剂,化学反应生成氯酯磺草胺 参考文献:N-Arylsulfilimine Compounds And Their Use As Catalysts In The 标题:N-Arylsulfilimine Compounds And Their Use As Catalysts In The 摘要:N-芳基磺酰亚胺化合物,例如s,S-二甲基-N-(2,6-二氯苯基)磺酰亚胺,已被制备并发现可催化芳香磺酰氯化合物,例如2-氯磺酰基-7-氟-5-乙氧基[1,2,4]三唑[1,5-C]嘧啶,与芳香胺化合物,例如2,6-二氯苯胺,形成n-芳基芳基磺酰胺化合物,例如n-(2,6-二氯苯基)-7-氟-5-乙氧基[1,2,4]三唑[1,5-C]嘧啶-2-磺酰胺.N-芳基磺酰亚胺催化剂的芳基部分和芳香胺化合物的芳基部分通常被选为相同的.
专利号:WO-2024256370-A1 优先权日:2023-06-13 标 题 :Synthesis of glufosinate using an amidase-based process 发明人:ZIMMERMANN GUNTHER; POTT MORITZ STEFAN 权利人:BASF SE 摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.
专利号:US-2025120400-A1 优先权日:2021-12-10 标题:Synthesis of glufosinate using a hydantoinase-based process 发明人:DITRICH KLAUS; BREUER MICHAEL; POTT MORITZ STEFAN; ZIMMERMANN GUNTHER; SEEMAYER STEFAN 权利人:BASF SE 摘要:The present invention relates to a method of manufacturing glufosinate, comprising the steps of hydrolysing a hydantoin with a Hydantoinase enzyme to form a N-carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N-carbamoyl amino acid compound.
专利号:US-11919928-B2 优先权日:2016-03-16 标题 :Method for producing dihydrotentoxin 发明人:KUBO TAKASHI; MACHIDA MASAYUKI; FUJIOKA TOMONORI; YAMAGUCHI Shigenari; KAWAI KIYOSHI 权利人:KUMIAI CHEMICAL INDUSTRY CO 摘要:An object of the present invention is to identify an enzyme having activity of synthesizing dihydrotentoxin that is a tentoxin precursor and an enzyme having activity of synthesizing tentoxin using dihydrotentoxin as a substrate. The present invention concerns a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 16 and having activity of nonribosomal peptide synthesis of dihydrotentoxin and a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 18 and having activity of converting dihydrotentoxin to tentoxin.
专利号:US-2021386068-A1 优先权日:2018-11-07 标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides 发明人:KISTER JEREMY; SATCHIVI NORBERT M 权利人:CORTEVA AGRISCIENCE LLC 摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.
专利号:US-2021352899-A1 优先权日:2018-11-07 标题 :Compositions comprising pyridine carboxylate herbicides and fatty acid and lipid synthesis inhibitor herbicides 发明人:KISTER JEREMY; SATCHIVI NORBERT M 权利人:CORTEVA AGRISCIENCE LLC 摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof.
专利号:ES-2717283-T3 优先权日:2012-07-24 标 题:Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid or a derivative thereof and herbicides inhibitors of VLCFA synthesis and synthesis of fatty acids / lipids
1: Zhang Y, Zhang J, Shi B, Li B, Du Z, Wang J, Zhu L, Wang J. Effects of cloransulam-methyl and diclosulam on soil nitrogen and carbon cycle-related microorganisms. J Hazard Mater. 2021 Sep 15;418:126395. doi: 10.1016/j.jhazmat.2021.126395. Epub 2021 Jun 12. 188(3):168. doi: 10.1007/s10661-016-5168-8. Epub 2016 Feb 16. 322:138242. doi: 10.1016/j.chemosphere.2023.138242. Epub 2023 Feb 23. 897(1-2):405-13. doi: 10.1016/s0021-9673(00)00818-9. 48(6):2532-46. doi: 10.1021/jf9909611. 11(4):467. doi: 10.3390/plants11040467. 7: Johnson TC, Martin TP, Mann RK, Pobanz MA. Penoxsulam--structure-activity relationships of triazolopyrimidine sulfonamides. Bioorg Med Chem. 2009 Jun 15;17(12):4230-40. doi: 10.1016/j.bmc.2009.02.010. Epub 2009 Feb 14. 30(1):8-14. doi: 10.1002/jssc.200600271. 1100(2):236-42. doi: 10.1016/j.chroma.2005.09.053. Epub 2005 Oct 5.
合成参考文献
摘要:Krieger, R. (ed.). Handbook of Pesticide Toxicology. Volume 2, 2nd ed. 2001. Academic Press, San Diego, California., p. 1654 摘要:Franke C et al; Chemosphere 29: 1501-14 (1994) 参考文献:10.1016/j.jhazmat.2021.126395 摘要:Zhang Y, Zhang J, Shi B, Li B, Du Z, Wang J, Zhu L, Wang J. Effects of cloransulam-methyl and diclosulam on soil nitrogen and carbon cycle-related microorganisms. J Hazard Mater. 2021 Sep 15;418():126395. doi: 10.1016/j.jhazmat.2021.126395.