📜辰砂(即硫化汞晶体),双(三甲基硫化硅) 反应生成三硫化钼 参考文献:Auborn J. J.; Barberio Y. L.; Hansan K. J.; Schleich D. M.; Martin M. J.,J. Electrochem. Soc.,134,(1987) N 3,580-585 标题:Auborn J. J.; Barberio Y. L.; Hansan K. J.; Schleich D. M.; Martin M. J.,J. Electrochem. Soc.,134,(1987) N 3,580-585
专利信息
专利号:US-2015182952-A1 优先权日:2013-12-18 标 题 :OBTENTION OF LOW LOADING CATALYSTS FOR DEEP HYDROCARBONS HYDRODESULFURIZATION BASED OF CoMoS, WITH NiMoS HYDRODENITROGENANT ADDITIVE, SUPPORTED ON THREE-DIMENSIONAL NANOSTRUCTURED MESOPOROUS MATERIALS 发明人:ALVAREZ CONTRERAS LORENA; AGUILAR ELGUEZABAL ALFREDO; IBARRA MARTINEZ ABRIL 权利人:ALVAREZ CONTRERAS LORENA; AGUILAR ELGUEZABAL ALFREDO; IBARRA MARTINEZ ABRIL 摘要:The present invention shows a synthesis method for a highly dispersed supported catalyst over a KIT-6 type nanostructured mesoporous oxide with elements from Groups IIIA or IVA, or IVB. The method includes the synthesis of the support, the incorporation of CoMo and NiMo active phases through impregnation to pore volume, assisted by ultrasound, calcination at controlled conditions in order to obtain a phase of hydrated trioxide molybdenum or molybdic acid, which facilitates the subsequent sulfihydration and the mechanical mixing of a CoMoS/support with a hydrodenitrogenant NiMoS/support additive. The obtained catalysts exhibit a catalytic activity mainly in reactions of hydrotreatment, hydrodesulfurization, and hydrodenitrogenation.
专利号:US-9290425-B2 优先权日:2013-06-20 标题 :Production of mixed alcohols from synthesis gas 发明人:TIJM PETER J; STEVENS REX R 权利人:TIJM PETER J; STEVENS REX R; STANDARD ALCOHOL COMPANY OF AMERICA INC 摘要:Higher mixed alcohols are produced from syngas contacting a catalyst in a reactor. The catalyst has a first component of molybdenum or tungsten, a second component of vanadium, a third component of iron, cobalt, nickel or palladium and optionally a fourth component of a promoter. The first component forms alcohols, while the vanadium and the third component stimulates carbon chain growth to produce higher alcohols.
专利号:US-4752622-A 优先权日:1984-07-30 标题:Process for producing alcohols from synthesis gas 发明人:STEVENS REX R 权利人:DOW CHEMICAL CO 摘要:A process for making alcohols comprising contacting a mixture of hydrogen and carbon monoxide with a catalyst comprising: (1) as a first component, at least one element selected from the group consisting of molybdenum and tungsten in free or combined form; (2) as a second component, at least one element selected from the group consisting of iron, cobalt and nickel in free or combined form; (3) as a third component, a promoter comprising an alkali or alkaline earth element in free or combined form; and optionally (4) as a fourth component, a support; to form an alcohol fraction boiling in the range of motor gasoline in at least 20 percent CO2 free carbon selectivity.
专利号:US-4749724-A 优先权日:1983-03-18 标 题:Process for producing alcohols from synthesis gas 发明人:QUARDERER GEORGE J; COCHRAN GENE A 权利人:DOW CHEMICAL CO 摘要:A Fischer-Tropsch reaction to form alcohols from hydrogen and carbon monoxide, using a catalyst containing: (1) at least one element selected from the group consisting of molybdenum, tungsten and rhenium in free or combined form; (2) a promoter comprising an alkali or alkaline earth element in free or combined form; and optionally (3) a support; forms an alcohol fraction boiling in the range of motor gasoline in at least about 20 percent CO2 free carbon selectivity.
专利号:US-4882360-A 优先权日:1984-07-30 标题:Process for producing alcohols from synthesis gas 发明人:STEVENS REX R 权利人:DOW CHEMICAL CO 摘要:A process for making alcohols comprising contacting a mixture of hydrogen and carbon monoxide with a catalyst comprising: (1) as a first component, at least one element selected from the group consisting of molybdenum and tungsten in free or combined form; (2) as a second component, at least one element selected from the group consisting of iron, cobalt and nickel in free or combined form; (3) as a third component, a promoter comprising an alkali or alkaline earth element in free or combined form; and optionally (4) as a fourth component, a support; to form an alcohol fraction boiling in the range of motor gasoline in at least 20 percent CO2 free carbon selectivity.
专利号:US-5116592-A 优先权日:1986-06-02 标题:Fluorinated carbons and uses thereof 发明人:WEINBERG NORMAN L 权利人:ELECTROSYNTHESIS CO INC 摘要:Specifically fluorinated carbons have enhanced chemical and/or electrochemical stabilities to corrosion, improved hydrophobicity, lubricating properties, etc., making them especially useful as electrodes in both energy consuming and energy producing electrochemical cells, such as batteries, fuel cells and cells for the electrochemical synthesis of organic and inorganic chemical compounds. The specifically fluorinated carbons may also be employed as lubricants, in fabrication of reactors for generating energy, chemical reaction vessels and as catalyst supports.
参考文献:10.1038/ncomms9668 摘要:Fei H, Dong J, Arellano-Jiménez MJ, Ye G, Dong Kim N, Samuel ELG, Peng Z, Zhu Z, Qin F, Bao J, Yacaman MJ, Ajayan PM, Chen D, Tour JM. Atomic cobalt on nitrogen-doped graphene for hydrogen generation. Nature Communications. 2015 Oct 21;6(1):8668. doi: 10.1038/ncomms9668.