CAS: 10112-91-1; Dimercury Dichloride

该化合物是一种配方汞2Cl2的无机化合物.它看起来是一种白色或黄色黄色晶体固体,在水中的溶解性较低,因此值得注意,在各种化学应用中,它是有用的试剂.卡洛梅主要用于电化学细胞,作为参考电极,并用于准备其他汞化合物.它与其他汞化合物相比,其毒性相对较低,但由于汞接触的可能性,仍应谨慎行事.该化合物在正常条件下保持稳定,但可分解取暖,释放出有毒汞蒸气.除了其化学应用外,卡洛梅在医学中具有历史意义,特别是在19世纪,它被用作炼液和抗菌剂.然而,由于汞接触的安全考虑,其使用量有所下降.

结构式图片

欧盟法规

《欧盟PIC法规》统一分类与标签ECHA物质工作场所安全标识要求ECHA物质OtherC&L通报REACH预注册废弃物危险特性清单

合成工艺路线路线简述

    氰化汞置于亚磷酸体系中,用 水 用作溶剂,以>99的收率获得氯化亚汞
    参考文献:Douris,R. G.,Comptes Rendus Hebdomadaires Des Seances De L'Academie Des Sciences,1941,Vol. 212,P. 240-242
    标题:Douris,R. G.,Comptes Rendus Hebdomadaires Des Seances De L'Academie Des Sciences,1941,Vol. 212,P. 240-242

    专利信息


    专利号:US-10925977-B2
    优先权日:2006-10-05
    标 题 :Efficient synthesis of chelators for nuclear imaging and radiotherapy: compositions and applications
    发明人:YANG DAVID J; YU DONGFANG; THOMPSON ANDREW S
    权利人:YANG DAVID J; YU DONGFANG; THOMPSON ANDREW S; CEIL POINT LLC; UNIV TEXAS
    摘要:Novel methods of synthesis of chelator-targeting ligand conjugates, compositions comprising such conjugates, and therapeutic and diagnostic applications of such conjugates are disclosed. The compositions include chelator-targeting ligand conjugates optionally chelated to one or more metal ions. Methods of synthesizing these compositions in high purity are also presented. Also disclosed are methods of imaging, treating and diagnosing disease in a subject using these novel compositions, such as methods of imaging a tumor within a subject and methods of diagnosing myocardial ischemia.

    专利号:WO-9855532-A1
    优先权日:1997-06-03
    标题:Electrochemical synthesis of electrically conductive polymers and products thereof
    发明人:KINLEN PATRICK J
    权利人:ZIPPERLING KESSLER & CO
    摘要:The electrochemical synthesis of electrically conductive polyaniline salts is provided. The method comprises electrochemical oxidation of an aromatic heterocyclic or aniline monomer oxidatively polymerizable to an intrinsically conductive polymer in the presence of water, an organic acid and, optionally, an organic solvent and an electron transfer mediator. Depending upon the water solubility of the organic acid, ICP salts soluble in either water or xylenes are produced.

    专利号:WO-2012085174-A1
    优先权日:2010-12-22
    标题:Process for the electrochemical synthesis of hydrogen peroxide and use of a catalyst therefore
    发明人:SCHIFFRIN DAVID JORGE; STASZAK-JIRKOVSKY JAKUB; HALASA MATEJ
    权利人:SOLVAY; SCHIFFRIN DAVID JORGE; STASZAK-JIRKOVSKY JAKUB; HALASA MATEJ
    摘要:A process for the electrochemical synthesis of hydrogen peroxide, comprising reacting oxygen and hydrogen in the presence of a catalyst comprising at least gold and palladium deposited on a carrier, wherein the molar ratio of gold to palladium is higher than 1:1.

    专利号:US-2023402618-A1
    优先权日:2020-10-27
    标 题:Method for synthesis of porous monoliths of transition-metal-doped-noble-metal
    发明人:SINGH KIRANPAL; BHAT YASH RAJESH; CHARAYA HEMANT; CHAUDHARI VIJAY RAMAN
    权利人:LOG 9 MATERIALS SCIENT PRIVATE LIMITED
    摘要:The embodiment herein provides a simple, one-pot and scalable methodology for the synthesis of porous monoliths of Transition-metal-doped-noble-metal nanoparticles for cathode catalyst in a metal-air battery, PEMFCs, AFCs, and anode catalyst in water electrolysers. Silver is used as a base material on which doping is done with the transition metals selected from Cu, Co, Mn, Fe, and Ni.

    专利号:US-10871463-B2
    优先权日:2016-09-12
    标题:Preparation method based on simultaneous package of target substance and synthesis of MOFs with redox activity
    发明人:WANG ZONGHUA; YU GEGE; XIA JIANFEI; GONG SHIDA
    权利人:UNIV QINGDAO
    摘要:A preparation method based on simultaneous package of a target substance and synthesis of MOFs with redox activity, wherein methylene blue is selected as an organic target molecule, the methylene blue is packaged in the MOFs when the MOFs are synthesized by using a one-pot method to obtain ZIF-8 modified by the methylene blue. The drawback that above-mentioned MOFs material does not have electrical conductivity is overcome, the method is simple, rapid and low in cost, and the prepared product can accurately, sensitively, simply and quickly detect dopamine, and a new development direction is provided for researches in the fields of biological detection and chemical analysis, etc.

    专利号:US-6350875-B1
    优先权日:1999-08-16
    标 题:Synthesis of cyclooctatetraene derivatives and their use as electron transporters in organic light emitting diodes
    发明人:WEBER WILLIAM P; LU PING; THOMPSON MARK E; HONG HAIPING
    权利人:UNIV SOUTHERN CALIFORNIA
    摘要:The synthesis of asymmetric tetrasubstituted cyclooctatetraenes (“COTsâ€?) and the use of said compounds in organic light emitting diodes is reported, wherein said COTs represent a class of wide gap electron transporters that are readily deposited in vacuum.
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    合成参考文献


    参考文献:10.2116/analsci.27.727
    摘要:Li Y, Yang W, Fan M, Liu A. A Sensitive Label-free Amperometric CEA Immunosensor Based on Graphene-Nafion Nanocomposite Film as an Enhanced Sensing Platform. Analytical Sciences. 2011 Jul 10;27(7):727–31. doi: 10.2116/analsci.27.727.
    参考文献:10.2116/analsci.27.745
    摘要:Martín-Merás ID, Rodríguez-Cáceres MI, Hurtado-Sánchez MDC. First-Order Multivariate Calibration Applied to the Simultaneous Fluorometric Determination of the Anticancer Agents CPT-11 and SN-38 in Serum and Urine Samples. Analytical Sciences. 2011 Jul 10;27(7):745–9. doi: 10.2116/analsci.27.745.
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