CAS: 927-83-3; Azo-T-Butane

该化合物是一种有机化合物,由于有阿索功能组(-N=N-)的存在,被归类为氮化合物,该物质具有对称结构的特点,由两个与中祖联系相连的2-甲基丙基基化合物组成,通常在室内温度下是无色的,可与黄色的黄色液体无异,在正常条件下以其稳定性而闻名;但是,该化合物可以在接触热或光时分解,释放氮气;该化合物主要用作聚合工艺的激进启动器,使其在生产各种塑料和树脂过程中具有价值;此外,该物质在水中可能表现出低溶性,但在有机溶剂中可溶性;在处理该化合物时,需要安全防范,因为如果浸入或吸入,可能会有危险,因此应采取适当的保护措施避免皮肤和眼睛接触.

结构式图片

物理性质

MSDS等安全信息

欧盟法规

ECHA物质C&L通报

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合成工艺路线路线简述

  • 40121-14-0 = 927-83-3 [标题:Reaction Conditions
    标题:Heterocyclic Compounds. Part 15. Nn'-Di-Tert-Butylthiadiaziridine 1,1-Dioxide: Synthesis And Reactions
    作者:Chang,Hsien Hsin; Weinstein,Boris
    参考文献:Journal Of The Chemical Society 日期:1977 卷标:(14) 页码:1601-5]

    13952-67-5 = 927-83-3
    反应条件:1.1 Reagents: Sodium Hydroxide,Sodium Hypochlorite Solvents: Pentane,Water; 3 H,< 35 °C
    标题:Chemical Reactions Of Some Nonaromatic Radical Anions
    作者:Myers,Drewfus Young Jr.
    参考文献:1974]

    = 927-83-3
    反应条件:1.1 Reagents: Sodium Nitrite,Sulfuric Acid
    标题:Helium Droplet Infrared Spectroscopy Of The Butyl Radicals
    作者:King,Kale E.; Franke,Peter R.; Pullen,Gregory T.; Schaefer,Henry F.; Douberly,Gary E.
    参考文献:Journal Of Chemical Physics 日期:2022 卷标:157(8)]

    = 927-83-3 [标题:Reaction Conditions
    标题:Azoethane
    作者:Ohme,Roland; Preuschhof,Helmut; Heyne,Hans-Ulrich
    参考文献:Organic Syntheses 日期:1972 卷标:52 页码:11-16]

    = 927-83-3
    反应条件:1.1 Reagents: Tetraethylammonium Chloride Solvents: Acetonitrile,Tetrahydrofuran; Rt -> 120 °C; 24 H,120 °C
    标题:Formation Of The Tetranuclear,Tetrakis-Terminal-Imido Mn4Iv(Ntbu)8 Cubane Cluster By Four-Electron Reductive Elimination Of Tbun:Ntbu. The Role Of The S-Block Ion In Stabilization Of High-Oxidation State Intermediates
    作者:Vaddypally,Shivaiah; Kondaveeti,Sandeep K.; Roudebush,John H.; Cava,Robert J.; Zdilla,Michael J.
    参考文献:Chemical Communications (Cambridge 日期:2014 卷标:50(9) 页码:1061-1063]

    13952-69-7 = 927-83-3 [标题:Reaction Conditions
    标题:Acyclic Trialkyldiazenium Cation Chemistry. Thermolysis And Solvolysis Of 1,2-Di-Tert-Butyl-1-Ethyldiazenium Perchlorate
    作者:Allred,Evan L.; Chow,Tahsin J.; Oberlander,Joseph E.
    参考文献:Journal Of The American Chemical Society 日期:1982 卷标:104(20) 页码:5422-7]

    = 927-83-3 [标题:Reaction Conditions
    标题:Syntheses And 15N Nmr Spectra Of Iminodiaziridines - Ring-Expansions Of 1-Aryl-3-Iminodiaziridines To 1H- And 3Ah-Benzimidazoles,2H-Indazoles,And 5H-Dibenzo[d,F][1,3]Diazepines
    作者:Quast,Helmut; Ross,Karl-Heinz; Philipp,Gottfried; Hagedorn,Manfred; Hahn,Harald; Et Al
    参考文献:European Journal Of Organic Chemistry 日期:2009 卷标:(23) 页码:3940-3952]

    = 927-83-3 [标题:Reaction Conditions
    标题:Synthesis Of Branched Azoalkanes And Kinetics Of Their Thermal Decomposition
    作者:Prochazka,M.
    参考文献:Collection Of Czechoslovak Chemical Communications 日期:1976 卷标:41(5) 页码:1557-64]

    = 927-83-3 [标题:Reaction Conditions
    标题:Chemistry Of Thiadiaziridine 1,1-Dioxides. Iii
    作者:Timberlake,J. W.; Hodges,M. L.; Garner,A. W.
    参考文献:Tetrahedron Letters 日期:1973 卷标:3843 页码:3843-6]

    = 927-83-3 [标题:Reaction Conditions
    标题:Synthesis Of Azoalkanes
    作者:Timberlake,J. W.; Hodges,M. L.; Betterton,K.
    参考文献:Synthesis 日期:1972 卷标:(11) 页码:632-4]

    = 927-83-3 [标题:Reaction Conditions
    标题:1,2-Diazetidinediones
    作者:Stowell,John C.
    参考文献:Journal Of Organic Chemistry 日期:1967 卷标:32(7360-2) 页码:2360-2]

    7188-38-7 + 75-64-9 = 927-83-3 + 5336-24-3
    反应条件:1.1 Reagents: Oxygen Catalysts: Tetrakis(Triphenylphosphine)Palladium Solvents: 1,4-Dioxane; 2 H,Rt
    标题:Synthesis Of 2-Aminobenzoxazoles And 3-Aminobenzoxazines Via Palladium-Catalyzed Aerobic Oxidation Of O-Aminophenols With Isocyanides
    作者:Liu,Bifu; Yin,Meizhou; Gao,Hanling; Wu,Wanqing; Jiang,Huanfeng
    参考文献:Journal Of Organic Chemistry 日期:2013 卷标:78(7) 页码:3009-3020]

    22975-87-7 = 927-83-3 + 5336-24-3
    反应条件:1.1 Solvents: 1,4-Dioxane,Water; 63 H,Reflux1.2 Reagents: Oxygen; 3 D,Rt
    标题:1-Acylsemicarbazides By Ring Opening Of Iminodiaziridines With Carboxylic Acids: Novel,Expeditious Access To The Azapeptide Motif
    作者:Quast,Helmut; Schmitt,Edeltraud; Ross,Karl-Heinz
    参考文献:Synthesis 日期:2010 卷标:(19) 页码:3358-3362]

    917-95-3 = 927-83-3 + 691-24-7 + 5336-24-3 + 16649-52-8
    反应条件:1.1 Reagents: Iron Pentacarbonyl Solvents: Tetrahydrofuran
    标题:Metathesis And Reduction Reactions Of Nitroso Compounds With Metal Carbenes And Metal Carbonyls
    作者:Herndon,James W.; Mcmullen,Leonard A.
    参考文献:Journal Of Organometallic Chemistry 日期:1989 卷标:368(1) 页码:83-101
📜1,2-Di-Tert-Butylhydrazine 反应 72.0H,以66%的收率获得产物偶氮叔丁烷
参考文献:通过氨基二咪唑烷与羧酸的开环作用来形成1-酰基半脲:新颖,快速地获得氮杂肽基序
标题:通过氨基二咪唑烷与羧酸的开环作用来形成1-酰基半脲:新颖,快速地获得氮杂肽基序
摘要:羧酸与亚氨基二氮杂吡啶快速且定量地反应,以多步顺序提供1,2,4-三取代的1-酰基半氨基肼.以这种方式,羧基容易转化为氮杂肽基序.在高场宽信号¹ H和¹³ C NMR光谱记录为产品指示动态过程. 氮杂肽-杂环-水解-开环-氨基脲
DOI:10.1055/s-0030-1257868

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合成方法参考DOI号:10.1055/s-0030-1257868
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