专利号:US-9018325-B2 优先权日:2011-08-25 标题 :Catalyst for living radical polymerization and polymerization method 发明人:GOTO ATSUSHI; KAJI HIRONORI 权利人:GOTO ATSUSHI; KAJI HIRONORI; UNIV KYOTO 摘要:A nonmetallic compound having an ionic bond with a halide ion is used as a catalyst for living radical polymerization. Even if a radical initiator is not used, a monomer can be subjected to a radical polymerization to obtain a polymer having narrow molecular weight distribution. The cost of the living radical polymerization can be remarkably reduced, and it is made possible to prevent adverse effects of using a radical initiator (such as side reactions). The present invention is significantly more environmentally friendly and economically excellent than conventional living radical polymerization methods, due to advantages such as low toxicity of the catalyst, low amount of the catalyst necessary, high solubility of the catalyst, mild reaction conditions, and no coloration/no odor, etc. The catalyst can be applied to various monomers and enables synthesis of high molecular weight polymers.
参考标题:The Cycloalkylation Of Cyclopentadiene By Functionally Substituted 1,2-Dibromoethanes Under Phase Transfer Catalysis Conditions As A General Method For The Synthesis Of Derivatives Of Spiro [2,4] Hepta-4,6-Diene 作者:A. I. D'Yachenko,L. G. Menchikov,O. M. Nefedov |发布日期:1985.3
合成参考文献
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