CAS: 5651-88-7; Phenylpropargylsulfide

该化合物是有机化合物,其特点是存在一种苯环,以丙酰硫基组物替代;该化合物的特点是将硫磺原子与三碳烷基组体捆绑在一起,这是一个三碳碳烷链,表明第二和第三碳原子之间存在三重结合;分子结构有助于其再活性,特别是由于烷的电提取性质而导致的核生殖性替代反应;该产品一般是一种无色的,淡黄色的液体,有不同的气味,相对不溶于水,但在有机溶剂中可溶解;该复合体可能具有中度毒性,在处理时应当采取适当的安全措施;其应用范围从有机合成用途到制药或农用化学品开发的潜在作用,尽管根据正在进行的研究和开发,其具体应用可能有所不同.

结构式图片

欧盟法规

ECHA物质C&L通报

上下游产品

CAS号108-98-5 硫酚 | CAS号106-96-7 溴代丙炔 | CAS号624-65-7 3-氯丙炔 | CAS号882-33-7 二苯二硫醚 | CAS号107-19-7 丙炔醇 | CAS号930-69-8 苯硫酚钠 | CAS号6165-75-9 苯磺酸炔丙酯 | CAS号82707-19-5 [[3-(trimethyls... | CAS号1007-27-8 trimethyl(pheny... | CAS号5042-53-5 (苯基硫代)丙酮 | CAS号19093-37-9 烯丙基苯基亚砜 | CAS号26981-77-1 1,2-Pentadiene,... | CAS号2525-46-4 2-methoxyprop-2... | CAS号624-67-9 炔丙醛 | CAS号5219-61-4 (苯硫基)乙腈 | CAS号76047-52-4 2-[(苯基硫醇)甲基]-2-... | CAS号5296-64-0 烯丙氧基苯硫酚 | CAS号108-98-5 硫酚 | CAS号874-79-3 苯基正丙基硫化物

合成工艺路线路线简述

    📜苯硫醇酸三甲基锡烷鎓置于二乙胺体系中,化学反应 0.3H,反应生成 苯基丙炔基硫醚
    参考文献:Bogoradovskii; Maksimov; Zubova,Russian Journal Of General Chemistry,1999,Vol. 69,# 7,P. 1167-1172
    标题:Bogoradovskii; Maksimov; Zubova,Russian Journal Of General Chemistry,1999,Vol. 69,# 7,P. 1167-1172

    海关参考信息

    专利信息


    专利号:US-9920160-B2
    优先权日:2014-09-03
    标题 :Method for synthesis of polymer containing multiple epoxy groups
    发明人:GAO CHAO; ZHENG YAOCHEN; PENG LI; CAI SHENGYING; WENG ZHULIN
    权利人:UNIV ZHEJIANG
    摘要:A method for a synthesis of a polymer containing multiple epoxy groups includes steps of: under protection of nitrogen or argon, with a photosensitive free radical initiator under an ultraviolet light irradiation, initiating a mixture of a dithiol compound and alkynyl glycidyl ether or other alkynyl-containing compounds to proceed a thiol-yne polymerization, so as to obtain the polymer. The number of the epoxy groups is able to be adjusted through changing a type of a dithiol monomer, a mixing ratio of the dithiol monomer, and a mixing ratio between the alkynyl glycidyl ether and other alkynyl compounds. The present invention has advantages of: fast reaction, convenient process, easy post-processing, a large number of the epoxy groups, and adjustable and controllable content. The obtained polymer has a wide potential application in fields of coating, adhesive, ink, encapsulating material, resin for composite material, additive, high performance material, function material, and so on.

    专利号:US-2024208898-A1
    优先权日:2021-03-25
    标 题 :Enamine n-oxides: synthesis and application to hypoxia-responsive prodrugs and imaging agents
    发明人:KIM JUSTIN; KANG DAHYE; CHEUNG SHELDON T
    权利人:DANA FARBER CANCER INST INC
    摘要:Disclosed are compounds and pharmaceutically acceptable salts and stereoisomers thereof that are suitable for diagnosis and the treatment of diseases and disorders characterized by, associate with or which exhibit tissue hypoxia, such as, for example, solid tumors. Also disclosed are pharmaceutical compositions containing same, and methods of making and using the compounds.

    专利号:WO-03061385-A1
    优先权日:2002-01-17
    标题:Tricyclic nucleoside library compounds, synthesis, and use as antiviral agents
    发明人:AN HAOYUN; HONG ZHI; SMITH KENNETH; DING YILI; GIRARDET JEAN-LUC
    权利人:RIBAPHARM INC; AN HAOYUN; HONG ZHI; SMITH KENNETH; DING YILI; GIRARDET JEAN-LUC
    摘要:Tricyclic nucleoside libraries and library compounds are prepared using combinatorial chemistry and non-combinatorial chemistry methods. Contemplated library compounds are particularly useful in inhibition of viral propagation, and particularly of viral propagation of the HCV virus.

    专利号:US-2017044304-A1
    优先权日:2014-09-03
    标 题:Method for synthesis of polymer containing multiple epoxy groups

    专利号:JP-2024512568-A
    优先权日:2021-03-25
    标 题:Enamine N-oxide: synthesis and application of hypoxia-responsive prodrugs and contrast agents

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    [参考文献]: Lingling Peng, Et Al. Transition-Metal-Catalyzed Rearrangement Of Allenyl Sulfides: A Route To Furan Derivatives. Angew Chem Int Ed Engl. 2007;46(11):1905-8.

    合成参考文献


    摘要:Negishi, E.; Wang, G., Science of Synthesis, (2010) 47, 978.
    摘要:Schatz, J.; Seler, M., Science of Synthesis Knowledge Updates, (2011) 2, 405.
    摘要:Hou, X.-L.; Peng, X.-S.; Yeung, K.-S.; Wong, H. N. C., Science of Synthesis Knowledge Updates, (2011) 2, 322.
    摘要:Ulfkjær, A.; Pittelkow, M., Science of Synthesis Knowledge Updates, (2018) 1, 158.
    摘要:Fringuelli, F.; Piermatti, O., Science of Synthesis: Water in Organic Synthesis, (2012) 1, 497.
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