专利号:WO-2024123268-A1 优先权日:2022-12-09 标 题 :Production of silver nanoparticles by green synthesis using hazelnut husk extract 发明人:AKDOGAN OZAN; GUNDUZ AKDOGAN NILAY; SIVRI DAMLA; KUREL ALI 权利人:BAHCESEHIR UNIV; PIRI REIS UNIV 摘要:The invention relates to synthesis of nanoparticles from hazelnut husk extract by green synthesis with high efficiency. Use of chemical is limited in the present invention and therefore the synthesis of nanoparticles is provided by green chemistry in the present invention. Said hazelnut may be Corylus and said hazelnut husk may be cob or shell of the hazelnut. In an embodiment of the invention said Corylus may be Colyrus colurna, Corylus americana Corylus avellana, Corylus avellana var. Avellana, Corylus avellana var. Pontica, Corylus chinensis, Corylus colchica, Corylus × colurnoides, Corylus cornuta, Corylus cornuta ssp. californica, Corylus cornuta ssp. cornuta, Corylus fargesii, Corylus ferox, Corylus ferox var. ferox, Corylus ferox var. thibetica, Corylus heterophylla, Corylus heterophylla var. heterophylla, Corylus heterophylla var. sutchuensis, Corylus jacquemontii, Corylus maxima, Corylus potaninii, Corylus sieboldiana, Corylus sieboldiana var. mandshurica, Corylus sieboldiana var. sieboldiana, Corylus wangii, Corylus wulingensis or Corylus yunnanensis.
专利号:US-11826833-B2 优先权日:2013-04-12 标 题 :Synthesis of bimetallic nanoparticle catalysts using microwave irradiation 发明人:HUMPHREY SIMON M; GARCIA STEPHANY 权利人:UNIV TEXAS 摘要:The present invention provides compositions and methods of making bimetallic metal alloys of composition for example, Rh/Pd; Rh/Pt; Rh/Ag; Rh/Au; Rh/Ru; Rh/Co; Rh/Ir; Rh/Ni; Ir/Pd; Ir/Pt; Ir/Ag; Ir/Au; Pd/Ni; Pd/Pt; Pd/Ag; Pd/Au; Pt/Ni; Pt/Ag; Pt/Au; Ni/Ag; Ni/Au; or Ag/Au prepared using microwave irradiation.
专利号:US-11465129-B2 优先权日:2017-06-06 标题:Microwave assisted and low-temperature fabrication of nanowire arrays on scalable 2D and 3D substrates 发明人:GAO PU-XIAN; LU XINGXU; HOANG SON 权利人:UNIV CONNECTICUT 摘要:A method of making a titanium dioxide nanowire array includes contacting a substrate with a solvent comprising a titanium (III) precursor, an acid, and an oxidant while microwave heating the solvent, thereby forming a hydrogen titanate H2Ti2O5.H2O nanowire array. The hydrogen titanate nanowire array is annealed to form a titanium dioxide nanowire array. The substrate is seeded with titanium dioxide before starting the hydrothermal synthesis of the hydrogen titanate nanowire array. The titanium dioxide nanowire array is loaded with a platinum group metal to form an exhaust gas catalyst. The titanium dioxide nanowire array can be used to catalyze oxidation of combustion exhaust.
专利号:US-9272334-B2 优先权日:2011-04-12 标 题:Synthesis of platinum-alloy nanoparticles and supported catalysts including the same 发明人:CARPENTER MICHAEL K 权利人:GM GLOBAL TECH OPERATIONS INC 摘要:Methods of synthesizing platinum-nickel-alloy nanoparticles and supported catalysts comprising the nanoparticles are provided. The methods may comprise forming a reaction mixture in a reaction vessel; heating the reaction mixture sealed in the reaction vessel to a reaction temperature; maintaining the temperature of the reaction vessel for a period of time; cooling the reaction vessel; and removing platinum-alloy nanoparticles from the reaction vessel. The reaction mixture may comprise a platinum precursor, a nickel precursor, a formamide reducing solvent, and optionally a cobalt precursor. In some embodiments the reaction temperature is at or below the boiling point of the formamide reducing solvent, such as from about 120° C. to about 150° C., for example. The platinum-alloy nanoparticles provide favorable electrocatalytic activity when supported on a catalyst support material.
专利号:US-5364981-A 优先权日:1993-11-08 标 题:On-step synthesis of methyl t-butyl ether from t-butanol using platinum/palladium modified β-zeolite catalysts 发明人:KNIFTON JOHN F; DAI PEI-SHING E 权利人:TEXACO CHEMICAL 摘要:Disclosed is an improved process for preparing alkyl tertiary alkyl ethers, especially methyl t-butyl ether, in one step which comprises reacting tertiary butanol and methanol in the presence of a catalyst comprising beta -zeolite modified with one or more metals selected from Group VIII of the Periodic Table, and optionally further modified with a halogen or a Group IB metal, with an alumina binder, at a temperature of about 20 DEG C. to 250 DEG C. and atmospheric pressure to about 1000 psig, wherein when the temperature is in the operating range above about 140 DEG C., the product comprises a two-phase mix of an MTBE-isobutylene and, optionally, diisobutylene product-rich phase and a heavier aqueous ethanol-rich phase.
专利号:US-2023211325-A1 优先权日:2020-06-01 标题 :Catalyst structure for synthesis gas production, synthesis gas production apparatus, and method for producing catalyst structure for synthesis gas production 发明人:BANBA Yuichiro; FUKUSHIMA MASAYUKI; UENO TAKAHIRO; MORI TOMOHIKO; NISHII Mai; MASUDA TAKAO; NAKASAKA YUTA; YOSHIKAWA TAKUYA 权利人:FURUKAWA ELECTRIC CO LTD; UNIV HOKKAIDO NAT UNIV CORP 摘要:A catalyst structure for synthesis gas production of a synthesis gas that contains carbon monoxide and hydrogen, the catalyst structure being provided with a carrier that has a porous structure, while being configured from a zeolite type compound; first catalyst particles that contain one or more iron group elements which are selected from the group consisting of nickel (Ni), iron (Fe) and cobalt (Co); and second catalyst particles that contain one or more platinum group elements which are selected from the group consisting of platinum (Pt), palladium (Pd), rhodium (Rh) and ruthenium (Ru). The catalyst structure for synthesis gas production has passages in communication with each other within the carrier. The first catalyst particles are present at least in the passages of the carrier; and the second catalyst particles are present at least either inside the carrier or on the outer surface of the carrier.
参考文献:10.1007/s11244-023-01782-y 摘要:Prabhudesai VS, Vinu R. Hydrodeoxygenation of Biomass-derived Oxygenate Mixtures Over Pt/C and HZSM-5 Mixed Catalysts. Top Catal. 2023 Jan 20;66(5-8):405–19. doi: 10.1007/s11244-023-01782-y. 参考文献:10.1007/s11814-023-1497-9 摘要:Woo Y, Oh DB, Park JE, Han SJ, Lee Y, Park M. CFD modeling of a multichannel Fischer-Tropsch reactor module with microscale cooling channels: Effects of mirrored structure cooling layers. Korean J. Chem. Eng. 2023 Jun 20;40(10):2572–80. doi: 10.1007/s11814-023-1497-9. 参考文献:10.1007/s40042-023-00974-9 摘要:Jeong E, Han S. Comparison of Fourier-transformed and Wavelet-transformed EXAFS. J. Korean Phys. Soc. 2023 Dec 12;84(3):208–17. doi: 10.1007/s40042-023-00974-9. 参考文献:10.1007/s12274-023-6220-y 摘要:Li Y, Jing L, Little JM, Yang H, Chung T, Chen P. Mechanically driven assembly of biomimetic 2D-material microtextures with bioinspired multifunctionality. Nano Res. 2023 Dec 02;17(2):663–78. doi: 10.1007/s12274-023-6220-y. 参考文献:10.1007/s12274-023-6328-0 摘要:Li X, Han X, Yang Z, Wang S, Yang Y, Wang J, Chen J, Chen Z, Jin H. Lattice-distorted Pt wrinkled nanoparticles for highly effective hydrogen electrocatalysis. Nano Res. 2024 Jan 02;17(5):3819–26. doi: 10.1007/s12274-023-6328-0.