CAS: 934-73-6; P-Chlorophenyl Methyl Sulfoxide

• 英文名称P-Chlorophenyl Methyl Sulfoxide
• 中文名称对氯苯基甲基亚砜
• IUPAC名称1-chloro-4-methylsulfinylbenzene
• 其它别名对-氯苯基甲基亚砜; 4-Chlorophenyl Methyl Sulfoxide
• CAS编号934-73-6
• MFCD编号:MFCD00040898
• EINECS号:804-573-5
• FDA UNII编号:6MHM4Y0Y72
• 分子式:C7H7ClOS分子量:174.65
• 产品CID: 1974332
• 产品分类有机原料→分子砌块→芳环类化合物→苯类化合物

• 相似结构搜索
• InChIKey: UBDUBBTYCRJUHW-UHFFFAOYNA-N
• 1S/C7H7ClOS/c1-10(9)7-4-2-6(8)3-5-7/h2-5H,1H3
• 计算化学: 氢键受体数1.0氢键供体数*可旋转键数1.0

物理性质

• 熔点47-48 °C
• 沸点142-144 °C at 6 mmHg
• 闪点135.5 °C
• 密度1.36g/cm3
• PSA:17.07
• LogP:2.0774
• 折射率1.621
• 蒸汽压0.0011 mmHg at 25 °C
• 外观形态白色固体
• 储存条件2-8°C

MSDS等安全信息

• GHS象形图
• GHS符号GHS07 & GHS05;
  注释: Exclamation mark & Corrosion
• 危险类别急性毒性 类别4(经口)
  皮肤腐蚀/刺激 类别2
  严重眼损伤 类别1
• 警示词Danger(危险)
• 危险描述H302 |吞咽有害.
  H315 |造成皮肤刺激.
  H318 |造成严重眼损伤.
• 防范说明P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501
• 危险品标志C
• 安全声明26-36/37/39-45-24/25
• 危险类别码22-34-41

欧盟法规

上下游产品

合成工艺路线路线简述

• 123-09-1 = 934-73-6
  反应条件:1.1 Reagents: Methyl Phenyl Sulfoxide,Dimethyldioxirane Solvents: Acetone,Chloroform
  标题:Dioxirane Epoxidation Of Alkenes
  作者:Adam,Waldemar; Saha-Moeller,Chantu R.; Zhao,Cong-Gui
  参考文献:Organic Reactions (Hoboken 日期:2002 卷标:61]
  
  123-09-1 = 934-73-6
  反应条件:1.1 Reagents: Oxygen Catalysts: 2739695-52-2; 4.5 H,1 Atm,Rt
  标题:Photocatalytic Activity Of Ruthenium(Ii) Complex With 1,10-Phenanthroline-3,8-Dicarboxylic Acid In Aerobic Oxidation Reactions
  作者:Zenkov,I. S.; Yakushev,A. A.; Abel,A. S.; Averin,A. D.; Bessmertnykh-Lemeune,A. G.; Et Al
  参考文献:Russian Journal Of Organic Chemistry 日期:2021 卷标:57(9) 页码:1398-1404]
  
  123-09-1 = 934-73-6
  反应条件:1.1 Catalysts: 2685787-09-9 Solvents: Methanol; 10 H,25 °C
  标题:Incorporating Photochromic Triphenylamine Into A Zirconium-Organic Framework For Highly Effective Photocatalytic Aerobic Oxidation Of Sulfides
  作者:Zou,Xin-Nan; Zhang,Deshan; Luan,Tian-Xiang; Li,Qiang; Li,Lei; Et Al
  参考文献:Acs Applied Materials & Interfaces 日期:2021 卷标:13(17) 页码:20137-20144]
  
  123-09-1 = 934-73-6
  反应条件:1.1 Reagents: Oxygen Catalysts: [4-[2-[10-[2-(4-Carboxyphenyl)Ethynyl]-9-Anthracenyl]Ethynyl]Benzoato(2-)-Ko,Ko′... Solvents: Methanol,Chloroform; 3 H,Rt
  标题:Selective Photooxidation Of Sulfides Mediated By Singlet Oxygen Using Visible-Light-Responsive Coordination Polymers
  作者:Liang,Xiao; Guo,Zhifen; Wei,Hongxia; Liu,Xin; Lv,Hui; Et Al
  参考文献:Chemical Communications (Cambridge 日期:2018 卷标:54(92) 页码:13002-13005]
  
  123-09-1 = 934-73-6
  反应条件:1.1 Reagents: Hydrogen Peroxide Catalysts: Vanadium,[[2,2′-[(2,2-Dimethyl-1,3-Propanediyl)Bis[(Nitrilo-Kn)Methylidyne]]Bis... Solvents: Ethanol; 10 Min,25 °C
  标题:Ni(Ii) And V(Iv) Schiff Base Complexes Derived From 2,2'-Dimethylpropandiamine: The Crystal Structure,Electrochemical Properties And Catalytic Activities In Oxidation Of Sulfides
  作者:Rayati,Saeed; Khodaei,Elham; Jafarian,Majid; Bahrami,Arezo; Wojtczak,Andrzej; Et Al
  参考文献:Journal Of Coordination Chemistry 日期:2017 卷标:70(8) 页码:1424-1437]
  
  123-09-1 = 934-73-6
  反应条件:1.1 Catalysts: Molybdovanadophosphoric Acid (H5Pmo10V2O40) Solvents: Acetic Acid; 1 H,70 °C; Cooled
  标题:Electron Transfer-Oxygen Transfer Oxygenation Of Sulfides Catalyzed By The H5Pv2Mo10O40 Polyoxometalate
  作者:Khenkin,Alexander M.; Leitus,Gregory; Neumann,Ronny
  参考文献:Journal Of The American Chemical Society 日期:2010 卷标:132(33) 页码:11446-11448]
  
  123-09-1 = 934-73-6
  反应条件:1.1 Reagents: Oxygen Catalysts: 12-Hexyl-6-Hydroxy-5H-Dibenzo[b,H]Fluorene-5,11,13-Trione Solvents: 1,1,1,3,3,3-Hexafluoro-2-Propanol; 2 Min,Rt; 60 Min,Rt
  标题:Kuquinone As A Highly Stable And Reusable Organic Photocatalyst In Selective Oxidation Of Thioethers To Sulfoxides
  作者:Forchetta,Mattia; Sabuzi,Federica; Stella,Lorenzo; Conte,Valeria; Galloni,Pierluca
  参考文献:Journal Of Organic Chemistry 日期:2022 卷标:87(21) 页码:14016-14025]
  
  123-09-1 = 934-73-6
  反应条件:1.1 Reagents: 2,3-Benzodioxin-1,4-Dione Solvents: Dichloromethane; 8 H,25 °C
  标题:Metal- And Additive-Free Oxygen-Atom Transfer Reaction: An Efficient And Chemoselective Oxidation Of Sulfides To Sulfoxides With Cyclic Diacyl Peroxides
  作者:Gan,Shaoyan; Yin,Junjie; Yao,Yuan; Liu,Yang; Chang,Denghu; Et Al
  参考文献:Organic & Biomolecular Chemistry 日期:2017 卷标:15(12) 页码:2647-2654]
  
  123-09-1 = 934-73-6
  反应条件:1.1 Reagents: Hydrogen Peroxide Catalysts: Niobium (Complexes With O2 And Chitosan,Sodium Salts),Chitosan Solvents: Water; 3 H,Rt
  标题:Organic-Solvent-Free Oxidation Of Styrene,Phenol And Sulfides With H2O2 Over Eco-Friendly Niobium And Tantalum Based Heterogeneous Catalysts
  作者:Talukdar,Hiya; Saikia,Gangutri; Das,Arpita; Sultana,Sazida Y.; Islam,Nashreen S.
  参考文献:Journal Of Industrial And Engineering Chemistry (Amsterdam 日期:2023 卷标:121 页码:249-263]
  
  123-09-1 = 934-73-6
  反应条件:1.1 Reagents: Iodobenzene Diacetate,Water Catalysts: Chromium(1+),[[rel-2,2′-[(1R,2R)-1,2-Cyclohexanediylbis[(Nitrilo-Kn)Methylidyne... Solvents: Methanol; 60 Min,23 °C
  标题:Visible Light Generation Of Chromium(V)-Oxo Salen Complexes And Mechanistic Insights Into Catalytic Sulfide Oxidation
  作者:Klaine,Seth; Fung Lee,Ngo; Dames,Angeline; Zhang,Rui
  参考文献:Inorganica Chimica Acta 日期:2020 卷标:509]
  
  123-09-1 = 934-73-6
  反应条件:1.1 Reagents: Hydrogen Peroxide Catalysts: Copper,[[4,4′-[(1-Methyl-1,2-Ethanediyl)Bis[(Nitrilo-Kn)Ethylidyne]]Bis[1,3-Ben... Solvents: Ethanol; 20 Min,25 °C
  标题:Catalytic Activity And Electrochemical Properties Of Cu(Ii)-Schiff Base Complex Encapsulated In The Nanocavities Of Zeolite-Y For Oxidation Of Olefins And Sulfides
  作者:Rayati,Saeed; Khodaei,Elham; Jafarian,Majid
  参考文献:Journal Of Coordination Chemistry 日期:2017 卷标:70(15) 页码:2736-2750]
  
  123-09-1 = 934-73-6
  反应条件:1.1 Reagents: Acetic Anhydride,Carbamide Peroxide Catalysts: Imidazole,Iron Oxide (Fe3O4),Silica,2102606-38-0 Solvents: Ethanol; 5 Min,Rt
  标题:Mn-Schiff Base Complex Supported On Magnetic Nanoparticles: Synthesis,Crystal Structure,Electrochemical Properties And Catalytic Activities For Oxidation Of Olefins And Sulfides
  作者:Rayati,Saeed; Khodaei,Elham; Jafarian,Majid; Wojtczak,Andrzej
  参考文献:Polyhedron 日期:2017 卷标:133 页码:327-335]
  
  123-09-1 = 934-73-6
  反应条件:1.1 Reagents: Iodobenzene Diacetate Catalysts: (Sp-5-31)-Carbonyl[5,10,15,20-Tetrakis(2,4,6-Trimethylphenyl)-21H,23H-Porphinato... Solvents: Chloroform-D; 100 H,25 °C
  标题:Visible Light-Promoted Selective Oxidation Of Sulfides To Sulfoxides Catalyzed By Ruthenium Porphyrins With Iodobenzene Diacetate
  作者:Chen,Tse-Hong; Yuan,Zhibo; Carver,Aaron; Zhang,Rui
  参考文献:Applied Catalysis 日期:2014 卷标:478 页码:275-282]
  
  123-09-1 = 934-73-6
  反应条件:1.1 Reagents: 2-Iodyl-3-Propoxypyridine Solvents: Acetonitrile; Rt1.2 Rt -> Reflux; 2.5 H,Reflux; Reflux -> Rt1.3 Reagents: Sodium Thiosulfate Solvents: Water; Rt
  标题:Preparation,X-Ray Structure,And Reactivity Of 2-Iodylpyridines: Recyclable Hypervalent Iodine(V) Reagents
  作者:Yoshimura,Akira; Banek,Christopher T.; Yusubov,Mekhman S.; Nemykin,Victor N.; Zhdankin,Viktor V.
  参考文献:Journal Of Organic Chemistry 日期:2011 卷标:76(10) 页码:3812-3819]
  
  123-09-1 = 934-73-6
  反应条件:1.1 Reagents: Acetic Acid; 0 °C1.2 Reagents: (-)-Methyl Phenyl Sulfoxide Solvents: Water; Overnight,Rt; Rt -> 0 °C1.3 Reagents: Sodium Hydroxide Solvents: Water; Basified
  标题:Access To N-Cyanosulfoximines By Transition Metal-Free Iminations Of Sulfoxides
  作者:Dannenberg,C. A.; Fritze,L.; Krauskopf,F.; Bolm,C.
  参考文献:Organic & Biomolecular Chemistry 日期:2017 卷标:15(5) 页码:1086-1090]
  
  123-09-1 = 934-73-6
  反应条件:1.1 Reagents: Iodobenzene Diacetate Catalysts: 1989691-31-7 Solvents: Methanol,Methanol-D4,Water; 3 H,23 °C1.2 Reagents: Sodium Hydroxide Solvents: Water
  标题:Highly Efficient And Chemoselective Oxidation Of Sulfides Catalyzed By Iron(Iii) Corroles With Iodobenzene Diacetate
  作者:Chen,Tse-Hong; Kwong,Ka Wai; Lee,Ngo Fung; Ranburger,Davis; Zhang,Rui
  参考文献:Inorganica Chimica Acta 日期:2016 卷标:451 页码:65-72]
  
  123-09-1 = 934-73-6
  反应条件:1.1 Reagents: Hydrochloric Acid,Oxygen Catalysts: Rose Bengal Solvents: Ethanol; 18 H,Rt
  标题:A Simple Metal-Free Catalytic Sulfoxidation Under Visible Light And Air
  作者:Gu,Xiangyong; Li,Xiang; Chai,Yahong; Yang,Qi; Li,Pixu; Et Al
  参考文献:Green Chemistry 日期:2013 卷标:15(2) 页码:357-361]
  
  123-09-1 = 934-73-6
  反应条件:1.1 Reagents: Hydrogen Peroxide Catalysts: 1-Butanaminium,N,N,N-Tributyl-,Stereoisomer Of Dioxobis[μ-(Peroxy-Ko1:Ko1,Ko2)... Solvents: Acetonitrile,Water; 120 Min,293 K
  标题:Highly Efficient Oxidation Of Sulfides With Hydrogen Peroxide Catalyzed By [seo4{wo(O2)2}2]2-
  作者:Kamata,Keigo; Hirano,Tomohisa; Mizuno,Noritaka
  参考文献:Chemical Communications (Cambridge 日期:2009 卷标:(26) 页码:3958-3960]
  
  123-09-1 = 934-73-6
  反应条件:1.1 Reagents: Hydrogen Peroxide Solvents: Water; 15 Min,Rt
  标题:Selective Oxidation Of Sulfides With H2O2 Catalyzed By Silica-Tungstate Core-Shell Nanoparticles
  作者:Sreedhar,B.; Radhika,P.; Neelima,B.; Hebalkar,Neha; Mishra,A. K.
  参考文献:Catalysis Communications 日期:2008 卷标:10(1) 页码:39-44]
  
  123-09-1 = 934-73-6
  反应条件:1.1 Reagents: Hydrogen Peroxide Catalysts: 2962812-46-8 Solvents: Methanol; 30 Min,50 °C
  标题:Two 3D Two-Fold Interpenetrated Dia-Like Polyoxometalate-Based Metal-Organic Frameworks: Synthesis And Sulfide Selective Oxidation Activity
  作者:Bai,Xue; Han,Xu; Wang,Yuxin; Zhang,Ange; Yang,Yanli; Et Al
  参考文献:Inorganic Chemistry 日期:2023 卷标:62(33) 页码:13221-13229

海关参考信息

• 2903919090-氯苯
  2930909099-其他有机硫化合物
• 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
• 详情请参考：📖 海关编码查询和海关进出口税则

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• ➥ 象形图和危险代码
• ➥ 防范代码详解
• ➥ 危险代码说明
• ➥ Globally Harmonized System
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