1,2-Dichloro-3,3,3-Trifluoropropene置于palladium On Activated Charcoal 氢气体系中,化学反应生成 3,3,3-三氟丙烯 参考文献:Process For Production Of 2-Chloro-3,3,3-Trifluoropropene 标题:Process For Production Of 2-Chloro-3,3,3-Trifluoropropene 摘要:根据本发明提供了一种生产2-氯-3,3,3-三氟丙烯的方法,包括:在存在具有过渡金属和毒化物质支撑物的催化剂的情况下,用氢气(h2)氢化1,2-二氯-3,3,3-三氟丙烯.目前的生产工艺在工业上具有优势,因为在适度的反应条件下,可以高选择性和高产率地获得目标2-氯-3,3,3-三氟丙烯,并且易于废物处理.
专利号:US-9126995-B2 优先权日:2011-11-08 标题:Method for catalytic asymmetric synthesis of optically active isoxazoline compound and optically active isoxazoline compound 发明人:TOYAMA KEN-ICHI; MORIYAMA YUJI; MATOBA KAZUTAKA; YAOSAKA MANABU; IKEDA EITATSU 权利人:NISSAN CHEMICAL IND LTD 摘要:There is provided a method for catalytic asymmetric synthesis of optically active isoxazoline compound and an optically active isoxazoline compound. A method for catalytic asymmetric synthesis of optically active isoxazoline compound of a formula (6) including reacting an α,β-unsaturated carbonyl compound of a formula (1) and a hydroxylamine in a solvent in the presence of a base by adding a chiral phase transfer catalyst. An optically active isoxazoline compound of a formula (13) that can be synthesized by the method.
专利号:US-4720573-A 优先权日:1986-07-31 标 题:Process for synthesis of glutamic acid from acrylate, amide and synthesis gas 发明人:LIN JIANG-JEN 权利人:TEXACO INC 摘要:A process for the synthesis of glutamic acid intermediate from an acrylate, amide and syngas by reacting them in the presence of a catalyst comprising a cobalt-containing compound, a bis-phosphine ligand and a solvent at a pressure of at least 500 psi and a temperature of at least 50° C. and thereafter extracting the glutamic acid.
专利号:US-2012184653-A1 优先权日:2011-01-18 标 题:Synthesis of linear phosphorus-containing functional fluorocopolymer 发明人:WANG LIANG; WANG VIKTORIA 权利人:WANG LIANG; WANG VIKTORIA 摘要:This invention relates to a synthesis of a linear fluorocopolymer having a plurality of pendant phosphorus-containing functional groups. The synthesized phosphorus-containing fluorocopolymer has chain linearity and narrow molecular weight distributions. It has applications as a lubricant additive that provides friction-reduction, anti-wear, and corrosion protection properties.
专利号:US-7371904-B2 优先权日:2004-04-29 标题:Processes for synthesis of 1,3,3,3-tetrafluoropropene 发明人:MA JING JI; MUKHOPADHYAY SUDIP; NAIR HARIDASAN K; TUNG HSUEH S; VAN DER PUY MICHAEL 权利人:HONEYWELL INT INC 摘要:Disclosed is a process for the synthesis of 1,3,3,3-tetrafluoropropene which comprises, in one embodiment, reacting a compound of CF 3 X 1 with a compound of CX 2 Hâ•?CHX 3 , wherein X 1 , X 2 , and X 3 are each independently selected from the group consisting of fluorine, chlorine, bromine and iodine, to produce a reaction product comprising a compound of CF 3 CHâ•?CHX 3 , wherein X 3 is as described above; and when X 3 is not fluorine, fluorinating the compound to produce 1,3,3,3-tetrafluoropropene. The process in another embodiment comprises preparing tetrafluoropropene comprising thermally cracking one or more compounds capable of producing a reaction mixture which preferably comprises diflurocarbene radicals and vinylidene fluoride, and converting said reaction mixture into—tetrafluoropropene (1,3,3,3-tetrafluoropropene).
专利号:US-7714177-B2 优先权日:2004-04-29 标题:Processes for synthesis of 1,3,3,3-tetrafluoropropene 发明人:MUKHOPADHYAY SUDIP; NAIR HARIDASAN K; TUNG HSUEH S; VAN DER PUY MICHAEL 权利人:HONEYWELL INT INC 摘要:Disclosed is a process for the synthesis of 1,3,3,3-tetrafluoropropene comprising: a) reacting a compound of the formula (I) CHFX 2 with a compound of formula (II) CH 2 â•?CF 2 to produce a reaction product comprising a compound of formula (III) CHXFCH 2 CXF 2 , wherein each X is independently selected from the group consisting of chlorine, bromine and iodine; and (b) exposing said compound of formula (III) to reaction conditions effective to convert said compound to 1,3,3,3-tetrafluoropropene.
专利号:US-9394394-B2 优先权日:2013-09-30 标题:Synthesis of chlorotrifluoroethylene-based block copolymers by iodine transfer polymerization 发明人:THENAPPAN ALAGAPPAN; AMEDURI BRUNO; LOPEZ GERALD 权利人:HONEYWELL INT INC 摘要:Methods for the synthesis of CTFE-based block copolymers through iodine transfer polymerization are disclosed. In an exemplary embodiment, a method includes reacting a fluoromonomer “Mâ€? with a chain transfer agent of the formula X—Y or Y—X—Y, wherein X represents a C 1 -C 3 hydrocarbon, a C 1 -C 6 hydrofluorocarbon, C 1 -C 6 hydrochlorofluorocarbon, or C 1 -C 6 fluorocarbon and Y represents iodine or bromine, in the presence of a radical initiator, to form a macro-initiator of the formula: X-poly(M)-Y or Y-poly(M)-X-poly(M)-Y, wherein poly(M) represents a polymer of the fluoromonomer. The method further includes reacting the macro-initiator with chlorotrifluoroethylene (CTFE) in the presence of a radical initiator to form a diblock or a triblock CTFE-based block copolymer of the formula: X-poly(M)-block-poly(CTFE) or PCTFE-block-poly(M)-X-poly(M)-block-PCTFE.