CAS: 19513-05-4; Manganese(Iii) Acetate Dihydrate

该化合物是一种无机化合物,配有Mn(C2H3O232H2O)的配方.它一般是红褐色固体,在各种化学反应中,特别是在有机合成中,以其催化剂作用而著称.该化合物中的锰处于+3氧化状态,它比锰的其他氧化状态不稳定,使它在协调化学中成为人们感兴趣的对象.二氢化物形式表明存在两个与每个配方单元相关的水分子,这促使其溶解于水中.曼甘尼西(III) 乙酸二氢酸乙酸乙酯可用于其他锰化合物的准备,并可能由于锰离子的存在而表现出有趣的磁性和电子性.与许多锰化合物一样,它应当谨慎处理,因为锰在一定形式和浓度上具有毒性.在实验室环境中与该物质打交道时,应当遵循适当的安全议定书.

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CAS号6156-78-1 乙酸锰,四水 | CAS号638-38-0 乙酸锰(II) | CAS号64-19-7 冰醋酸 | CAS号495-71-6 1,2-联苯甲酰乙烷 | CAS号61820-12-0 5-(2,2-dichloro...

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    专利号:WO-2025098128-A1
    优先权日:2023-11-06
    标 题 :A method of synthesizing glucaric acid and the enzymes used thereof
    发明人:HU HU; Sun Fenshuai; XIA ZEKUN; CHEN CHENG; CHEN HAIBIN; YANG HAO; LIN SHIJIA; PENG QINLI; XU JUNPENG
    权利人:ENZYMASTER NINGBO BIO ENG CO LTD
    摘要:Provided is a biocatalytic method to synthesize L-guluronic acid and glucaric acid. The technical solution is as follow: 1) Firstly, developed is an enzyme-catalyzed route for synthesizing L-guluronic acid by GOase. 2) Secondly, developed is a biocatalytic route for the synthesis of glucaric acid from L-guluronic acid, catalyzed by uronate dehydrogenase (UDH).

    专利号:US-11168064-B2
    优先权日:2017-03-27
    标 题:Synthesis of thapsigargin, nortrilobolide, and analogs thereof
    发明人:EVANS P ANDREW; CHEN DEZHI
    权利人:UNIV KINGSTON
    摘要:The present invention relates to the preparation of compounds of Formula I, including thapsigargin, nortrilobolide and 8-O-debutanoyl-thapsigargin from commercially available (R)-(−)-carvone via synthetic intermediate compound of formula 12 by pinacol coupling and in situ lactonization.

    专利号:US-2025206771-A1
    优先权日:2022-03-25
    标 题:7-ketolithocholic acid intermediate, synthesis method therefor, and application thereof
    发明人:YANG YINGQUAN; YUAN HAITAO; Zhou panlong; WANG FEI; WU HUCHENG
    权利人:SUZHOU ENTECH NEW MATERIAL TECH CO LTD
    摘要:A synthesis method for a 7-ketolithocholic acid is prepared from a new intermediate I-1. According to the method, phytosterol degradation product bisnoralcohol is used as a starting material, and the 7-ketolithocholic acid or the intermediate thereof is obtained by means of an oxidation reaction, a Knoevenagel reaction (or wittig reaction), hydrogenation, a ketal protection reaction, an allylic oxidation reaction, ketal removal protection, and the hydrogenation.

    专利号:US-2008262255-A1
    优先权日:2006-08-16
    标题:Stabilized vegetable oils and methods of making same
    发明人:HIGGINS NEIL WALLACE; STULTS JERRY F
    权利人:BUNGE OILS INC
    摘要:A method for modifying ethylenic unsaturation in a triglyceride. One or more unsaturated fatty acyl moieties present in the triglyceride are substituted with a lactone or ketone moiety via a electron acceptor mediated reaction. The resulting reaction products are useful, for example, as lubricants, metalworking fluids, mold release agents, hydraulic fluids, or dielectric fluids, or as components of lubricants, metalworking fluids, mold release agents, hydraulic fluids, or dielectric fluids, and intermediates for polymer synthesis.

    专利号:US-4332914-A
    优先权日:1981-06-26
    标 题 :Manufacture of alkanols from synthesis gas
    发明人:KNIFTON JOHN F
    权利人:TEXACO INC
    摘要:This invention concerns a process of making alkanols and particularly methanol which comprises the steps of contacting a mixture of CO and H2 with a catalyst system comprising a ruthenium-containing compound and a halogen-free rhenium-containing compound or a halogen-free manganese-containing compound dispersed in a low melting quaternary phosphonium base or salt, and heating said resultant reaction mixture under a pressure of 500 psig or greater at a temperature of at least 150 DEG C.

    专利号:US-6118008-A
    优先权日:1996-05-03
    标 题:Diamino pyrazols, their synthesis, keratin fibre dyeing compositions containing them, keratin fibre dyeing methods
    发明人:MALLE GERARD; VIDAL LAURENT; BURANDE AGNES; MAUBRU MIREILLE
    权利人:OREAL
    摘要:The invention discloses new 5-substituted 3,4-diamino pyrazols, their methods of preparation, compositions for keratin fiber oxidation dyeing containing them as an oxidizing base, and the dyeing methods using same.

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    主要参考文献

    [参考文献]: Barry B. Snider, Et Al. Manganese(Iii)-Based Oxidative Free-Radical Cyclizations. Chem Rev. 1996 Feb 1;96(1):339-364.
    [参考文献]: Jean-Paul Otamonga, Et Al. A Kinetic Study Of The Enhancement Of Solution Chemiluminescence Of Glyoxylic Acid Oxidation By Manganese Species. Luminescence. 2015 Aug;30(5):507-11.

    合成参考文献


    参考文献:10.1002/glia.21023
    摘要:Rao KV, Jayakumar AR, Reddy PV, Tong X, Curtis KM, Norenberg MD. Aquaporin-4 in manganese-treated cultured astrocytes. Glia. 2010 Sep;58(12):1490–9. doi: 10.1002/glia.21023.
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