5,5,5-三氟-4-羟基-戊-3-烯-2-酮 以 水 作为反应溶剂,化学反应生成 三氟乙酰丙酮 参考文献:The Reactions Of Zinc(II) With 1,3-Diketones In Aqueous Solution. Catalysis By Cacodylic Acid During Complex Formation 标题:The Reactions Of Zinc(II) With 1,3-Diketones In Aqueous Solution. Catalysis By Cacodylic Acid During Complex Formation 摘要:The Reactions Of Zinc(II) With Three 1,3-Diketones Have Been Investigated In Aqueous Solution At 25-Degrees-C And An Ionic Strength Of 0.5 Mol Dm-3 Naclo4. The Catalytic Effect Of Cacodylic Acid On The Reactions Of Zinc(II) With Pentane-2,4-Dione Has Been Demonstrated. In Addition,The Effect Of Cacodylic Acid On The Hydrolysis Of The Nickel(II) And Copper(II) Triglycine Complexes Has Been Investigated. DOI:10.1039/dt9930000313
专利号:US-9079818-B2 优先权日:2007-10-15 标 题 :Process for synthesis of fluorinated olefins 发明人:MUKHOPADHYAY SUDIP; BORTZ CHERYL L; LIGHT BARBARA A; CANTLON CHERYL L; JOHNSON ROBERT C 权利人:MUKHOPADHYAY SUDIP; BORTZ CHERYL L; LIGHT BARBARA A; CANTLON CHERYL L; JOHNSON ROBERT C; HONEYWELL INT INC 摘要:Disclosed is a process for the synthesis of fluorinated olefins, and in particularly preferred embodiments tetrafluorinated olefins having F on an unsaturated, non-terminal carbon, such as 2,3,3,3-tetrafluoropropene. The preferred processes of the present invention in accordance with one embodiment generally comprise:n (a) reacting a compound of formula (I)n nX 1 X 2   (I)n nwith a compound of formula (II)n nCX 1 X 2 X 3 CX 1 â•?CX 1 X 2   (II)n nto produce a reaction product comprising a compound of formula (III)n nCF 3 CHX 1 CH 2 X 2   (III), andn (b) exposing said compound of formula (III) to reaction conditions effective to convert said compound of formula (III) to a compound of formula (IV)n nCF 3 CZâ•?CH 2   (IV)n nwherein X 1 , X 2 , and X 3 are each independently selected from the group consisting of hydrogen, chlorine, bromine, fluorine and iodine, provided that X 1 and X 2 in formula (I) are not both hydrogen and Z is Cl, I, Br, or F
专利号:WO-9747313-A1 优先权日:1996-06-10 标题:Total synthesis of bacitracin polypetides 发明人:GRIFFIN JOHN H; MCDOUGAL PATRICK G 权利人:UNIV LELAND STANFORD JUNIOR 摘要:Methods for the total synthesis of bacitracin-type polypeptides are described, as well as useful analogs of bacitracin A, and treatment of bacterial infection using such analogs.
专利号:US-5028724-A 优先权日:1990-03-30 标题:Synthesis of volatile fluorinated and non-fluorinated metal-beta-ketonate and metal-beta-ketoiminato complexes 发明人:IVANKOVITS JOHN C; BOHLING DAVID A; NORMAN JOHN A T; ROBERTS DAVID A 权利人:AIR PROD & CHEM 摘要:A process for the vapor-phase synthesis of non-adduct volatile fluorinated and non-fluorinated metal-ligand complexes comprising contacting a β-diketone or β-ketoimine ligand with an inert carrier gas to vaporize the ligand, reacting the vaporized ligand with a metal species at a temperature sufficient to form the metal-ligand complex and recovering the metal-ligand complex by sublimation. The process is conducted in the absence of solvent thereby providing pure non-adduct metal-ligand complexes. Such complexes are particularly suited for specialty applications requiring use of high purity compounds.
专利号:US-3966818-A 优先权日:1972-03-25 标 题 :Novel process for preparation of 4-hydroxy-2,4,6-trimethyl-2,5-cyclohexadiene-1-one 发明人:ICHIKAWA YATARO; YAMANAKA YOSHIYUKI; TSURUTA HIDEKI 权利人:TEIJIN LTD 摘要:A process for preparing 4-hydroxy-2,4,6-trimethyl-2,5-cyclohexadiene-1-one comprising reacting 2,4,6-trimethyl phenol with molecular oxygen or a molecular oxygen-containing gas. The product (also called mesitylquinol) is an intermediate useful as a raw material for the synthesis of a variety of industrial chemicals such as a drugs, dyestuffs, and pigments.
专利号:WO-2024104923-A1 优先权日:2022-11-16 标 题 :Manganese- and iron-containing catalysts comprising an imine ligand for the synthesis of polyurethanes 发明人:SCHAUB THOMAS; JOOST MAXIMILIAN; SALA OLIVER; RUDDIGKEIT MIRIAM; POELTL JOERG; BOKERN STEFAN; KAMM MARINA; HASHMI A STEPHEN K; OCANSEY EDWARD 权利人:BASF SE 摘要:The present invention relates to a process for the production of a polyurethane comprising the application of a manganese- and iron-containing catalysts wherein the catalyst comprises at least on imine ligand, which is defined by the general formula (I). The catalysts comprise a salicylaldehyde based imine according to the general formula (II) as an imine ligand. The present invention is further directed to a polyol component comprising a catalyst according to the invention, and a polyurethane produced according to such a process.
专利号:US-8008526-B2 优先权日:2005-03-17 标 题 :Synthesis reaction catalyst and method of synthesizing compound using the same 发明人:TANAKA HIROHISA; KANEKO KIMIYOSHI 权利人:DAIHATSU MOTOR CO LTD; HOKKO CHEM IND CO 摘要:To improve a catalytic activity of a composite oxide, to carry out a reaction in a high yield, and to provide a synthesis reaction catalyst having excellent handling properties and a method of a synthesizing a compound using the same, a synthesis reaction catalyst containing a palladium-containing perovskite-type composite oxide having a specific surface area of 0.5 to 9.5 m 2 /g is used in Suzuki Cross-Couplings given by the following general scheme (14).