CAS: 2562-38-1; Nitrocyclopentane

该化合物是一种有机化合物,其特点是环戊烷环状环状,以硝基(-NO2)组替代.它是一种无色的,在室内温度下呈现出一种独特的气味的浅黄色液体.硝基化合物的存在使分子具有极性特征,影响分子在各种溶剂中的溶解性;它通常在有机溶剂中溶解,但在水中较少溶解.氮环戊酸以其相对较高的密度和适度的挥发性而著称.该化合物在各种化学应用中都有兴趣,包括作为有机合成中的潜在中间体,以及研究由于其硝基混合物而具有的能动物质,这在某些条件下会助长爆炸性.此外,重要的是要小心处理硝基环丙烷,因为它在接触时可能会对健康造成危险,包括对皮肤和呼吸系统造成刺激.在实验室环境中与该化合物打交道时,应采取适当的安全措施.

结构式图片

相似化合物

1684399-22-1 1628753-67-2 71830-07-4

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

Cyclopentyl bromide Cyclopentanone oxime Cyclopentane cyclopentyl iodide(1-nitro-cyclopentyl)-(4-nitro-phenyl)-methane piperidin-2-one Cyclopentanone oxime Cyclopentamine

合成工艺路线路线简述

    📜碘代环戊烷置于silver(I) Nitrite,乙醚体系中,化学反应生成硝基环戊烷
    参考文献:Rosanow,Zhurnal Russkago Fiziko-Khimicheskago Obshchestva,1915,Vol. 47,P. 611
    标题:Rosanow,Zhurnal Russkago Fiziko-Khimicheskago Obshchestva,1915,Vol. 47,P. 611

    海关参考信息

    专利信息


    专利号:US-12281398-B2
    优先权日:2022-02-07
    标题:Microfluidic process for the general electrochemical synthesis of geminal dipseudohalide or halide-pseudohalide compounds
    发明人:SCHROER THORSTEN G; LECROY GREGORY E; AGUILA MIGUEL; RODRIGUEZ MAYRA P; DOWNARD TYLER J; MACLEOD BRIANNA L
    权利人:US GOV AIR FORCE; US AIR FORCE
    摘要:A process for the microfluidic electrochemical synthesis of geminal dipseudohalide or halide-pseudohalide compounds comprising the steps ofpumping a solution comprising a compound of Formula Iinto a microfluidic electrochemical reactor in the presence of a base, one of a halide or pseudohalide salt (MY), and a mediator;applying an electrical current through the microfluidic electrochemical reactor; andperforming oxidative addition to create a geminal dipseudohalide or halide-pseudohalide compound of the general Formula II

    专利号:US-2024218528-A1
    优先权日:2022-02-07
    标题 :Microfluidic Process for the General Electrochemical Synthesis of Geminal Dipseudohalide or Halide-Pseudohalide Compounds

    专利号:US-7713401-B2
    优先权日:2007-08-08
    标 题 :Methods for performing electrochemical nitration reactions
    发明人:LISTER TEDD EDWARD; FOX ROBERT VINCENT
    权利人:BATTELLE ENERGY ALLIANCE LLC
    摘要:A method for the electrochemical synthesis of dinitro compounds is disclosed. The method comprises using an anode to oxidize an inactive chemical mediator, such as a ferrocyanide (Fe(CN) 6 −4 ) ion, to an active chemical mediator or oxidizing agent, such as a ferricyanide (Fe(CN) 6 −3 ) ion, in the presence of a differential voltage. The oxidizing agent reacts with a nitro compound and a nitrite ion to form a geminal dinitro compound. The anode may continuously oxidize ferrocyanide to regenerate active ferricyanide, thus keeping sufficient amounts of ferricyanide available for reaction.

    专利号:US-2023250540-A1
    优先权日:2022-02-07
    标题 :Microfluidic Process for the General Electrochemical Synthesis of Geminal Dipseudohalide or Halide-Pseudohalide Compounds

    专利号:US-11926911-B2
    优先权日:2022-02-07
    标题:Microfluidic process for the general electrochemical synthesis of geminal dipseudohalide or halide-pseudohalide compounds

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    [参考文献]: C C Conaway, Et Al. Evaluation Of Secondary Nitroalkanes, Their Nitronates, Primary Nitroalkanes, Nitrocarbinols, And Other Aliphatic Nitro Compounds In The Ames Salmonella Assay. Mutat Res. 1991 Nov;261(3):197-207.

    合成参考文献


    摘要:MacMillan, D. W. C.; Watson, A. J. B., Science of Synthesis: Asymmetric Organocatalysis, (2012) 1, 345.
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