CAS: 1615-91-4; Hop-22(29)-Ene

该化合物是自然产生的有机化合物,被归类为三叶管,主要来自某些植物物种,以其在各种自然产品生物合成中的作用著称;二百合苯具有复杂的碳氢化合物结构,有助于其疏水特性;该化合物通常以无色和淡黄色液体的形式出现,具有一种独特的气味;在水中溶解,但有机溶剂中溶解,因此在各种应用中有用,包括香水和作为潜在的生物活性剂;二百合苯由于其可能的治疗性能,包括抗炎和抗微生物效应,在药剂和工业的治疗性方面引起了兴趣;此外,该化合物还可能在其衍生的植物的生态相互作用中发挥作用,影响草药和植物-污染的关系;

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上下游产品

(29)-ene3-oxo-hop-22(29)-ene hopan-22-ol 2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaene (4S,5R)-4-Benzyloxymethyl-2,2-dimethyl-5-(R)-oxiranyl-[1,3]dioxolanedry°Crassol hopyltriphenylphosphonium iodide

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    专利信息


    专利号:US-12163174-B1
    优先权日:2023-05-26
    标题 :Method for producing sclareol by fermentation of cigar tobacco flower buds
    发明人：YU JUN; YANG CHUNLEI; WANG ZHI; CHEN XIONG; LI ZONGPING; YANG JINPENG; LI HAO; YAO LAN; RAO XIONGFEI; PENG HAO; XU SHIPING; WANG WENMING
    权利人:TOBACCO RES INSTITUTE OF HUBEI PROVINCE; UNIV HUBEI TECHNOLOGY
    摘要:A method for producing sclareol by fermentation of cigar tobacco flower buds is provided, including: mixing cigar tobacco flower buds with deionized water, sterilizing and adding edible yeast, then fermenting at 25-30° C. and 100-300 rpm/min for 24-30 h. This method uses cigar tobacco flower buds as the sole raw material, without adding additional nutrients, and only ferments tobacco flower buds with edible yeast to synthesize sclareol. Meanwhile, this method has extremely high synthesis efficiency.

    专利号:US-2022162188-A1
    优先权日:2019-01-15
    标 题:Isoprenoids and methods of making thereof
    发明人：WILLIAMS GAVIN; LUND SEAN; HALL RACHAEL
    权利人:UNIV NORTH CAROLINA STATE
    摘要:Disclosed are methods for preparing isoprenoid subunits, as well as methods of employing these isoprenoid subunits for the synthesis of isoprenoids. Also provided are isoprenoids prepared using the methods described herein.

    专利号:US-2024287010-A1
    优先权日:2021-06-23
    标题:Process For Making Epoxide Derivatives of Farnesene and Use Thereof in Further Synthesis
    发明人：PERSIANI GIACOMO; BAUMGARTNER CORINNE; GRANIER THIERRY; LOVCHIK MARTIN; SCHROEDER FRIDTJOF
    权利人:GIVAUDAN SA
    摘要:Described herein are methods for making intermediates in the production of fragrance ingredients starting from β-farnesene. In particular, methods for making acetylmethylfarnesol and hydroxy-farnesylacetone are described. Methods for making other intermediates in the process are also described. In addition, compositions comprising intermediates in the process and uses of the intermediates are described.

    专利号:WO-2022268840-A1
    优先权日:2021-06-23
    标题:Process for making epoxide derivatives of farnesene and use thereof in further synthesis

    专利号:EP-4359393-A1
    优先权日:2021-06-23
    标题 :Process for making epoxide derivatives of farnesene and use thereof in further synthesis

    专利号:CN-117597334-A
    优先权日:2021-06-23
    标 题 :Methods for preparing epoxide derivatives of farnesene and their use in further synthesis

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    合成参考文献


    摘要:Yu, Z. W.; Yeung, Y.-Y., Science of Synthesis: Applications of Domino Transformations in Organic Synthesis, (2015) 2, 322.
    参考文献:10.1021/ol0496125
    摘要:Hess BA, Smentek L. Concerted nature of AB ring formation in the enzymatic cyclization of squalene to hopenes. Org Lett. 2004 May 27;6(11):1717–20. doi: 10.1021/ol0496125.
    参考文献:10.1007/978-3-319-45618-8_1
    摘要:Falk H, Wolkenstein K. Natural Product Molecular Fossils. Prog Chem Org Nat Prod. 2017;104():1–126. doi: 10.1007/978-3-319-45618-8_1.
    参考文献:10.1021/ol026180u
    摘要:Hoshino T, Ohashi S. Importance of the methyl group at C10 of squalene for hopene biosynthesis and novel carbocyclic skeletons with 6/5 + 5/5 + (6) ring system(s). Org Lett. 2002 Jul 25;4(15):2553–6. doi: 10.1021/ol026180u.
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