专利号:US-2024215280-A1 优先权日:2022-10-31 标 题:In situ core/shell perovskite nanocrystal material, method of preparation thereof, and light emitting device comprising the same 发明人:LEE TAE-WOO; KIM JOO SUNG 权利人:SEOUL NAT UNIV R&DB FOUNDATION; PEROLED CO LTD 摘要:The present inventive concept relates to an in situ core/shell perovskite nanocrystal film formed by an in situ nanocrystal synthesis process, a method for producing the same, and a light emitting device comprising the same as a light-emitting layer. The in situ core/shell perovskite nanocrystal film formed by the in situ nanocrystal synthesis process according to the present inventive concept exhibits a strong charge confinement effect by nanocrystal formation, and can simultaneously greatly improve the luminescence efficiency and lifetime by maintaining the fast charge transport capability of polycrystalline perovskite.
专利号:US-7714145-B2 优先权日:2006-05-15 标题 :2-2′-disubstituted 9,9′-spirobifluorene-base triaryldiamines and their application 发明人:TSAI MING-HAN; LIN HAO-WU; SU HAI-CHING; WU CHUNG-CHIH; FANG FU-CHUAN; LIAO YUAN-LI; WONG KEN-TSUNG; WU CHIH-I; LIN CHI-YEN; HUNG WEN-YI; HOU TEI-HUNG; CHEN WEI-JIUN 权利人:TSAI MING-HAN; LIN HAO-WU; SU HAI-CHING; WU CHUNG-CHIH; FANG FU-CHUAN; LIAO YUAN-LI; WONG KEN-TSUNG; WU CHIH-I; LIN CHI-YEN; HUNG WEN-YI; HOU TEI-HUNG; CHEN WEI-JIUN 摘要:The present invention discloses synthesis of 2,2′-disubstituted 9,9′-spirobifluorene-based triaryldiamine. First, 2,2′-diamino-9,9′-spirobifluorene, a Pd-catalyst as auxiliary and aryl halide BX are provided, wherein X is selected from the group consisting of: Cl, Br and I, B comprises one of the following group: aryl moiety, hetero cycle, multiple fused ring, multiple fused ring with hetero atom(s). Next, a substitution reaction is performed to react the 2,2′-diamino-9,9′-spirobifluorene with the aryl halide BX to produce the 2,2′-disubstituted 9,9′-spirobifluorene-based triaryldiamines. In addition, the present invention discloses organic light emitting devices comprising hole transporting material comprising 2,2′-bis(N,N-disubstituted amino)-9,9′-spirobifluorenes.
专利号:EP-1927610-A2 优先权日:2003-08-12 标 题:Process for the synthesis of aryl- or heteroarylamine boronic acid derivatives
专利号:US-2024158692-A1 优先权日:2022-10-31 标题 :In-situ core/shell nanoparticle structured metal halide perovskite luminescent material, light emitting device including the same, and manufacturing method thereof 发明人:LEE TAE-WOO; KIM JOO SUNG 权利人:SEOUL NAT UNIV R&DB FOUNDATION; PEROLED CO LTD 摘要:The present inventive concept relates to an in situ core/shell perovskite nanocrystal film formed by an in situ nanocrystal synthesis process, a method for producing the same, and a light emitting device comprising the same as a light-emitting layer. The in situ core/shell perovskite nanocrystal film formed by the in situ nanocrystal synthesis process according to the present inventive concept exhibits a strong charge confinement effect by nanocrystal formation, and can simultaneously greatly improve the luminescence efficiency and lifetime by maintaining the fast charge transport capability of polycrystalline perovskite.
[参考文献]: P Rapta, Et Al. In Situ Epr And Uv-Vis Spectroelectrochemistry Of Hole-Transporting Organic Substrates. Spectrochim Acta A Mol Biomol Spectrosc. 2000 Feb 1;56A(2):357-62. [参考文献]: Xiao-Dong Zhuang, Et Al. Conjugated-Polymer-Functionalized Graphene Oxide: Synthesis And Nonvolatile Rewritable Memory Effect. Adv Mater. 2010 Apr 18;22(15):1731-5.
合成参考文献
摘要:Shirakawa, E., Science of Synthesis, (2021) , 153. 摘要:Mateos-Gil, J.; Fa, Science of Synthesis: Knowledge Updates, (2024) 1, 198.