CAS: 1134-23-2; Cycloate

该化合物是甘蔗等作物和其他大叶子植物中的杂草;通过在特定生物化学路径上采取行动阻止杂草生长,干扰杂草发育,从而阻止杂草生长;该物质的特点是水溶性相对较低,影响其应用方法和环境行为;通常在出现前或出现后针对杂草,同时尽量减少对作物的伤害;其化学结构包括环形藻环,有助于其作为除草剂的稳定性和有效性;与许多农用化学品一样,妥善处理和应用对于减轻潜在的环境影响和确保非目标生物的安全至关重要;进行了监管评估,以评价其安全性和有效性,从而在各种农业做法中使用指南.

结构式图片

物理性质

欧盟法规

REACH注册ECHA物质C&L通报REACH预注册

上下游产品

ethyl iodide N-ethyl-cyclohexanamine cycloate sulphone ethylamine

合成工艺路线路线简述

    📜N-乙基环己胺置于potassium Carbonate,Sulfur体系中,用 二甲基亚砜 用作溶剂,20.0 °C,101.33 Kpa 条件下,反应 6.0H,反应生成环草敌
    参考文献:通过一氧化碳和硫将胺羰基化来实际合成s-烷基硫代氨基甲酸酯除草剂
    标题:通过一氧化碳和硫将胺羰基化来实际合成s-烷基硫代氨基甲酸酯除草剂
    摘要:已经开发了胺与一氧化碳和硫的工业和经济羰基化,以合成硫代氨基甲酸酯的s-烷基除草剂.在碳酸钾和dmso溶剂存在下,在温和的条件下(1 Atm,20oc)由胺,一氧化碳,硫和烷基卤化物以优异的收率合成s-烷基硫代氨基甲酸酯,例如硫代苯甲酸酯和邻苯甲酸酯(除草剂) .
    Doi:10.1016/j.Tet.2004.01.060

    海关参考信息

    专利信息


    专利号:WO-2024256370-A1
    优先权日:2023-06-13
    标 题 :Synthesis of glufosinate using an amidase-based process
    发明人:ZIMMERMANN GUNTHER; POTT MORITZ STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.

    专利号:US-2006223947-A1
    优先权日:2005-04-05
    标题 :Chemical synthesis of polymeric nanomaterials and carbon nanomaterials
    发明人:OLESIK SUSAN V; DING LUNHAN
    权利人:UNIV OHIO STATE RES FOUND
    摘要:A high yield method for chemically synthesizing low polydispersivity carbon microspheres, nanospheres, nanocrystals, nanotubes, or nanofibers comprising dispersing a self-polymerizing end-capped polyyne in a solvent; heating the dispersed self-polymerizing end-capped tetrayne to form a polymeric material selected from the group consisting of polymer microspheres, polymer nanospheres, polymer nanocrystals, polymer nanotubes, and polymer nanofibers; and pyrolyzing the polymeric material to form a carbon material selected from the group consisting of carbon microspheres, carbon nanospheres, carbon nanocrystals carbon nanotubes, and carbon nanofibers, wherein the polydispersivity is less than 2.

    专利号:US-2025120400-A1
    优先权日:2021-12-10
    标题:Synthesis of glufosinate using a hydantoinase-based process
    发明人:DITRICH KLAUS; BREUER MICHAEL; POTT MORITZ STEFAN; ZIMMERMANN GUNTHER; SEEMAYER STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of manufacturing glufosinate, comprising the steps of hydrolysing a hydantoin with a Hydantoinase enzyme to form a N-carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N-carbamoyl amino acid compound.

    专利号:US-11919928-B2
    优先权日:2016-03-16
    标题 :Method for producing dihydrotentoxin
    发明人:KUBO TAKASHI; MACHIDA MASAYUKI; FUJIOKA TOMONORI; YAMAGUCHI Shigenari; KAWAI KIYOSHI
    权利人:KUMIAI CHEMICAL INDUSTRY CO
    摘要:An object of the present invention is to identify an enzyme having activity of synthesizing dihydrotentoxin that is a tentoxin precursor and an enzyme having activity of synthesizing tentoxin using dihydrotentoxin as a substrate. The present invention concerns a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 16 and having activity of nonribosomal peptide synthesis of dihydrotentoxin and a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 18 and having activity of converting dihydrotentoxin to tentoxin.

    专利号:US-2021386068-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.

    专利号:US-2021352899-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and fatty acid and lipid synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof.

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献


    1: Czapski J, Horbowicz M, Dobrzanski A, Bakowski J. Residues of cycloate and influence of herbicides on some of nutritional factors in spinach. J Environ Sci Health B. 1983 Aug;18(4-5):497-503. doi: 10.1002/ps.1792.
    5: Voronova GF, Aleksandrova LG. [Chromatographic analysis of the herbicide cycloate in the soil]. Gig Sanit. 1989 Aug;(8):46-7. Russian.
    7: Onisko BC, Barnes JP, Staub RE, Walker FH, Kerlinger N. Metabolism of cycloate in radish leaf: metabolite identification by packed capillary flow fast atom bombardment tandem mass spectrometry. Biol Mass Spectrom. 1994 Oct;23(10):626-36. doi: 10.1016/j.ejphar.2016.02.041. Epub 2016 Feb 12.

    合成参考文献


    摘要:Fundamental and Applied Toxicology., 7(299), 1986
    摘要:Gigiena i Sanitariya. For English translation, see HYSAAV., 45(5)(29), 1980
    摘要:Tsitologiya i Genetika. Cytology and Genetics. For English translation, see CYGEDX., 16(1)(45), 1982
    摘要:USDA; Agric Res Service. ARS Pesticide Properties Database. Cycloate (1134-23-2). Available from the database query page at
    摘要:Weed Science Society of America. Herbicide Handbook. 5th ed. Champaign, Illinois: Weed Science Society of America, 1983., p. 123
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