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CAS号142-04-1 苯胺盐酸盐 | CAS号95-51-2 2-氯苯胺 | CAS号18708-70-8 2,4,6-三氯硝基苯 | CAS号529-23-7 邻氨基苯甲醛 | CAS号351027-75-3 N-(2,4,6-Trichl... | CAS号84104-39-2 2-(5-methyl-1,2... | CAS号1678-25-7 N-苯基苯磺酰胺 | CAS号24522-44-9 2-cyano-2',4',6... | CAS号799823-29-3 (Z)-3-(acetoxyi... | CAS号33979-03-2 2,2',4,4',6,6'-六氯联苯 | CAS号59291-64-4 2,2',3,4,4',6'-六氯联苯 | CAS号35693-92-6 2,4,6-三氯联苯 | CAS号32598-12-2 2,4,4',6-四氯联苯 | CAS号56558-16-8 2,2,4,6,6-五氯联苯 | CAS号31118-87-3 N-(2,4,6-三氯苯基)硫脲 | CAS号59291-65-5 2,3',4,4',5',6-六氯联苯 | CAS号50-43-1 2,4,6-三氯苯甲酸 | CAS号554-00-7 2,4-二氯苯胺 | CAS号106-47-8 对氯苯胺合成工艺路线路线简述
- 合成目标产物 2,4,6-Trichloroaniline 主要起始原料 2,4,6-Trichloronitrobenzene
- (文献来源)合成步骤主要原料 2,4,6-Trichloronitrobenzene
苯胺置于sodium Bismuthate,Zinc(II) Chloride体系中,用 溶剂黄146 作为反应溶剂,化学反应 0.5H,以72%的收率获得产物2,4,6-三氯苯胺
参考文献:金属卤化物和铋酸钠对芳香族化合物的氧化卤化作用
标题:金属卤化物和铋酸钠对芳香族化合物的氧化卤化作用
摘要:报道了一种新的温和高效的方法,用于在acoh中存在铋酸钠nabo 3的情况下用多种卤化物进行芳族卤化.ia,Iia,Iiia,Iva,Va族的金属卤化物和第一排过渡元素都适用于此方法.
DOI:10.1002/hlca.200390007
专利信息
专利号:US-2006052577-A1
优先权日:2001-02-06
标题:Methods of synthesis of polymers and copolymers from natural products
发明人:SWIFT GRAHAM; WESTMORELAND DAVID G; HUGHES KATHLEEN
权利人:SWIFT GRAHAM; WESTMORELAND DAVID G; HUGHES KATHLEEN
摘要:Described are polymers and copolymers containing sorbitol, citric acid, starch, aspartic acid, succinic anhydride, adipic acid mixtures thereof, methods of their synthesis and their uses.
专利号:US-5243032-A
优先权日:1989-06-22
标题:Preparation of azo pigments with low pcb content by coupling in the presence of olefins
发明人:RIEPER WOLFGANG
权利人:HOECHST AG
摘要:The production which is customary in practice of monoazo compounds based on dichloro- and trichloroanilines or disazo compounds of the chlorinated biphenyl series by conventional coupling methods meets with difficulties in that the resulting pigments are contaminated by traces of polychlorinated biphenyls. n According to the invention, it has now been found that by addition of water-soluble olefins of the type ##STR1## (R =H, alk or Oalk; X =--COOR 1 , --CONHR 2 or --NR 3 COR 4 ) n in the azo coupling, the side reactions which form PCBs can be decidedly suppressed during synthesis of the pigments.
专利号:US-4705866-A
优先权日:1985-12-26
标 题 :Synthesis of N-halogenated phenyl maleimide compounds with tin containing catalysts
发明人:GASTINGER ROBERT G
权利人:ATLANTIC RICHFIELD CO
摘要:A process for the preparation of N-brominated or N-chlorinated phenylmaleimide by reacting maleic anhydride and a brominated or chlorinated aniline compound at temperatures of from about 100 DEG C. to about 210 DEG C. in the presence of tin containing catalyst compound and optionally an inert solvent.
专利号:WO-2024155469-A1
优先权日:2023-01-19
标 题:One step reaction for the catalytic synthesis of cyclic urea derivatives
发明人:ZHOU HUI
权利人:HUNTSMAN PETROCHEMICAL LLC
摘要:A process for preparing a cyclic urea derivative by reacting an alkylene carbonate and a primary amine in the presence of a metal oxide catalyst to form the cyclic urea derivative.
专利号:US-4257942-A
优先权日:1977-10-06
标题:New water-insoluble azo dyes
发明人:DEFEO FRANCESCO; CIPOLLI ROBERTO
权利人:ACNA
摘要:The present invention relates to the synthesis of new dyes having the following general formula: wherein: D is the residue of a diazotizable component of the carbocyclic or heterocyclic series X is an ethylene group, optionally substituted by halogen-methyl, alkyl C1-C4, aryl, aralkyl or CH2OCO(HN)nR (wherein R and n have the meanings hereinafter defined); R is alkyl C1-C8 optionally substituted by halogen, CN,COOH; aryl optionally substituted by one or more atoms of halogen, alkyl C1-C4, alkoxyl C1-C4; alkoxyl C1-C4; alkoxyl C1-C8; Aryloxy; aralkoxy; cycloalkoxy; aralkyl; naphthyl optionally substituted by halogen; alkenyl C2-C8, optionally substituted by halogen, CN, COOH; R1 and R2, either like or unlike each other, may be alkyl C1-C4 optionally substituted by halogen or CN groups; aralkyl; R3 is H; halogen, alkyl C1-C4; alkoxyl C1-C4, optionally substituted. n is 0 or 1.
专利号:WO-9008142-A1
优先权日:1989-01-23
标题 :SYNTHESIS AND APPLICATION OF 1,3,6,8- AND 2,4,6,8-SUBSTITUTED DIBENZOFURANS AND DIBENZO-p-DIOXINS AS ANTITUMORIGENIC AGENTS
发明人:SAFE STEPHEN H
权利人:TEXAS A & M UNIV SYS
摘要:Novel 2,4,6,8- and 1,3,6,8-substituted dibenzofurans and dibenzo-p-dioxins, the preparation thereof and the use thereof as antiestrogens in the treatment of estrogen dependent tumors.