CAS: 1133-63-7; [1,1'-Biphenyl]-2,3-Diol

该化合物是二氢氧替代芳香化合物,其组成为联苯组,附于一个催化氢核心,这种结构具有显著的回活动性,特别是在切热和氧化过程中,使其在合成有机化学和协调化学应用中具有价值;两个相邻的氢氧基组的存在增强了其作为金属离子和金属离子的功能,促进了稳定的复合物的形成;此外,其芳香框架有助于其作为药物,农用化学品和特殊聚合物合成中间体的用途;该化合物的界定明确再活动特征和结构多功能性使其成为精细化学和材料科学领域研究人员的有用基石.

结构式图片

相似化合物

1079-21-6 1806-29-7 3934-76-7

欧盟法规

ECHA物质C&L通报

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CAS号40972-86-9 2,3-二甲氧基苯硼酸 | CAS号91-16-7 1,2-二甲氧基苯 | CAS号108-86-1 溴苯 | CAS号115377-97-4 1-(methoxymetho... | CAS号70871-45-3 2-羟基-3-苯基-2-环己酮 | CAS号98-59-9 对甲苯磺酰氯(PTSC) | CAS号90-43-7 2-苯基苯酚 | CAS号85-97-2 [1,1'-Biphenyl]... | CAS号120-80-9 邻苯二酚

合成工艺路线路线简述

    海关参考信息

    专利信息


    专利号:US-6201101-B1
    优先权日:1998-11-19
    标 题:Catalyst and its use for the synthesis of polyol polyethers
    发明人:TOZZOLA GABRIELLA; PO' RICCARDO; CARDI NICOLETTA
    权利人:ENICHEM SPA
    摘要:The present invention relates to a catalyst having general formula (I):wherein: M represents at least one cation of an element selected from earth-alkaline metals belonging to groups IIA, IIIA, VA, or transition metals belonging to groups IIB, IIIB, VB or VIIIB; n represents an integer between 0 and 2 and x is an integer between 2 and 5.The invention also relates to a process for the synthesis of polyol polyethers which uses a catalyst having general formula (I).

    专利号:US-7348395-B2
    优先权日:2003-12-15
    标 题:Synthesis of oligomeric cyanate esters
    发明人:KELLER TEDDY M; LASKOSKI MATTHEW
    权利人:US NAVY
    摘要:A cyanate ester system is disclosed. An aryl ether oligomer may be made from a dihydroxyaromatic compound and a dihaloaromatic compound in the presence of a base. The oligomer is then reacted with a cyanide compound in the presence of a base to form the cyanate ester shown below. The cyanate ester may then be cross-linked to a thermoset having triazine ring cross-links.n nHO—Ar 2 O—Ar 1 —O—Ar 2 n OH

    专利号:US-6096853-A
    优先权日:1998-12-21
    标 题 :Synthesis of phenolic monomers containing imide or diimide moieties and high heat carbonate polymers prepared therefrom
    发明人:AMERIK VALENTINA; HOEKS THEODORUS L; LIKIBI PARFAIT JEAN MARIE; NELSON MARK
    权利人:GEN ELECTRIC
    摘要:A process has been surprisingly discovered that can produce a high heat carbonate polymer (i.e., one with a Tg greater that 150° C.), without the drawbacks encountered in attempts to produce a high heat carbonate polymer. The process of the instant invention comprises the steps of: n (1) reacting an aromatic amine with a dihydric phenol to prepare an aminophenol; n (2) reacting an anhydride or dianhydride with the aminophenol to prepare a phenolic precursor; and n (3) reacting the phenolic precursor with a carbonate precursor to prepare a high heat carbonate polymer.

    专利号:US-5214118-A
    优先权日:1990-10-05
    标 题:Process for synthesis of polyestercarbonate-siloxane copolymers
    发明人:HAWKINS CHRISTOPHER M; ROSENQUIST NILES R
    权利人:GEN ELECTRIC
    摘要:A process for synthesizing polyestercarbonate-siloxane copolymers which have a smaller concentration of low molecular weight species and greater thermal stability has been described. Essentially the process includes adding the comonomer, diacid chloride siloxane, after approximately 1/3 of the phosgene has been added, in a conventional interfacial copolymerization, (as opposed to addition at the beginning of the polymerization).

    专利号:US-10017391-B2
    优先权日:2015-04-23
    标题:Direct polymer templating synthesis of mesoporous carbon
    发明人:DAI SHENG; NELSON KIMBERLY M
    权利人:UT BATTELLE LLC; UNIV TENNESSEE RES FOUND
    摘要:The invention is directed to a method for fabricating a mesoporous carbon composite material. The method comprises providing a precursor composition and subjecting the precursor material to a curing step followed by carbonization step. The precursor composition comprises (i) a templating component comprised of a linear homopolymer material, (ii) a phenolic compound or material, (iii) a crosslinkable aldehyde component, and (iv) an acid catalyst.

    专利号:US-7776971-B2
    优先权日:2003-05-06
    标题:Processes for the synthesis of dentritic macromolecules from conventional monomers
    发明人:PERCEC VIRGIL
    权利人:UNIV PENNSYLVANIA
    摘要:The inventive subject matter relates to novel synthetic processes which use a multifunctional compound (the “TERMINI compoundâ€?) having a masked or protected functional group, wherein the TERMINI compound is capable of quantitatively and irreversibly interrupting a living polymerization or a chain organic reaction. After deprotection or demasking of the functional group of the TERMINI compound, the same living polymerization or organic reaction resumes with 100% efficiency, or a different living polymerization or organic reaction resumes with 100% chemoselectivity, respectively. Once incorporated into a growing molecule, the TERMINI compound generates a branching point upon resumption of the polymerization or reaction.

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    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    [参考文献]: Angelina Chemerys, Et Al. Characterization Of Novel Polycyclic Aromatic Hydrocarbon Dioxygenases From The Bacterial Metagenomic Dna Of A Contaminated Soil. Appl Environ Microbiol. 2014 Nov;80(21):6591-600.
    [参考文献]: E Uchida, Et Al. Secretion Of Bacterial Xenobiotic-Degrading Enzymes From Transgenic Plants By An Apoplastic Expressional System: An Applicability For Phytoremediation. Environ Sci Technol. 2005 Oct 1;39(19):7671-7.
    [参考文献]: Frédéric H Vaillancourt, Et Al. Characterization Of Extradiol Dioxygenases From A Polychlorinated Biphenyl-Degrading Strain That Possess Higher Specificities For Chlorinated Metabolites. J Bacteriol. 2003 Feb;185(4):1253-60.
    [参考文献]: Frédéric H Vaillancourt, Et Al. Definitive Evidence For Monoanionic Binding Of 2,3-Dihydroxybiphenyl To 2,3-Dihydroxybiphenyl 1,2-Dioxygenase From Uv Resonance Raman Spectroscopy, Uv/vis Absorption Spectroscopy, And Crystallography. J Am Chem Soc. 2002 Mar 20;124(11):2485-96.
    [参考文献]: Hiroshi Habe, Et Al. Characterization Of The Upper Pathway Genes For Fluorene Metabolism In Terrabacter Sp. Strain Dbf63. J Bacteriol. 2004 Sep;186(17):5938-44.

    合成参考文献


    摘要:Allen, C. C. R., Science of Synthesis: Biocatalysis in Organic Synthesis, (2015) 3, 9.
    摘要:S109 | PARCEDC | List of 7074 potential endocrine disrupting compounds (EDCs) by PARC T4.2 | DOI:10.5281/zenodo.10944198
    参考文献:10.1007/s00284-005-0194-8
    摘要:Lambo AJ, Patel TR. Cometabolic degradation of polychlorinated biphenyls at low temperature by psychrotolerant bacterium Hydrogenophaga sp. IA3-A. Curr Microbiol. 2006 Jul;53(1):48–52. doi: 10.1007/s00284-005-0194-8.
    参考文献:10.1186/1471-2164-15-384
    摘要:D'Argenio V, Notomista E, Petrillo M, Cantiello P, Cafaro V, Izzo V, Naso B, Cozzuto L, Durante L, Troncone L, Paolella G, Salvatore F, Di Donato A. Complete sequencing of Novosphingobium sp. PP1Y reveals a biotechnologically meaningful metabolic pattern. BMC Genomics. 2014 May 19;15():384.
    参考文献:10.1007/s00253-019-09956-z
    摘要:Jia Y, Wang J, Ren C, Nahurira R, Khokhar I, Wang J, Fan S, Yan Y. Identification and characterization of a meta-cleavage product hydrolase involved in biphenyl degradation from Arthrobacter sp. YC-RL1. Applied Microbiology and Biotechnology. 2019 Jun 26;103(16):6825–36. doi: 10.1007/s00253-019-09956-z.
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