CAS: 912350-01-7; Potassium [4-(Phenylamino-1-Carbonyl)-Phenyl]Trifluoroborate
该化合物是一种有机三氟乙烷化合物,通常在苏祖基-米亚乌拉的交错反应中用作稳定的碳酸酸代谢器,其三氟乙酸混合物可以稳定地防止子球和氧化,改进处理和储存与常规碳酸相比.苯氨基碳基子成分引入了额外的功能,使其成为制药和材料科学应用的多种中间体.这种化合物因其可预见地回动性及与不同反应条件的兼容性,在可受控的选择性转化中特别有用.其晶体特性可以确保高纯度,便于合成工作流程的再生结果.
- 英文名称Potassium [4-(Phenylamino-1-Carbonyl)-Phenyl]Trifluoroborate
- 中文名称4-(苯基胺基羰基)苯基三氟硼酸钾
- IUPAC名称potassium trifluoro(4-(phenylcarbamoyl)phenyl)borate
- 其它别名Potassium [4-(Phenylaminocarbonyl)Phenyl]Trifluoroborate; Potassium [4-(Phenylamino-1-Carbonyl)-Phenyl]Trifluoroborate; Borate(1-), Trifluoro[4-[(Phenylamino)Carbonyl]Phenyl]-, Potassium (1:1), (T-4)-
- CAS编号912350-01-7
- MFCD编号:MFCD11977719
- EINECS号:677-307-7
- 分子式:C13H10BF3KNO分子量:303.13
- 产品CID: 1947180
- 产品分类有机原料 → 有机氟化合物 → 氟硼酸钾系列
MSDS等安全信息
欧盟法规
C&L通报合成工艺路线路线简述
- 374564-35-9 = 912350-01-7
反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran; 1 H,-78 °C1.2 10 Min,-78 °C; -78 °C -> Rt; 30 Min,Rt1.3 Reagents: Potassium Bifluoride Solvents: Water; 10 Min,Rt
标题:Linchpin Synthons: Metalation Of Aryl Bromides Bearing A Potassium Trifluoroborate Moiety
作者:Molander,Gary A.; Et Al
参考文献:Journal Of Organic Chemistry 日期:2006 卷标:71(19) 页码:7491-7493
📜异氰酸苯酯,4-溴苯基三氟硼酸钾置于正丁基锂,Potassium Hydrogen Bifluoride体系中,用 四氢呋喃 作为反应溶剂,化学反应 1.92H,以68%的收率获得产物4-(苯基胺基羰基)苯基三氟硼酸钾
参考文献:Linchpin Synthons: Metalation Of Aryl Bromides Bearing A Potassium Trifluoroborate Moiety
标题:Linchpin Synthons: Metalation Of Aryl Bromides Bearing A Potassium Trifluoroborate Moiety
摘要:Aryl Bromides Bearing A Potassium Trifluoroborate Moiety Were Subjected To Lithium-Halogen Exchange At Low Temperature Using A Variety Of Alkyllithium Reagents. A Number Of Different Electrophiles Were Evaluated In Their Reactions With The Aryllithiums Produced Therein. Under Carefully Optimized Conditions,Potassium Bromophenyl Trifluoroborates Afforded Good To Excellent Yields Of The Corresponding Alcohols (64-94% Isolated Yield) When Aldehydes Or Ketones Were Used As The Electophilic Partner. Esters Were Unfortunately Found To Be Unreactive.
DOI:10.1021/jo061324U
海关参考信息
- 2912110000-甲醛
2912210000-苯甲醛
2924199090-其他无环酰胺 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
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合成参考文献
参考文献:10.1055/s-2006-955611
摘要:Molander G, Ellis N. Metallation of Aryl Bromides Bearing a Potassium Trifluoroborate Moiety. Synfacts. 2006 Dec;2006(12):1269. doi: 10.1055/s-2006-955611.
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