CAS: 40327-96-6; 1,2,2,6,6-Pentamethylpiperidin-4-Amine

该化合物是一种具有显著用途的,在聚合物稳定化和有机合成中具有显著作用的受阻碍的衍生物,其结构以五甲基组为侧侧面的第三层探雷中心为特征,增强了其作为光稳定剂和抗氧化剂的效力,特别是在防止受紫外辐射或热应力照射的多烯和其他聚合物退化方面.该化合物的高度僵化阻力将不想要的侧面反应减少到最低程度,提高了催化工艺的选择性. 此外,在恶劣条件下,其稳定性在先进的材料科学和特殊化学配方中具有价值. 该矿物质功能进一步允许衍生,并允许对具体的工业或研究应用进行有针对性的修改.

结构式图片

相似化合物

36768-62-4 79-55-0 62995-79-3

欧盟法规

ECHA物质C&L通报

上下游产品

CAS号66651-24-9 3-[(1,2,2,6,6-p...

合成工艺路线路线简述

    Alkaline Earth Salt Of/the/ Methylsulfuric Acid置于异戊醇,Sodium体系中,化学反应生成 4-氨基-1,2,2,6,6-五甲基哌啶
    参考文献:Orthner,Justus Liebigs Annalen Der Chemie,1927,Vol. 456,P. 251
    标题:Orthner,Justus Liebigs Annalen Der Chemie,1927,Vol. 456,P. 251

    海关参考信息

    专利信息


    专利号:US-2009318592-A1
    优先权日:2005-10-11
    标 题 :Process for the Synthesis of Amine Ethers
    发明人:FREY MARKUS; BROENNIMANN VALERIE
    权利人:CIBA GEIGY CORP
    摘要:The present invention relates to novel processes for the preparation of a sterically hindered amine ether by reacting a corresponding sterically hindered amine oxide with a ketone or an aldehyde with at least one reactive H in the presence of a peroxydisulphate. Products obtained by this process may be hydrogenated. The compounds made by these processes are particularly effective in the stabilization of polymer compositions against harmful effects of light, oxygen and/or heat and as flame-retardants for polymers.

    专利号:US-2007191516-A1
    优先权日:2004-03-15
    标题 :Process for the synthesis of amine ethers
    发明人:FREY MARKUS; RAST VALERIE; BRAIG ADALBERT; KRAMER ANDREAS
    权利人:FREY MARKUS; RAST VALERIE; BRAIG ADALBERT; KRAMER ANDREAS
    摘要:A process for the preparation of a sterically hindered amine ether which comprises reacting a corresponding sterically hindered aminoxide with a C 5 -C 18 alk-1-ene in the presence of an organic hydroperoxide and optionally hydrogenating the resulting product as well as the product mixtures obtained therewith and their use as stabilizers and flame retardants.

    专利号:US-7402675-B2
    优先权日:2000-05-26
    标题 :Process for the synthesis of amine ethers from secondary amino oxides
    发明人:HAFNER ANDREAS; KIRNER HANS JUERG; SCHWARZENBACH FRANZ; VAN DER SCHAAF PAUL ADRIAAN; NESVADBA PETER
    权利人:CIBA SC HOLDING AG
    摘要:An amine ether of formula A n nwherein a is 1 or 2; and when a is 1, E is E′; when a is 2, E is L;n E′ is C 1 -C 36 alkyl; C 3 -C 18 alkenyl; C 2 -C 18 alkinyl; C 5 -C 18 cycloalkyl; C 5 -C 18 cycloalkenyl; a radical of a saturated or unsaturated aliphatic bicyclic or tricyclic hydrocarbon of 7 to 12 carbon atoms; C 2 -C 7 alkyl or C 3 -C 7 alkenyl substituted by halogen; C 7 -C 15 aralkyl or C 7 -C 15 aralkyl substituted by C 1 -C 4 alkyl or phenyl; or E′ is a radical of formula (VII) as explained in claim 1; T′ is tertiary C 4 -C 18 alkyl or phenyl, each of which are unsubstituted or substituted by halogen, OH, COOR 21 or C(O)—R 22 ; or T′ is C 5 -C 12 cycloalkyl; C 5 -C 12 cycloalkyl which is interrupted by at least one O or —NR 18 —; a polycyclic alkyl radical having 7-18 carbon atoms, or the same radical which is interrupted by at least one O or —NR 18 —; or T′ is —C(G 1 )(G 2 )-T″; or C 1 -C 18 alkyl or C 5 -C 12 cycloalkyl substituted by n n n n n n n n n n n n T″ is hydrogen, halogen, NO 2 , cyano, or is a monovalent organic radical comprising 1-50 carbon atoms; n or T″ and T′ together form a divalent organic linking group completing, together with the hindered amine nitrogen atom and the quaternary carbon atom substituted by G 1 and G 2 , an optionally substituted five- or six-membered ring structure; and all other residues are as defined in claim 1, n are obtained in good yield from the corresponding N-oxyl hindered amine precursor by reaction with a hydrocarbon E 1 -H or H-L-H in the presence of an organic hydroperoxide and a catalytic amount of copper or a copper compound. n n n n n The products of present process find utility as polymerization regulators and/or light stabilizers for organic material.

    专利号:US-6559311-B1
    优先权日:2001-10-30
    标题 :Process for the synthesis of a photo-stabilizer
    发明人:DESAI SHROJ AL MOHITKUMAR; SINGH RAJ PAL
    权利人:COUNCIL SCIENT IND RES
    摘要:The present invention relates to a process for the preparation of a photo-stabilizer of the general formula (I): n wherein R 1 is hydrogen, halogen, C 1 to C 12 alkyl, alkoxy (linear and branched), R 2 is hydrogen, C 1 -C 8 alkyl, cyclopentyl, cyclohexyl or cumyl, R 3 is hydrogen, C 1 -C 4 alkyl, R 4 is methyl or ethyl, R 5 is C 1 -C 8 alkyl, alkyl phenyl, alkoxy, acyl, cycloalkyl and allyl, X is O, NH, C 1 -C 8 alkyloxy and alkylamino (linear or branched), and derivatives and intermediates thereof.

    专利号:US-6417363-B1
    优先权日:1997-12-04
    标题 :Heterocyclyl ligand containing ruthenium and osmium catalysts
    发明人:VAN DER SCHAAF PAUL ADRIAAN; MUEHLEBACH ANDREAS; HAFNER ANDREAS; KOLLY ROMAN
    权利人:CIBA SC HOLDING AG
    摘要:Penta- and hexa-coordinated, bridged ruthenium and osmium catalysts of the formulawherein Me is ruthenium or osmium; L1 and L2 are neutral ligands having electron donor properties;X is an anionic ligand; Y is oxygen or sulphur; A is a direct bond, C1-C4alkylene or C2-C4alkylidene;Z is a direct bond, oxygen, sulphur or the groupswherein R1 and R2 are hydrogen or hydrocarbon radicals; their preparation and their us in the synthesis of polymers, in the ring-closure metathesis of diolefins, in the cross metathesis of olefins and in the isomerisation of olefins are disclosed.

    专利号:US-6077805-A
    优先权日:1997-03-06
    标题:Hexacoordinated ruthenium or osmium carbene catalysts
    发明人:VAN DER SCHAAF PAUL ADRIAAN; HAFNER ANDREAS; MUEHLEBACH ANDREAS
    权利人:CIBA SC HOLDING AG
    摘要:Hexacoordinated ruthenium and osmium catalysts of the formulae in which M and M' independently of one another are ruthenium or osmium; X, X', Y and Y' independently of one another are anionic ligands, or X and Y and X' and Y' in each case together are bis-anionic ligands L1 and L1' independently of one another are tertiary phosphine; L2 and L3 independently of one another are a monodentate ligand, or L2 and L3 together are bidentate, neutral electron donor ligands; L4 is tetradentate, neutral electron donor ligand; L5 is a bidentate, neutral electron donor ligand; and T and T' indepedently of one another are H or organic substituents, are useful for the synthesis of custom-tailored polymers and for the ring-closing metathesis of olefins.
    北京偶合科技有限公司
    ⚠️ 未注册 · 未认证企业
    ⚠️ 该商家尚未完成注册及企业认证,请用户仔细辨别,谨慎交易。
    数据来源于公开网络搜索,平台未作核实,请自行辨别。
    🏢敬请 企业认领
    🏬开设公司展台
    📢获取免费会员权益
    🎖️点亮专属注册企业标签
    📇展现公司完整信息 样本查看立即注册认领 →
    网址: http://www.ouhechem.com
    企业联系电话:010-51280831(不占线);010-82967028👤
    📞北京偶合科技有限公司 ⚠️参考联系方式
    联系人:刘先生
    电话:010-51280831(不占线);010-82967028
    手机:13911808554
    传真:010-82967029
    邮箱:sales@ouhechem.com
    通信地址: 北京市海淀区西三旗桥东上奥世纪2b-1328室
    邮编: 100096
    🆔 联系时候可告知是从"百琢研"平台获取的信息.
    ⚠️ 声明: 该企业未认证、未认领,请自行辨别信息的真实性和可靠性。咨询或交易时请注意风险评估与信息核实,百琢研不参与任何交易。企业认领注册入口→

    地址:北京市海淀区西三旗桥东上奥世纪2b-1328室
    ⚠️ 未注册 · 未认证企业
    注册入口 备注: 📌 数据来源说明:本展台内容基于各搜索引擎等公开数据整理,仅作展示用途。请用户自行辨别
    ✉️ 若企业需抹除展台内容或有异议, 请通过页面底部联系方式告知我们,我们会尽快处理。
    沈阳市摩尔医药技术开发有限责任公司
    ⚠️ 未注册 · 未认证企业
    ⚠️ 该商家尚未完成注册及企业认证,请用户仔细辨别,谨慎交易。
    数据来源于公开网络搜索,平台未作核实,请自行辨别。
    🏢敬请 企业认领
    🏬开设公司展台
    📢获取免费会员权益
    🎖️点亮专属注册企业标签
    📇展现公司完整信息 样本查看立即注册认领 →
    网址: http://www.mole-pharm.com
    企业联系电话:024-31204918 13889278616👤
    📞沈阳市摩尔医药技术开发有限责任公司 ⚠️参考联系方式
    联系人:余德胜
    电话:024-31204918 13889278616
    手机:13889278616
    传真:024-24519518
    邮箱:sales@mole-pharm.com
    通信地址: 沈阳市浑南新区文溯街17-1号
    邮编: 110017
    🆔 联系时候可告知是从"百琢研"平台获取的信息.
    ⚠️ 声明: 该企业未认证、未认领,请自行辨别信息的真实性和可靠性。咨询或交易时请注意风险评估与信息核实,百琢研不参与任何交易。企业认领注册入口→

    地址:沈阳市浑南新区文溯街17-1号
    ⚠️ 未注册 · 未认证企业
    注册入口 备注: 📌 数据来源说明:本展台内容基于各搜索引擎等公开数据整理,仅作展示用途。请用户自行辨别
    ✉️ 若企业需抹除展台内容或有异议, 请通过页面底部联系方式告知我们,我们会尽快处理。
    第 1 / 1 页
    现货

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    参考文献:10.1007/bf01158496
    摘要:Nikit-skaya ES, Alekseeva LM, Sheinker YN, Yakhontov LN. Synthesis of N′-substituted 4-amino piperidines with a shielded nitrogen atom. Chemistry of Heterocyclic Compounds. 1971 Dec;7(12):1553–9. doi: 10.1007/bf01158496.
    📝 需求与反馈
    尽可能描述清楚需求与问题信息
    ×

    通知