CAS: 28434-00-6; (+)-Trans-(S)-Allethrin
- 英文名称(+)-Trans-(S)-Allethrin
- 中文名称S-生物烯丙菊酯
- IUPAC名称3-Allyl-2-methyl-4-oxocyclopent-2-en-1-yl (1R-(1alpha(S*),3beta))-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylate
- 其它别名3-Allyl-2-methyl-4-ox°Cyclopent-2-en-1-yl [1R-[1α(S*),3β]]-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylate; Esbiol
- CAS编号28434-00-6
- MFCD编号:MFCD00167397
- EINECS号:249-013-5
- 分子式:C19H26O3分子量:302.41
- 产品CID: 1264520
- 产品分类化学农药原药 → 杀虫剂 → 拟除虫菊脂杀虫剂
物理性质
- 熔点49.5 °C
- 沸点386.8 °C at 760 mmHg
- 闪点166 °C
- 密度1.05 g/cm3
- PSA:43.37
- LogP:4.002
- 折射率1.505 (25ºC)
- 蒸汽压3.46E-06mmHg at 25°C
- 溶解性DMSO: 100 mg/mL (330.68 Mm; Need Ultrasonic)
- 敏感性D-TRANS-ALLETHRIN is incompatible with alkalis.
- 外观形态淡黄色至黄色液体
- 储存条件2-8°C
- 产品应用S-生物丙烯菊酯(28434-00-6)的用途:为扰乱轴突传导的触杀型神经毒剂.作用于昆虫引起剧烈的麻痹作用,倾仰落下,直至死亡.用于制作蚊香,电热蚊香片,气雾剂的有效成分.主要用于家蝇和蚊子等卫生害虫,有很强的触杀和驱避作用,击倒力较强.
MSDS等安全信息
- GHS象形图
- GHS符号GHS07 & GHS09;
注释: Exclamation mark & Environment - 危险类别急性毒性 类别4(吸入)
急性毒性 类别4(经口)
水生急性毒性 类别1
水生慢性毒性 类别1
急性毒性 类别4(经皮)
急性毒性 类别2(吸入) - 警示词Warning(警告)
- 危险描述H332 |吸入有害.
H302 |吞咽有害.
H400 |对水生生物毒性极大.
H410 |对水生生物毒性极大并具有长期持续影响.
H312 |皮肤接触有害.
H330 |吸入致命. - 防范说明P260-P280-P301+P312+P330-P304+P340+P310-P403+P233
- 危险等级6.1
- UN编号UN3082 9/PG 3
- 危险品标志Xn,N
- 包装等级III
- 安全声明36-60-61
- 危险类别码20/22-50/53
- WGK Germany3
欧盟法规
统一分类与标签ECHA物质工作场所安全标识要求ECHA物质C&L通报REACH预注册废弃物危险特性清单上下游产品
(1R)-trans-3-(2-methyl-1-propenyl)-2,2-dimethylcyclopropanecarboxylic acid chloride 3-(2-methyl-1-propenyl)-2,2-dimethylcyclopropanecarbonyl chloride (2)-dion-(1,4)2-Allyl-3-methyl-cyclopenten-(2)-dion-(1,4) (1S,3S)-trans-chrysanthemic acidallethrolone allethronyl glyoxylate allethronyl glyoxylate monohydrate 3-Methyl-but-2-enoic acid 3-allyl-2-methyl-4-oxo-cyclopent-2-enyl ester合成工艺路线路线简述
📜(-)-Trans-Chrysanthemoyl Chloride,Alkaline Earth Salt Of/the/ Methylsulfuric Acid置于吡啶体系中,化学反应生成S-生物烯丙菊酯
参考文献:Allethrin. Resolution Of Dl-Allethrolone And Synthesis Of The Four Optical Isomers Of Trans-Allethrin
标题:Allethrin. Resolution Of Dl-Allethrolone And Synthesis Of The Four Optical Isomers Of Trans-Allethrin
摘要:
Doi:10.1021/jo01368A027
海关参考信息
- 2901210000-乙烯
2901220000-丙烯
2905122000-异丙醇
2909110000-乙醚 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
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品牌试剂参考报价(招募中)
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主要参考文献
1: Al-Hussaini TK, Abdelaleem AA, Elnashar I, Shabaan OM, Mostafa R, El-Baz MAH, El-Deek SEM, Farghaly TA. The effect of follicullar fluid pesticides and polychlorinated biphenyls concentrations on intracytoplasmic sperm injection (ICSI) embryological and clinical outcome. Eur J Obstet Gynecol Reprod Biol. 2018 Jan;220:39-43. doi: 10.1016/j.ejogrb.2017.11.003. Epub 2017 Nov 16. doi: 10.1016/j.chroma.2017.06.056. Epub 2017 Jun 19. doi: 10.1016/j.chemosphere.2016.08.022. Epub 2016 Aug 24. doi: 10.1016/j.actatropica.2016.06.019. Epub 2016 Jun 17. doi: 10.1016/j.neuro.2016.03.010. Epub 2016 Mar 21. Review.
6: Head lice. Dimeticone is the pediculicide of choice. Prescrire Int. 2014 Jul;23(151):187-90. doi: 10.1016/j.envres.2014.01.003. Epub 2014 Mar 15. doi: 10.1016/j.carbpol.2013.08.002. Epub 2013 Aug 13. doi: 10.1016/j.neuro.2012.03.007. Epub 2012 Mar 28.
10: Ostrea EM Jr, Reyes A, Villanueva-Uy E, Pacifico R, Benitez B, Ramos E, Bernardo RC, Bielawski DM, Delaney-Black V, Chiodo L, Janisse JJ, Ager JW. Fetal exposure to propoxur and abnormal child neurodevelopment at 2 years of age. Neurotoxicology. 2012 Aug;33(4):669-75. doi: 10.1016/j.neuro.2011.11.006. Epub 2011 Dec 1.
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