专利号:US-9295978-B2 优先权日:2012-02-15 标题:Catalyst and method for the direct synthesis of dimethyl ether from synthesis gas 发明人:SCHÄFER ALEXANDER; MADON ROSTAM JAL; VON FEHREN THORSTEN 权利人:BASF CORP 摘要:Catalysts and methods for their manufacture and use for the synthesis of dimethyl ether from syngas are disclosed. The catalysts comprise ZnO, CuO, ZrO 2 , alumina and one or more of boron oxide, tantalum oxide, phosphorus oxide and niobium oxide. The catalysts may also comprise ceria. The catalysts described herein are able to synthesize dimethyl ether directly from synthesis gas, including synthesis gas that is rich in carbon monoxide.
专利号:US-2010099894-A1 优先权日:2006-10-09 标 题 :Method for the Synthesis of Cyclic Acetals by the Reactive Extraction of a Polyol in a Concentrated Solution 发明人:DUBOIS JEAN-LUC; IBORRA CHORNET SARA; VELTY ALEXANDRA I LUCIENNE; CORMA CANOS AVELINO 权利人:DUBOIS JEAN-LUC; IBORRA CHORNET SARA; VELTY ALEXANDRA I LUCIENNE; CORMA CANOS AVELINO 摘要:A method for the synthesis of cyclic acetals comprises reacting at least one carbonyl-function compound selected from aldehydes, ketones, and/or linear acetals, on a polyol in a concentrated aqueous solution exceeding 20 wt % in a reactor containing an acidic catalyst. The carbonyl-function compound is selected so that the cyclic acetal obtained has a water solubility lower than 20000 mg/kg. During the catalytic reaction for the cyclic acetal synthesis, at least one portion of the organic phase containing the cyclic acetal is separated. The acidic catalysis is either homogeneous when using a water-soluble strong acid, or heterogeneous when using a solid acid such as a resin, a zeolite, or any appropriately acidified solid. The extractive reaction method can be used for obtaining high conversions and selectivity.
专利号:US-7591897-B2 优先权日:2005-03-22 标 题 :Method for the rapid synthesis of large quantities of metal oxide nanowires at low temperatures 发明人:SUNKARA MAHENDRA KUMAR; VADDIRAJU SREERAM; MOZETIC MIRAN; CVELBAR UROS 权利人:UNIV LOUISVILLE RES FOUND 摘要:A process for the rapid synthesis of metal oxide nanoparticles at low temperatures and methods which facilitate the fabrication of long metal oxide nanowires. The method is based on treatment of metals with oxygen plasma. Using oxygen plasma at low temperatures allows for rapid growth unlike other synthesis methods where nanomaterials take a long time to grow. Density of neutral oxygen atoms in plasma is a controlling factor for the yield of nanowires. The oxygen atom density window differs for different materials. By selecting the optimal oxygen atom density for various materials the yield can be maximized for nanowire synthesis of the metal.
专利号:US-4267070-A 优先权日:1979-10-30 标题:Catalyst for the synthesis of aromatic monoisocyanates 发明人:NEFEDOV BORIS K; MANOV-JUVENSKY VLADIMIR I; DERGUNOV JURY I; RYSIKHIN ANATOLY I; CHIMISHKIAN ALEXANDR L 权利人:NEFEDOV BORIS K; MANOV JUVENSKY VLADIMIR I; DERGUNOV JURY I; RYSIKHIN ANATOLY I; CHIMISHKIAN ALEXANDR L 摘要:A catalyst for the synthesis of aromatic monoisocyanates comprising 1.64 to 16.6% by weight of palladium chloride, 0.16 to 47.6% by weight of an oxide of a metal of Group VB of the periodic system, 1.5 to 81.8% by weight of an oxide of a metal of Group VI B of the periodic system, 1.64 to 89.8% by weight of pyridine or an alkylsubstituted pyridine. n The use of the catalyst according to the invention in the synthesis of aromatic monoisocyanates makes it possible to obtain a high degree of conversion of the starting compound of up to 100%, a high yield of the desired product of up to 97%, and increased productivity of the catalyst of up to 40 g of the desired product per g of PdCl 2 per hour.
专利号:US-8815963-B1 优先权日:2013-11-04 标 题:Catalyst composition formulated for synthesis of alcohols and method of preparing the same 发明人:CARAM HUGO S; SAHOO RANJAN K; HERMAN RICHARD G; ACHARYA DIVYANSHU R 权利人:AUXILIUM GREEN LLC; UNIV LEHIGH 摘要:A catalyst composition includes an active material having a molybdenum- and sulfur-containing substance impregnated with an effective amount of cesium sufficient to promote synthesis of an alcohol, optionally carried on an inert support, wherein the active material is at least substantially free of a transition metal. The present invention is further directed to methods of preparing and using the same.
专利号:US-11753503-B2 优先权日:2018-05-17 标 题:Supported onium salts as initiators for the synthesis of polycarbonates by copolymerization of CO2 with epoxides 发明人:FENG XIAOSHUANG; PATIL NAGANATHA; LUCIANI CAROLINE; GNANOU YVES; HADJICHRISTIDIS NIKOS 权利人:UNIV KING ABDULLAH SCI & TECH 摘要:Supported onium salts used as initiators for the synthesis of polycarbonates by copolymerization of carbon dioxide with epoxides are described. Embodiments of the present disclosure describe initiators comprising an insoluble portion including an onium cation attached to an insoluble support; and an anion, wherein the anion is a counter-ion to the onium cation. Embodiments further describe methods of making polycarbonates using the initiator, methods of making initiators, and the like.