CAS: 116-11-0; 2-Methoxypropene

上下游产品

CAS号463-49-0 丙二烯 | CAS号74-99-7 丙炔 | CAS号67-56-1 甲醇 | CAS号77-76-9 2,2-二甲氧基丙烷 | CAS号124-38-9 二氧化碳 | CAS号74-83-9 溴甲烷 | CAS号24262-31-5 1-methylvinyl o... | CAS号110-86-1 吡啶 | CAS号91481-65-1 tert-butyl 2,2,... | CAS号67-64-1 丙酮 | CAS号108149-61-7 4-Methyl 3-(2-m... | CAS号112031-10-4 (R)-2,2-二甲基-1,3... | CAS号60456-21-5 (S)-(-)-2,2-二甲基... | CAS号37031-29-1 (-)-二甲基-2,3-邻异丙... | CAS号60822-65-3 2,2,4-三甲基-1,3-氧... | CAS号768-52-5 N-异丙基苯胺 | CAS号4107-98-6 N,N-二异丙苯胺 | CAS号147531-47-3 2-(ISOPROPYLAMI... | CAS号143527-74-6 3-(t-B°C)-2,2-d... | CAS号14252-46-1 2,2-bis(phenylt...

2,2-二甲氧基丙烷置于(Trimethylsilyl)Manganese Pentacarbonyl体系中,用 乙腈 用作溶剂,化学反应 2.0H,以77%的收率获得2-甲氧基丙烯
参考文献:通过金属硅烷试剂进行有机转化:由二甲基缩酮和(co)5 Mnsi(ch 3)3合成乙烯基醚
标题:通过金属硅烷试剂进行有机转化:由二甲基缩酮和(co)5 Mnsi(ch 3)3合成乙烯基醚
摘要:二甲基缩酮与(co)5 Mnsi(ch 3)3(在50oc的ch 3 Cn中)反应生成甲基烯醇醚,通常产率为75-95%.
Doi:10.1016/s0040-4039(00)86908-7

专利信息

专利号:US-9012625-B2
优先权日:2009-04-07
标 题 :Method for the synthesis of a trisaccharide
发明人：DÉKANY GYULA; Ã?GOSTON KÃ?ROLY; BAJZA ISTVAN; BOUTET JULIEN; BØJSTRUP MARIE; FANEFJORD METTE; PÉREZ FIGUEROA IGNACIO; HEDEROS MARKUS; HORVATH FERENC; KOVÃ?CS-PÉNZES PIROSKA; KRÖGER LARS; OLSSON JOHAN; RÖHRIG CHRISTOPH; SCHROVEN ANDREAS; VRASIDAS IOANNIS
权利人:DÉKANY GYULA; Ã?GOSTON KÃ?ROLY; BAJZA ISTVAN; BOUTET JULIEN; BØJSTRUP MARIE; FANEFJORD METTE; PÉREZ FIGUEROA IGNACIO; HEDEROS MARKUS; HORVATH FERENC; KOVÃ?CS-PÉNZES PIROSKA; KRÖGER LARS; OLSSON JOHAN; RÖHRIG CHRISTOPH; SCHROVEN ANDREAS; VRASIDAS IOANNIS; GLYCOM AS
摘要:The present invention relates to an improved synthesis of a trisaccharide of the formula (1), novel intermediates used in the synthesis and the preparation of the intermediates.

专利号:WO-2022107013-A1
优先权日:2020-11-19
标 题 :Silver assisted gold catalysis for the preparation of fondaparinux pentasaccharide and intermediates
发明人：HOTHA SRINIVAS; WALKE GULAB; KASDEKAR NITESHLAL; SUTAR YOGESH
权利人:INDIAN INSTITUTE OF SCIENCE EDUCATION AND RES
摘要:The present invention relates to a process for the synthesis of Fondaparinux pentasaccharide and its intermediates. Specifically, the present invention relates to a novel catalytic process for the synthesis of Fondaparinux pentasaccharide and its intermediates. The present invention further relates to a silver assisted gold catalysis for glycosylation reactions in the synthesis of Fondaparinux pentasaccharide and its intermediates. (I)

专利号:US-11220513-B2
优先权日:2015-04-30
标题:Chromium-mediated coupling and application to the synthesis of halichondrins
发明人：KISHI YOSHITO; YAN WUMING; LI JINGWEI; LI ZHANJIE; YAHATA KENZO
权利人:HARVARD COLLEGE
摘要:The present invention provides unified synthesis of the C1-C19 building blocks of halichondrins and analogs thereof using selective coupling of poly-halogenated nucleophiles in chromium-mediated coupling reactions. The present invention also provides a practical and efficient synthesis of C20-C38 building blocks of halichondrins and analogs thereof. Also provided herein are general methods of selective activation and coupling of poly-halogenated analogs with an aldehyde. The provided coupling reactions are selective for halo-enone and halo-acetylenic ketal over vinyl halide and halide attached to a sp hybridized carbon. The provided efficient selective coupling reactions can allow easy access to the C1-C19 building blocks and C20-C38 building blocks of halichondrins and analogs thereof with limited or no purification or separation of the intermediates.

专利号:US-4769497-A
优先权日:1986-07-04
标题:Process for the synthesis of 2,2-dialkoxy-propanes
发明人：MESSINA GIUSEPPE; MORETTI MARIO D; SANNA GAVINO; SANNA SALVATORE R; SOMA GIOVANNI
权利人:ENICHEM ANIC SPA
摘要:A new method of synthesis of a 2,2-dialkoxy-propane e.g. 2,2-dimethoxy-propane, is described through reaction of a cyclic ketal, e.g. 2,2-dimethyl-(1,3)-dioxolane, with a boric acid alkyl ester, e.g. boric acid trimethyl ester, in the presence of an acidic catalyst. The reaction may be carried out either in liquid or in vapour phase. In the latter case, heating of the thus obtained intermediate mixture to the reflux temperature should follow the catalytic step.

专利号:US-4743694-A
优先权日:1986-04-11
标 题 :Diastereocontrolled synthesis of 2-amino alcohols
发明人：CLAREMON DAVID A
权利人:MERCEK & CO INC
摘要:The addition of organolithium to dimethylhydrazones of certain ethers of a-hydroxyaldehydes results in the synthesis of threo- or erythro- intermediates readily convertible to threo- or erythro-2-amino alcohols.

专利号:US-8580975-B2
优先权日:2008-01-11
标 题:Synthesis of macrocyclic cancer chemotherapy agents and methods of use
发明人：GHOSH ARUN K; XU XIAOMING
权利人:GHOSH ARUN K; XU XIAOMING; PURDUE RESEARCH FOUNDATION
摘要:Herein are described a process for forming a quaternary carbon useful in the preparation of macrolactones, an enantioselective synthesis of (+)-peloruside A, and methods for treating a patient in need of relief from cancer or a cancer-related disease. The described processes are useful for preparing compounds containing quaternary carbons, including structural analogs and derivatives of peloruside A.