专利号:US-6235871-B1 优先权日:1997-12-03 标题:Synthesis of oligoarylamines, and uses and reagents related thereto 发明人:SINGER ROBERT A; SADIGHI JOSEPH P; BUCHWALD STEPHEN L; MACKEWITZ THOMAS 权利人:MASSACHUSETTS INST TECHNOLOGY 摘要:The transition metal-catalyzed amination of aryl halides, in conjunction with an orthogonal protective group scheme, forms the basis of two routes to oligoaniline precursors. The oligoaniline precursors are soluble in a variety of common organic solvents, and are easily converted to the deprotected oligoanilines. The method allows the preparation of oligoanilines of even or odd chain lengths, and the incorporation of a variety of functional groups into the oligomers. Polyanilines of low polydispersity can also be prepared by this method.
专利号:US-5025107-A 优先权日:1988-02-09 标题:Process for coproduction of arylene diamine dihalides and alkyl halides 发明人:CHAMBERLIN KIM S 权利人:EASTMAN KODAK CO 摘要:Disclosed is a process for the preparation of bis-acylamido aromatic compounds by reacting certain arylene dihalides with certain arylene dihalides in the presence of a copper catalyst. The process may be utilized in the synthesis of arylenediamines.
专利号:WO-9928290-A1 优先权日:1997-12-03 标 题:Synthesis of oligoarylamines, and uses and reagents related thereto
专利号:US-10731038-B2 优先权日:2016-06-23 标题 :(Dis)symmetric azomethine-type direct dye comprising at least one pyrazolopyridine unit, process for dyeing keratin fibers using this dye 发明人:SABELLE STÉPHANE; BLAIS STÉPHANE; FADLI AZIZ 权利人:OREAL 摘要:The subject of the present invention is symmetric or dissymetric azomethine direct dyes comprising at least one pyrazolopyridine unit of formula (I), a composition comprising said dyes, a process for treating keratin fibers using said dyes, a process for preparing these compounds, synthesis intermediates and a kit. In which formula (I) X, Y 1 , Y 2 , Z 1 , and R 1 to R 5 are as defined in the description.
专利号:US-5721280-A 优先权日:1996-10-07 标 题 :Method for depolymerizing polyimides and recovering reagents therefrom 发明人:WETZEL JOSEPH RICHARD; CARUSO ANDREW JAMES 权利人:GEN ELECTRIC 摘要:Polyimides, especially thermoset polyimides such as those prepared by the reaction of p-phenylenediamine with 4,4'-hexafluoroisopropylidenebis(phthalic anhydride) and nadic ester, are converted to monomers which may be recycled for polyimide synthesis by heating with a solution of an alkali metal hydroxide, such as lithium hydroxide or sodium hydroxide, in a dipolar aprotic solvent such as N-methylpyrrolidone. The products are the diamine and the tetracarboxylic acid alkali metal salt corresponding to the dianhydride.
专利号:WO-2006032879-A2 优先权日:2004-09-23 标 题:Methods of chemical synthesis and purification of diaminophenothiazinium compounds including methylthioninium chloride (mtc)
摘要:Doull, J., C.D. Klaassen, and M. D. Amdur (eds.). Casarett and Doull's Toxicology. 2nd ed. New York: Macmillan Publishing Co., 1980., p. 281 摘要:U.S. DEPT of HEALTH EDUC & WELFARE; Bioassay of p-Phenylenediamine Dihydrochloride for Possible Carcinogenicity; 10/25/78; EPA Doc No. 40-7936206; Fiche No. OTS0506154 摘要:S13 | EUCOSMETICS | Combined Inventory of Ingredients Employed in Cosmetic Products (2000) and Revised Inventory (2006) | DOI:10.5281/zenodo.2624118 摘要:Final Report 12/2007 Available from CIR 摘要:IARC. Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Humans. Geneva: World Health Organization, International Agency for Research on Cancer, 1972-PRESENT. (Multivolume work).